DE492279C - Process for the production of fine synthetic threads from viscose - Google Patents

Process for the production of fine synthetic threads from viscose

Info

Publication number
DE492279C
DE492279C DEB106495D DEB0106495D DE492279C DE 492279 C DE492279 C DE 492279C DE B106495 D DEB106495 D DE B106495D DE B0106495 D DEB0106495 D DE B0106495D DE 492279 C DE492279 C DE 492279C
Authority
DE
Germany
Prior art keywords
viscose
production
threads
synthetic threads
fine synthetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB106495D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DEB106495D priority Critical patent/DE492279C/en
Priority to FR693700D priority patent/FR693700A/en
Application granted granted Critical
Publication of DE492279C publication Critical patent/DE492279C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Description

Beim weiteren "Ausbau des Verfahrens nach der schweizerischen Patentschrift 94 666, insbesondere beim weiteren Ausbau des. Verfahrens zur Herstellung von Fäden aus fri-S scher, ungereinigter Viskose in neutralen bzw. schwachsauren Metallsalzbäderen nach der schweißerischen Patentschrift 87 368, ergibt sich, daß man um so leichter feine Kapillarfäden erzielen kann, je höher der Cellulosegehalt der zu verspinnenden Viskose gehalten wird. Besonders ist dies zutreffend, wenn die beiden vorerst genannten Verfahren kombiniert angewendet werden, also eine frische oder wenig vorgereifte Viskose in neutralen bzw. schwachsauren Metallsalzbädern zu dickeren Fäden versponnen und nach der Koagulierung, jedoch vor der Hydratisierung, gestreckt wird, wobei noch als besonderes Merkmal der Zellstoffgehalt derWith further "expansion of the process according to Swiss patent specification 94 666, in particular in the further expansion of the. Process for the production of threads from fri-S shear, unpurified viscose in neutral or weakly acidic metal salt baths the welding patent specification 87 368, it follows that it is all the easier for fine capillary threads can achieve the higher the cellulose content of the viscose to be spun will. This is particularly true when the two procedures mentioned above can be used in combination, i.e. a fresh or slightly pre-ripened viscose in neutral or weakly acidic metal salt baths into thicker threads and after coagulation, but before hydration, is stretched, with still as special feature of the pulp content of the

ao Viskose auf über io°/0, vorzugsweise auf 10 bis I5°/O gehalten wird.ao viscose is kept at over 10 ° / 0 , preferably at 10 to 15 ° / 0 .

Die so hergestellteKunstseide zeichnet sich durch besonders hervorragende textile Eigenschaften aus. Sie besitzt eine erheblichThe artificial silk produced in this way is characterized by particularly excellent textile properties the end. She owns a substantial

2^ größere Deckkraft, größere Weichheit und hat einen der echten Seide ähnlichen ruhigen Glanz. Auch läßt sich diese Seide mit den gebräuchlichen Farbstoffen erheblich gleichmäßiger anfärben. 2 ^ greater opacity, greater softness and a calm sheen similar to real silk. This silk can also be dyed much more evenly with the usual dyes.

Es ist zwar schon vorgeschlagen, Viskose mit einem Cellulosegehalt von über io°/0 zu verspinnen (s. Patentschrift 337672), doch bezog sich das besagte Verfahren auf die sonst übliche Arbeitsweise und auf die Erstellung von verhältnismäßig starken Kapillarfäden von 6 Denier und darüber.Although it has already been proposed to spin viscose with a cellulose content of over 10 ° / 0 (see patent specification 337672), the said process referred to the otherwise customary procedure and to the production of relatively strong capillary threads of 6 denier and above.

Auch die Herstellung feiner Fäden ist bereits mit französischer Patentschrift 511 823 beschrieben. Jedoch handelt es sich hier um das Verspinnen sehr reifer Viskose, während nach dem vorliegenden Verfahren frische, wenig vorgereifte Viskose verwendet wird. Mithin ist schon das Erfindungsmerkmal der französischen Patentschrift 511 823, welches — wie es im Anspruch heißt — in der Verwendung sehr reifer Viskose besteht, ein ganz anderes als das Erfindungsmerkmal der vorliegender Erfindung.The production of fine threads is also already covered by French patent specification 511 823 described. However, this involves the spinning of very ripe viscose while according to the present process, fresh, less premature viscose is used. Thus, the feature of the invention of the French patent specification 511 823, which - as it says in the claim - consists in the use of very ripe viscose quite different from the feature of the present invention.

Im übrigen wird der hervorragende technische Effekt nach vorliegender Erfindung durch die Kombination erreicht, daß man frische oder wenig vorgereifte Viskose in neutralen oder schwachsauren Metallsalzbädern zu Fäden verspinnt und den Faden nach der Koagulierung, jedoch vor der Hydratisierung, streckt, wobei der Zellstoffgehalt auf über io°/0 bzw. auf 12 bis I5°/O gehaltenIn addition, the excellent technical effect according to the present invention is achieved by the combination that fresh or slightly pre-ripened viscose is spun into threads in neutral or weakly acidic metal salt baths and the thread is stretched after coagulation, but before hydration, the pulp content being over io held ° / 0 and at 12 ° to I5 / O

Aus dem nachstehend angeführten Ausführungsbeispiel gehen die Arbeitsweise und die textlien Eigenschaften des erzeugten Produktes hervor.The working method and go from the exemplary embodiment given below the textile properties of the product produced.

A u s f üh r u η g s b e i s ρ i elA u u u η g s b e i s ρ i el

Zum Verspinnen gelangt eine Viskose von ii,45°/0 Cellulosegehalt und io,oy°j0 Alkaligehalt. Die Viskosität betrug 43,4 und die Reife nach Hottenroth 13,6. Die fertigenA viscose with a cellulose content of 1.45 ° / 0 and an alkali content of 10, oy ° j 0 is used for spinning. The viscosity was 43.4 and the Hottenroth maturity was 13.6. The finished

Fäden zeigten einen Titer von 152 Den. und eine Kapillarfadenzahl von 37, eine Dehnbarkeit von 122 mm auf 1 m und eine Stärke von 180 für 100 Den. ■Threads had a titer of 152 den. and a capillary thread count of 37, an extensibility of 122 mm to 1 m and a thickness from 180 for 100 den. ■

Claims (1)

Patentanspruch:Claim: Verfahren zur Herstellung feiner Fäden durch Verspinnen von Viskose in schwachsaure Fällbäder mit hohem Salzgehalt, dadurch gekennzeichnet, daß man frische oder wenig vorgereifte Viskose mit einem Cellulosegehalt von io°/0 und darüber, vorzugsweise 12 bis iS°/0, in schwachsaure Fällbäder mit hohem Salzgehalt verspinnt und den ersponnenenCellulosexanthogenatfaden vor der Umwandlung in Cellulosehydrat streckt.Process for the production of fine threads by spinning viscose in weakly acidic precipitation baths with a high salt content, characterized in that fresh or slightly pre-ripened viscose with a cellulose content of 10 ° / 0 and above, preferably 12 to 15 ° / 0 , in weakly acidic precipitation baths with a high Salinity and stretch the spun cellulose xanthate thread before it is converted into cellulose hydrate.
DEB106495D 1922-09-19 1922-09-19 Process for the production of fine synthetic threads from viscose Expired DE492279C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEB106495D DE492279C (en) 1922-09-19 1922-09-19 Process for the production of fine synthetic threads from viscose
FR693700D FR693700A (en) 1922-09-19 1930-04-11 Manufacturing process of fine artificial threads

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB106495D DE492279C (en) 1922-09-19 1922-09-19 Process for the production of fine synthetic threads from viscose

Publications (1)

Publication Number Publication Date
DE492279C true DE492279C (en) 1930-09-18

Family

ID=6991648

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB106495D Expired DE492279C (en) 1922-09-19 1922-09-19 Process for the production of fine synthetic threads from viscose

Country Status (2)

Country Link
DE (1) DE492279C (en)
FR (1) FR693700A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2491937A (en) * 1944-09-12 1949-12-20 Rayonier Inc Method of producing rayon filaments from viscose
US2572936A (en) * 1947-02-27 1951-10-30 American Viscose Corp Process for making crimped artificial filaments
DE969389C (en) * 1949-08-25 1958-05-29 Chimiotex S A Process for the production of cotton-like threads, fibers or ribbons by deforming viscose

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2491937A (en) * 1944-09-12 1949-12-20 Rayonier Inc Method of producing rayon filaments from viscose
US2572936A (en) * 1947-02-27 1951-10-30 American Viscose Corp Process for making crimped artificial filaments
DE969389C (en) * 1949-08-25 1958-05-29 Chimiotex S A Process for the production of cotton-like threads, fibers or ribbons by deforming viscose

Also Published As

Publication number Publication date
FR693700A (en) 1930-11-24

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