DE3779985T2 - Kohlenwasserstoffumwandlung mit trimetallischem katalysator. - Google Patents

Kohlenwasserstoffumwandlung mit trimetallischem katalysator.

Info

Publication number
DE3779985T2
DE3779985T2 DE8787307234T DE3779985T DE3779985T2 DE 3779985 T2 DE3779985 T2 DE 3779985T2 DE 8787307234 T DE8787307234 T DE 8787307234T DE 3779985 T DE3779985 T DE 3779985T DE 3779985 T2 DE3779985 T2 DE 3779985T2
Authority
DE
Germany
Prior art keywords
component
hydrocarbons
uniformly
hydrocarbon conversion
trimetallic catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8787307234T
Other languages
English (en)
Other versions
DE3779985D1 (de
Inventor
Mark D Moser
Randy J Lawson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Publication of DE3779985D1 publication Critical patent/DE3779985D1/de
Application granted granted Critical
Publication of DE3779985T2 publication Critical patent/DE3779985T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J35/397
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/624Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with germanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8966Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B01J35/19
    • B01J35/396
    • B01J35/399
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/085Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09Bimetallic catalysts in which at least one of the metals is a platinum group metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Disintegrating Or Milling (AREA)
  • Glass Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE8787307234T 1986-09-22 1987-08-17 Kohlenwasserstoffumwandlung mit trimetallischem katalysator. Expired - Fee Related DE3779985T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/910,099 US4677094A (en) 1986-09-22 1986-09-22 Trimetallic reforming catalyst

Publications (2)

Publication Number Publication Date
DE3779985D1 DE3779985D1 (de) 1992-07-30
DE3779985T2 true DE3779985T2 (de) 1992-12-10

Family

ID=25428309

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787307234T Expired - Fee Related DE3779985T2 (de) 1986-09-22 1987-08-17 Kohlenwasserstoffumwandlung mit trimetallischem katalysator.

Country Status (24)

Country Link
US (1) US4677094A (de)
EP (1) EP0261785B1 (de)
JP (1) JPS6393352A (de)
KR (1) KR900004492B1 (de)
CN (2) CN1009804B (de)
AT (1) ATE77572T1 (de)
AU (1) AU601220B2 (de)
CA (1) CA1299161C (de)
CS (1) CS274458B2 (de)
DD (1) DD281968A5 (de)
DE (1) DE3779985T2 (de)
ES (1) ES2032830T3 (de)
FI (1) FI874114A (de)
HU (1) HU201484B (de)
IN (1) IN170964B (de)
MX (1) MX165236B (de)
MY (1) MY101980A (de)
NO (1) NO873942L (de)
NZ (1) NZ221363A (de)
PH (1) PH26593A (de)
PT (1) PT85767B (de)
RU (1) RU1797496C (de)
TR (1) TR23037A (de)
ZA (1) ZA875432B (de)

Families Citing this family (49)

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US4737483A (en) * 1986-09-22 1988-04-12 Uop Inc. Trimetallic reforming catalyst
US4791087A (en) * 1986-09-22 1988-12-13 Uop Inc. Trimetallic reforming catalyst
US4923595A (en) * 1986-09-22 1990-05-08 Uop Trimetallic reforming catalyst
CA2055929A1 (en) * 1990-12-14 1992-06-15 William C. Baird, Jr. Process for reforming at low severities with high activity, high yield tin modified platinum-iridium catalysts
US5106809A (en) * 1990-12-14 1992-04-21 Exxon Research And Engineering Company High activity, high yield tin modified platinum-iridium catalysts, and reforming process utilizing such catalysts
US5221465A (en) * 1990-12-14 1993-06-22 Exxon Research And Engineering Company High activity, high yield tin modified platinum-iridium catalysts, and reforming process utilizing such catalysts
US5269907A (en) * 1990-12-14 1993-12-14 Exxon Research And Engineering Co. Process for reforming at low severities with high-activity, high-yield, tin modified platinum-iridium catalysts
CA2064520A1 (en) * 1991-05-06 1992-11-07 William C. Baird, Jr. Low pressure, semi-regenerative reforming process
FR2682949B1 (fr) * 1991-10-24 1993-12-17 Rhone Poulenc Chimie Procede de synthese d'aldehydes.
US5382350A (en) * 1992-10-16 1995-01-17 Uop High hydrogen and low coke reforming process
EP0681870B1 (de) * 1992-11-12 1999-07-28 Uop Mehrmetall-Reformierungskatalysator zur Umwandlung von Paraffinen zu Aromater
US5314854A (en) * 1992-11-12 1994-05-24 Uop Stable, high-yield reforming catalyst
US5464800A (en) * 1992-11-12 1995-11-07 Uop Stable, high-yield reforming catalyst
US5755956A (en) * 1992-11-12 1998-05-26 Uop Stable, high-yield reforming catalyst
US5366617A (en) * 1992-12-28 1994-11-22 Uop Selective catalytic reforming with high-stability catalyst
US5461016A (en) * 1992-12-28 1995-10-24 Uop High-stability catalyst containing a platinum group metal and nickel on zeolite L and a binder
FR2726486B1 (fr) * 1994-11-07 1997-01-24 Eurecat Europ Retrait Catalys Procede de regeneration hors site de catalyseur comprenant au moins un metal precieux
FR2735396B1 (fr) * 1995-06-16 1997-08-22 Inst Francais Du Petrole Catalyseurs utilisables dans les reactions de transformation d'hydrocarbures et contenant du titane, zirconium, hafnium, cobalt, nickel et/ou zinc
WO1997000130A1 (fr) 1995-06-16 1997-01-03 Institut Français Du Petrole Catalyseurs utilisables dans les reactions de transformation d'hydrocarbures et contenant du silicium
FR2735389B1 (fr) * 1995-06-16 1997-08-22 Inst Francais Du Petrole Catalyseurs utilisables dans les reactions de transformation d'hydrocarbures
CN1055106C (zh) * 1995-06-16 2000-08-02 法国石油公司 用于烃转化反应的含有一种加入金属的催化剂
FR2735388B1 (fr) * 1995-06-16 1997-08-22 Inst Francais Du Petrole Catalyseurs contenant du silicium et du titane, zirconium, hafnium, cobalt, nickel et/ou zinc, utilisables dans les reactions de transformation d'hydrocarbures
FR2753984B1 (fr) * 1996-10-02 1999-05-28 Inst Francais Du Petrole Procede de conversion d'une fraction lourde d'hydrocarbures impliquant une hydrodemetallisation en lit bouillonnant de catalyseur
CA2217145A1 (en) * 1996-11-12 1998-05-12 Phillips Petroleum Company An improved zeolite material and the use thereof in the conversion of non-aromatic hydrocarbons to aromatics and light olefins
US5800696A (en) * 1996-11-12 1998-09-01 Phillips Petroleum Company Method for inhibiting the rate of coke formation during the zeolite catalyzed aromatization of hydrocarbons
US6132595A (en) * 1996-11-21 2000-10-17 Uop Llc Reforming with selective multimetallic multigradient catalyst
US5883032A (en) * 1996-11-21 1999-03-16 Uop Llc Selective multimetallic multigradient reforming catalyst
CN1075106C (zh) * 1997-09-08 2001-11-21 环球油品公司 有选择性的双功能多金属烃类转化催化剂组合物及其使用方法
FR2770420B1 (fr) * 1997-10-31 1999-12-03 Inst Francais Du Petrole Lit homogene de catalyseur et procede de transformation d'hydrocarbures en composes aromatiques avec ledit lit
CN1108189C (zh) * 1999-07-09 2003-05-14 浙江大学 甲烷二氧化碳重整制合成气的催化剂及其制备方法和用途
CN1091134C (zh) * 1999-09-29 2002-09-18 中国石油化工集团公司 一种渣油加氢转化催化剂及其制备方法
US6503866B1 (en) * 2000-06-05 2003-01-07 Uop Llc Attrition resistant catalyst with reduced surface area
US6514904B1 (en) 2000-06-05 2003-02-04 Uop Llc Hydrocarbon conversion catalyst and process of using thereof
US6548444B2 (en) * 2001-06-20 2003-04-15 Eastman Chemical Company Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols
US20040147619A1 (en) * 2003-01-23 2004-07-29 Conocophillips Company Chlorine-containing synthesis gas catalyst
US7220701B2 (en) * 2003-11-24 2007-05-22 Exxonmobil Chemical Patents Inc. Catalyst and process for selective hydrogenation
US7199273B2 (en) * 2003-11-24 2007-04-03 Exxonmobil Chemical Patents, Inc. Selective hydrogenation of alkynes and/or diolefins
US20050113614A1 (en) * 2003-11-24 2005-05-26 Lowe David M. Catalyst and process for selective hydrogenation
US7220700B2 (en) 2003-11-24 2007-05-22 Exxonmobil Chemical Patents Inc. Catalyst and process for selective hydrogenation
US20060102520A1 (en) * 2004-11-12 2006-05-18 Lapinski Mark P Reforming process using high density catalyst
CN102728352A (zh) 2005-07-27 2012-10-17 切夫里昂菲利普化学有限责任公司 选择性加氢催化剂及其制备和使用方法
CN101454077B (zh) * 2006-09-29 2014-02-26 株式会社科特拉 铑担载用溶液及用该溶液制备的铑催化剂
CN101633850B (zh) * 2008-07-24 2012-10-10 中国石油化工股份有限公司 一种催化重整催化剂的制备方法
US20100116714A1 (en) * 2008-11-12 2010-05-13 Lapinski Mark P Process and System for the Addition of Promoter Metal In Situ in a Catalytic Reforming Unit
US20120277511A1 (en) * 2011-04-29 2012-11-01 Uop Llc High Temperature Platformer
US8758599B2 (en) 2011-07-15 2014-06-24 Uop Llc Reforming catalyst and process
US20150045597A1 (en) 2013-08-07 2015-02-12 Uop Llc Integrated process for gasoline or aromatics production
US9199893B2 (en) 2014-02-24 2015-12-01 Uop Llc Process for xylenes production
CN105562043B (zh) * 2014-10-10 2017-12-22 中国石油化工股份有限公司 一种多金属重整催化剂的制备方法

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US3764557A (en) * 1969-10-09 1973-10-09 Chevron Res Catalyst activation process and activated catalyst
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US4431750A (en) * 1982-05-19 1984-02-14 Phillips Petroleum Company Platinum group metal catalyst on the surface of a support and a process for preparing same

Also Published As

Publication number Publication date
KR900004492B1 (ko) 1990-06-28
CN1044488A (zh) 1990-08-08
CN1009804B (zh) 1990-10-03
FI874114A (fi) 1988-03-23
AU7881587A (en) 1988-03-24
CN87106454A (zh) 1988-06-01
TR23037A (tr) 1989-01-24
EP0261785A2 (de) 1988-03-30
PT85767A (en) 1987-10-01
PT85767B (pt) 1990-07-31
JPS6393352A (ja) 1988-04-23
EP0261785B1 (de) 1992-06-24
DD281968A5 (de) 1990-08-29
CN1020918C (zh) 1993-05-26
ZA875432B (en) 1988-03-30
DE3779985D1 (de) 1992-07-30
MY101980A (en) 1992-02-29
NO873942L (no) 1988-03-23
ATE77572T1 (de) 1992-07-15
EP0261785A3 (en) 1989-01-11
IN170964B (de) 1992-06-20
FI874114A0 (fi) 1987-09-21
HU201484B (en) 1990-11-28
MX165236B (es) 1992-11-03
CS274458B2 (en) 1991-04-11
KR880004068A (ko) 1988-06-01
PH26593A (en) 1992-08-19
RU1797496C (ru) 1993-02-23
AU601220B2 (en) 1990-09-06
CA1299161C (en) 1992-04-21
HUT44450A (en) 1988-03-28
ES2032830T3 (es) 1993-03-01
NZ221363A (en) 1990-06-26
CS675787A2 (en) 1990-09-12
US4677094A (en) 1987-06-30

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