DE3669310D1 - Verfahren zur herstellung von cycloolefinen. - Google Patents

Verfahren zur herstellung von cycloolefinen.

Info

Publication number
DE3669310D1
DE3669310D1 DE8686113578T DE3669310T DE3669310D1 DE 3669310 D1 DE3669310 D1 DE 3669310D1 DE 8686113578 T DE8686113578 T DE 8686113578T DE 3669310 T DE3669310 T DE 3669310T DE 3669310 D1 DE3669310 D1 DE 3669310D1
Authority
DE
Germany
Prior art keywords
cycloolefines
producing
producing cycloolefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8686113578T
Other languages
English (en)
Inventor
Hajime Nagahara
Mitsuo Asahikasei Kura Konishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP60219263A external-priority patent/JPS6281332A/ja
Priority claimed from JP61041981A external-priority patent/JPS62201830A/ja
Priority claimed from JP61160717A external-priority patent/JPS6317834A/ja
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Application granted granted Critical
Publication of DE3669310D1 publication Critical patent/DE3669310D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8953—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • B01J35/393—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE8686113578T 1985-10-03 1986-10-02 Verfahren zur herstellung von cycloolefinen. Expired - Lifetime DE3669310D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP60219263A JPS6281332A (ja) 1985-10-03 1985-10-03 シクロオレフインを製造する方法
JP61041981A JPS62201830A (ja) 1986-02-28 1986-02-28 シクロオレフインを製造する方法
JP61160717A JPS6317834A (ja) 1986-07-10 1986-07-10 シクロオレフインの製造方法

Publications (1)

Publication Number Publication Date
DE3669310D1 true DE3669310D1 (de) 1990-04-12

Family

ID=27291021

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8686113578T Expired - Lifetime DE3669310D1 (de) 1985-10-03 1986-10-02 Verfahren zur herstellung von cycloolefinen.

Country Status (4)

Country Link
US (1) US4734536A (de)
EP (1) EP0220525B1 (de)
CA (1) CA1267914A (de)
DE (1) DE3669310D1 (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8816722D0 (en) * 1988-07-14 1988-08-17 British Petroleum Co Plc Chemical process & catalyst
GB8816721D0 (en) * 1988-07-14 1988-08-17 British Petroleum Co Plc Chemical process & catalyst
NL8901239A (nl) * 1989-05-18 1990-12-17 Meern Bv Engelhard De Katalysator voor hydrogenering en/of dehydrogenering.
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
CN1032251C (zh) * 1991-08-13 1996-07-10 旭化成工业株式会社 使单环芳烃连续部分氢化的方法
TW218865B (de) * 1992-01-24 1994-01-11 Asahi Carbon Kabushiki Kaisha
DE4203220A1 (de) * 1992-02-05 1993-08-12 Basf Ag Verfahren zur herstellung von cyclohexen durch partielle hydrierung von benzol
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US5414171A (en) * 1992-02-26 1995-05-09 Catalytica, Inc. Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins
EP0659718B1 (de) * 1993-12-24 1997-06-18 Mitsubishi Chemical Corporation Verfahren zur Herstellung von Cycloolefinen
DE4423725A1 (de) 1994-07-08 1996-01-11 Basf Ag Verfahren zur kontinuierlichen Herstellung von Cyclohexen durch partielle Hydrierung von Benzol
JP4008527B2 (ja) * 1997-04-02 2007-11-14 旭化成ケミカルズ株式会社 シクロオレフィンとシクロアルカンの製造方法
JP4025411B2 (ja) * 1997-04-16 2007-12-19 旭化成ケミカルズ株式会社 シクロオレフィンの製造方法
JPH1129503A (ja) * 1997-07-08 1999-02-02 Asahi Chem Ind Co Ltd シクロオレフィンの製造方法
US7919659B2 (en) * 2004-07-09 2011-04-05 Asahi Kasei Chemicals Corporation Catalyst for cycloolefin production and process for production
US7683227B2 (en) * 2004-12-22 2010-03-23 Exxonmobil Chemical Patents Inc. Production of aromatic hydrocarbons from methane
KR100966947B1 (ko) * 2005-08-26 2010-06-30 아사히 가세이 케미칼즈 가부시키가이샤 시클로올레핀의 제조 방법
US7977519B2 (en) * 2006-04-21 2011-07-12 Exxonmobil Chemical Patents Inc. Production of aromatic hydrocarbons from methane
JP5239570B2 (ja) 2007-09-04 2013-07-17 Ｊｆｅスチール株式会社 亜鉛系めっき鋼板
US20110054232A1 (en) 2008-02-21 2011-03-03 Neeraj Sangar Production of Aromatics from Methane
CN102264471A (zh) 2008-12-22 2011-11-30 旭化成化学株式会社 环烯烃制造用钌催化剂的制备方法、环烯烃的制造方法以及制造装置
IT1402745B1 (it) * 2010-10-27 2013-09-18 Polimeri Europa Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
ITMI20121724A1 (it) 2012-10-12 2014-04-13 Versalis Spa Catalizzatore a base di rutenio e suo impiego nell'idrogenazione selettiva di composti aromatici o poliinsaturi
CN103785382B (zh) * 2012-11-01 2016-08-03 中国石油化工股份有限公司 一种高稳定性苯加氢制环己烯催化剂及其制备方法和应用
CN103721709B (zh) * 2013-12-23 2015-08-12 浙江大学 一种苯选择加氢制环己烯催化剂的制备方法
CN103752307B (zh) * 2014-02-07 2015-09-23 赣州诚博科技服务有限公司 用于苯选择加氢制环己烯的核壳结构催化剂的制备方法
MX2018004214A (es) * 2015-10-05 2018-05-17 Basf Se Metodo para la produccion de catalizadores portadores de rutenio/hierro/carbono.
EP3632538B1 (de) * 2017-05-25 2021-11-24 Osaka Gas Co., Ltd. Entschwefelungsmittel für gase und gasentschwefelungsverfahren
CN109569595B (zh) * 2018-12-10 2021-09-14 郑州师范学院 一种苯选择加氢制环己烯Ru催化体系及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3767720A (en) * 1972-02-25 1973-10-23 Du Pont Selective hydrogenation of aromatic hydrocarbons to cycloolefins
US3912787A (en) * 1972-07-26 1975-10-14 Phillips Petroleum Co Selective partial hydrogenation of aromatics
US4055512A (en) * 1974-05-09 1977-10-25 Mitsubishi Chemical Industries Ltd. Catalyst for producing cycloolefin and method for making the same
US4197415A (en) * 1976-10-08 1980-04-08 Toray Industries, Inc. Process for preparing cyclic olefins by selective partial hydrogenation of aromatic hydrocarbons
DE3164339D1 (en) * 1980-12-31 1984-07-26 Stamicarbon Process for the preparation of a cycloalkene through partial hydrogenation of the corresponding aromatic hydrocarbon
US4532351A (en) * 1982-06-16 1985-07-30 Exxon Research And Engineering Co. Process for hydrogenating organic compounds by use of Group VIII aluminum-silicate catalysts
JPS59184138A (ja) * 1983-04-04 1984-10-19 Asahi Chem Ind Co Ltd シクロオレフインの製造方法
JPS60184031A (ja) * 1984-02-29 1985-09-19 Sumitomo Chem Co Ltd シクロオレフインの製造方法
JPS60199637A (ja) * 1984-03-23 1985-10-09 中村製袋株式会社 紐付袋の製造装置
EP0170915B1 (de) * 1984-07-31 1989-04-05 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von Zykloolefinen

Also Published As

Publication number Publication date
EP0220525A1 (de) 1987-05-06
EP0220525B1 (de) 1990-03-07
US4734536A (en) 1988-03-29
CA1267914A (en) 1990-04-17

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