DE3300866A1 - Oxalkylierte polyamidoamine, deren herstellung und deren verwendung als erdoelemulsionsspalter - Google Patents
Oxalkylierte polyamidoamine, deren herstellung und deren verwendung als erdoelemulsionsspalterInfo
- Publication number
- DE3300866A1 DE3300866A1 DE19833300866 DE3300866A DE3300866A1 DE 3300866 A1 DE3300866 A1 DE 3300866A1 DE 19833300866 DE19833300866 DE 19833300866 DE 3300866 A DE3300866 A DE 3300866A DE 3300866 A1 DE3300866 A1 DE 3300866A1
- Authority
- DE
- Germany
- Prior art keywords
- oxalkylated
- polyamidoamines
- polyamines
- oxpropylation
- alkoxylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000962 poly(amidoamine) Polymers 0.000 title claims description 16
- 239000000839 emulsion Substances 0.000 title description 14
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000003208 petroleum Substances 0.000 title description 7
- 239000000203 mixture Substances 0.000 claims description 19
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000010779 crude oil Substances 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 229920000768 polyamine Polymers 0.000 claims description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000000047 product Substances 0.000 description 22
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 16
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 15
- 239000003921 oil Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001555 benzenes Chemical class 0.000 description 3
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical group C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- TWCCSZRRWBBFHB-UHFFFAOYSA-N formaldehyde;2-(7-methyloctyl)phenol Chemical class O=C.CC(C)CCCCCCC1=CC=CC=C1O TWCCSZRRWBBFHB-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- UZVAZDQMPUOHKP-UHFFFAOYSA-N 2-(7-methyloctyl)phenol Chemical compound CC(C)CCCCCCC1=CC=CC=C1O UZVAZDQMPUOHKP-UHFFFAOYSA-N 0.000 description 1
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 1
- ZAXCZCOUDLENMH-UHFFFAOYSA-N 3,3,3-tetramine Chemical compound NCCCNCCCNCCCN ZAXCZCOUDLENMH-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 235000014820 Galium aparine Nutrition 0.000 description 1
- 240000005702 Galium aparine Species 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- SCHTXWZFMCQMBH-UHFFFAOYSA-N pentane-1,3,5-triamine Chemical compound NCCC(N)CCN SCHTXWZFMCQMBH-UHFFFAOYSA-N 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833300866 DE3300866A1 (de) | 1983-01-13 | 1983-01-13 | Oxalkylierte polyamidoamine, deren herstellung und deren verwendung als erdoelemulsionsspalter |
| US06/568,831 US4546151A (en) | 1983-01-13 | 1984-01-06 | Oxyalkylated polyamidoamines and their preparation |
| GB08400774A GB2135685B (en) | 1983-01-13 | 1984-01-12 | Oxyalkylated polyamidoamines and their preparation |
| NO840104A NO157704C (no) | 1983-01-13 | 1984-01-12 | Oksalkylerte polyamidoaminer, fremgangsmaate for fremstilling av slike, samt anvendelse av dem. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19833300866 DE3300866A1 (de) | 1983-01-13 | 1983-01-13 | Oxalkylierte polyamidoamine, deren herstellung und deren verwendung als erdoelemulsionsspalter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3300866A1 true DE3300866A1 (de) | 1984-07-19 |
| DE3300866C2 DE3300866C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-11-14 |
Family
ID=6188149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19833300866 Granted DE3300866A1 (de) | 1983-01-13 | 1983-01-13 | Oxalkylierte polyamidoamine, deren herstellung und deren verwendung als erdoelemulsionsspalter |
Country Status (4)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0264755A1 (de) * | 1986-10-16 | 1988-04-27 | BASF Aktiengesellschaft | Alkoxylierte amidgruppenhaltige Polyamine und deren Verwendung zum Brechen von Öl-in-Wasser- und Wasser-in-Öl-Emulsionen |
| WO1991011242A1 (de) * | 1990-01-29 | 1991-08-08 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur spaltung von öl-/wasser-emulsionen |
| WO2002077069A1 (de) * | 2001-03-28 | 2002-10-03 | Basf Aktiengesellschaft | Verwendung modifizierter polyaminoamide zur hydrophilierung von oberflächen |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4877842A (en) * | 1988-02-29 | 1989-10-31 | Petrolite Corporation | Demulsifier compositions and methods of preparation and use thereof |
| DE10319028B4 (de) * | 2003-04-28 | 2006-12-07 | Clariant Produkte (Deutschland) Gmbh | Demulgatoren für Mischungen aus Mitteldestillaten mit Brennstoffölen pflanzlichen oder tierischen Ursprungs |
| DE102004002080B4 (de) * | 2004-01-15 | 2007-03-29 | Clariant Produkte (Deutschland) Gmbh | Demulgatoren für Mischungen aus Mitteldestillaten mit Brennstoffölen pflanzlichen oder tierischen Ursprungs und Wasser |
| DE102004024532B4 (de) * | 2004-05-18 | 2006-05-04 | Clariant Gmbh | Demulgatoren für Mischungen aus Mitteldestillaten mit Brennstoffölen pflanzlichen oder tierischen Ursprungs und Wasser |
| CN101716475B (zh) * | 2009-11-11 | 2012-01-18 | 中国科学院化学研究所 | 一种反相破乳剂及其制备方法 |
| DE102012005377A1 (de) * | 2012-03-16 | 2013-03-14 | Clariant International Ltd. | Alkoxylierte Polyamidoamine und deren Verwendung als Emulsionsspalter |
| DE102012005279A1 (de) * | 2012-03-16 | 2013-03-14 | Clariant International Limited | Alkoxylierte, vernetzte Polyamidoamine und deren Verwendung als Emulsionsspalter |
| MX2020013204A (es) | 2018-06-06 | 2021-02-26 | Basf Se | Poliamidoaminas alcoxiladas como agentes dispersantes. |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1595302A1 (de) * | 1966-02-08 | 1970-03-05 | Basf Ag | Verfahren zur Herstellung von wasserloeslichen Kondensationsprodukten |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3684735A (en) * | 1970-03-23 | 1972-08-15 | Knut Oppenlaender | Crude oil demulsifiers |
| DE2030008A1 (de) * | 1970-06-18 | 1971-12-23 | Basf Ag | Verfahren zum Herstellen von hochoxalkylierten Polyamiden |
| US3725503A (en) * | 1971-06-03 | 1973-04-03 | Basf Ag | Polyamides with dispersed oxyalkyated grafted polyamides |
| DE2209242A1 (de) * | 1972-02-26 | 1973-10-04 | Wolff Walsrode Ag | Wasserloesliches verankerungsmittel aus kunstharz |
| DE2227546C3 (de) * | 1972-06-07 | 1979-04-05 | Basf Ag, 6700 Ludwigshafen | Verwendung von oxalkylierten PoIyalkylenpolyaminen zur SchneUentwässening von Rohölen |
| DE2347932C3 (de) * | 1973-09-24 | 1980-01-10 | Henkel Kgaa, 4000 Duesseldorf | Addukte von Epoxierverbindungen an Umsetzungsprodukte des E -Caprolactams mit N-Alkylalkandiaminen, deren Herstellung und Verwendung als antimikrobielle Mittel |
| DE2719978C3 (de) * | 1977-05-04 | 1980-09-25 | Basf Ag, 6700 Ludwigshafen | Erdölemulsionsspalter |
-
1983
- 1983-01-13 DE DE19833300866 patent/DE3300866A1/de active Granted
-
1984
- 1984-01-06 US US06/568,831 patent/US4546151A/en not_active Expired - Lifetime
- 1984-01-12 NO NO840104A patent/NO157704C/no not_active IP Right Cessation
- 1984-01-12 GB GB08400774A patent/GB2135685B/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1595302A1 (de) * | 1966-02-08 | 1970-03-05 | Basf Ag | Verfahren zur Herstellung von wasserloeslichen Kondensationsprodukten |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0264755A1 (de) * | 1986-10-16 | 1988-04-27 | BASF Aktiengesellschaft | Alkoxylierte amidgruppenhaltige Polyamine und deren Verwendung zum Brechen von Öl-in-Wasser- und Wasser-in-Öl-Emulsionen |
| US4935162A (en) * | 1986-10-16 | 1990-06-19 | Basf Aktiengesellschaft | Alkoxylated amido-containing polyamines and their use for breaking oil-in-water and water-in-oil emulsions |
| WO1991011242A1 (de) * | 1990-01-29 | 1991-08-08 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur spaltung von öl-/wasser-emulsionen |
| WO2002077069A1 (de) * | 2001-03-28 | 2002-10-03 | Basf Aktiengesellschaft | Verwendung modifizierter polyaminoamide zur hydrophilierung von oberflächen |
Also Published As
| Publication number | Publication date |
|---|---|
| NO157704B (no) | 1988-01-25 |
| GB8400774D0 (en) | 1984-02-15 |
| US4546151A (en) | 1985-10-08 |
| GB2135685B (en) | 1986-07-30 |
| NO157704C (no) | 1988-05-04 |
| NO840104L (no) | 1984-07-16 |
| GB2135685A (en) | 1984-09-05 |
| DE3300866C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-11-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |