DE3211221C2 - Verfahren zum Konditionieren von wäßrigen, radioaktiven Lösungen für die Endlagerung - Google Patents
Verfahren zum Konditionieren von wäßrigen, radioaktiven Lösungen für die EndlagerungInfo
- Publication number
- DE3211221C2 DE3211221C2 DE3211221A DE3211221A DE3211221C2 DE 3211221 C2 DE3211221 C2 DE 3211221C2 DE 3211221 A DE3211221 A DE 3211221A DE 3211221 A DE3211221 A DE 3211221A DE 3211221 C2 DE3211221 C2 DE 3211221C2
- Authority
- DE
- Germany
- Prior art keywords
- water
- waste
- polymer
- container
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 230000002285 radioactive effect Effects 0.000 title claims description 4
- 230000003750 conditioning effect Effects 0.000 title claims description 3
- 230000008569 process Effects 0.000 title description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000002699 waste material Substances 0.000 claims abstract description 40
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 37
- 229920000642 polymer Polymers 0.000 abstract description 29
- 238000001704 evaporation Methods 0.000 abstract description 13
- 230000008020 evaporation Effects 0.000 abstract description 12
- 239000002901 radioactive waste Substances 0.000 abstract description 3
- 239000002002 slurry Substances 0.000 abstract description 3
- 229920000620 organic polymer Polymers 0.000 abstract description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 40
- 239000007788 liquid Substances 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000000178 monomer Substances 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- 238000009835 boiling Methods 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 8
- 230000000379 polymerizing effect Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005538 encapsulation Methods 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- -1 divinyl ester Chemical class 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- KQNZLOUWXSAZGD-UHFFFAOYSA-N benzylperoxymethylbenzene Chemical compound C=1C=CC=CC=1COOCC1=CC=CC=C1 KQNZLOUWXSAZGD-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 239000012633 leachable Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/08—Processing by evaporation; by distillation
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
- G21F9/167—Processing by fixation in stable solid media in polymeric matrix, e.g. resins, tars
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Processing Of Solid Wastes (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Sealing Material Composition (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/250,439 US4434074A (en) | 1981-04-02 | 1981-04-02 | Volume reduction and encapsulation process for water containing low level radioactive waste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3211221A1 DE3211221A1 (de) | 1982-10-14 |
| DE3211221C2 true DE3211221C2 (de) | 1986-08-21 |
Family
ID=22947756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3211221A Expired DE3211221C2 (de) | 1981-04-02 | 1982-03-26 | Verfahren zum Konditionieren von wäßrigen, radioaktiven Lösungen für die Endlagerung |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4434074A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS57166600A (cg-RX-API-DMAC10.html) |
| KR (1) | KR890002386B1 (cg-RX-API-DMAC10.html) |
| BE (1) | BE892745A (cg-RX-API-DMAC10.html) |
| CH (1) | CH658334A5 (cg-RX-API-DMAC10.html) |
| DE (1) | DE3211221C2 (cg-RX-API-DMAC10.html) |
| ES (1) | ES511042A0 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2503438B1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB2096390B (cg-RX-API-DMAC10.html) |
| IT (1) | IT1151710B (cg-RX-API-DMAC10.html) |
| NL (1) | NL8201383A (cg-RX-API-DMAC10.html) |
| SE (1) | SE8202108L (cg-RX-API-DMAC10.html) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3710319A1 (de) * | 1987-03-28 | 1988-10-06 | Wilhelm Geiger Gmbh & Co | Verfahren zur langfristigen und umweltfreundlichen entsorgung von industriestaeuben mit wasserloeslichen anteilen, insbesondere von filterstaub aus muellverbrennungsanlagen |
| NO172967C (no) * | 1987-11-06 | 1993-10-06 | Rohm & Haas | Fremgangsmaate til innkapsling eller til aa bringe i fast tilstand et produkt som omfatter en stort sett kontinuerligvandig fase og loeste eller suspenderte stoffer |
| DD293219A5 (de) * | 1988-12-14 | 1991-08-22 | ������@������������k�� | Verfahren zum aufbereiten von borverbindungen und radionuklide enthaltendem abwasser |
| US5078924A (en) * | 1989-06-09 | 1992-01-07 | Spinello Ronald P | Apparatus and method for verifiably sterilizing, destroying and encapsulating regulated medical wastes |
| US4992217A (en) * | 1989-06-09 | 1991-02-12 | Spinello Ronald P | Apparatus and method for sterilizing, destroying and encapsulating medical implement wastes |
| US5401444A (en) * | 1989-06-09 | 1995-03-28 | Spintech Inc. | Apparatus and method for verifiably sterilizing, destroying and encapsulating regulated medical wastes |
| GB9217594D0 (en) * | 1992-08-19 | 1992-09-30 | Reads Plc | Process for the treatment of sludge |
| US5434334A (en) * | 1992-11-27 | 1995-07-18 | Monolith Technology Incorporated | Process for treating an aqueous waste solution |
| US5512730A (en) * | 1993-11-30 | 1996-04-30 | Spintech Inc. | Self sterilizing hypodermic syringe and method |
| US6387274B1 (en) | 2000-03-28 | 2002-05-14 | Chem-Nuclear Systems, Llc | System and method for the removal of radioactive particulate from liquid waste |
| WO2009055661A2 (en) * | 2007-10-24 | 2009-04-30 | Bemis Manufacturing Company | Methods and apparatus for collecting and disposing of sharps |
| US11027469B2 (en) | 2017-10-10 | 2021-06-08 | General Electric Company | Mold system including separable, variable mold portions for forming casting article for investment casting |
| US11148331B2 (en) | 2017-10-10 | 2021-10-19 | General Electric Company | Mold system including separable, variable mold portions for forming casting article for investment casting |
| US10618104B2 (en) | 2017-10-10 | 2020-04-14 | General Electric Company | Core with thermal conducting conduit therein and related system and method |
| KR102925685B1 (ko) * | 2024-04-25 | 2026-02-11 | (주)나일프렌트 | 방사성 붕산 폐기물 처리장치 및 처리방법 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954526A (en) * | 1971-02-22 | 1976-05-04 | Thiokol Corporation | Method for making coated ultra-fine ammonium perchlorate particles and product produced thereby |
| DE2363474C3 (de) * | 1973-12-20 | 1986-02-13 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur Verfestigung von im wesentlichen organischen, radioative oder toxische Stoffe enthaltenden Abfallflüssigkeiten |
| US4077901A (en) | 1975-10-03 | 1978-03-07 | Arnold John L | Encapsulation of nuclear wastes |
| DE2714672A1 (de) * | 1976-04-02 | 1977-11-10 | Bofors Ab | Verfahren zum abtrennen von festen, radioaktiven bestandteilen aus fluessigem abfall und ueberfuehren in einheiten fuer die langzeitlagerung |
| US4119560A (en) * | 1977-03-28 | 1978-10-10 | United Technologies Corporation | Method of treating radioactive waste |
-
1981
- 1981-04-02 US US06/250,439 patent/US4434074A/en not_active Expired - Fee Related
- 1981-08-07 JP JP56123154A patent/JPS57166600A/ja active Granted
-
1982
- 1982-02-22 GB GB8205165A patent/GB2096390B/en not_active Expired
- 1982-03-18 CH CH1692/82A patent/CH658334A5/de not_active IP Right Cessation
- 1982-03-25 IT IT20376/82A patent/IT1151710B/it active
- 1982-03-26 DE DE3211221A patent/DE3211221C2/de not_active Expired
- 1982-04-01 ES ES511042A patent/ES511042A0/es active Granted
- 1982-04-01 NL NL8201383A patent/NL8201383A/nl not_active Application Discontinuation
- 1982-04-01 SE SE8202108A patent/SE8202108L/ not_active Application Discontinuation
- 1982-04-02 BE BE0/207744A patent/BE892745A/fr not_active IP Right Cessation
- 1982-04-02 KR KR8201457A patent/KR890002386B1/ko not_active Expired
- 1982-04-02 FR FR8205748A patent/FR2503438B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2503438A1 (fr) | 1982-10-08 |
| CH658334A5 (de) | 1986-10-31 |
| BE892745A (fr) | 1982-10-04 |
| ES8405990A1 (es) | 1984-06-16 |
| KR890002386B1 (ko) | 1989-07-02 |
| IT1151710B (it) | 1986-12-24 |
| JPS6134118B2 (cg-RX-API-DMAC10.html) | 1986-08-06 |
| KR840000047A (ko) | 1984-01-30 |
| GB2096390B (en) | 1985-01-30 |
| NL8201383A (nl) | 1982-11-01 |
| US4434074A (en) | 1984-02-28 |
| IT8220376A0 (it) | 1982-03-25 |
| GB2096390A (en) | 1982-10-13 |
| JPS57166600A (en) | 1982-10-14 |
| FR2503438B1 (fr) | 1988-05-27 |
| ES511042A0 (es) | 1984-06-16 |
| SE8202108L (sv) | 1982-10-03 |
| DE3211221A1 (de) | 1982-10-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8128 | New person/name/address of the agent |
Representative=s name: EGGERT, H., DIPL.-CHEM. DR., 5000 KOELN MOSER, H., |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: PACIFIC NUCLEAR SYSTEMS, INC., FEDERAL WAY, WASH., |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: STREHL, P., DIPL.-ING. DIPL.-WIRTSCH.-ING. SCHUEBEL-HOPF, U., DIPL.-CHEM. DR.RER.NAT. GROENING, H.,DIPL.-ING., PAT.-ANWAELTE SCHULZ, R., DIPL.-PHYS. DR.RER.NAT., PAT.- U. RECHTSANW., 8000 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |