DE3201966A1 - Verfahren zur herstellung von tert.-alkyl-hypohalogeniten - Google Patents
Verfahren zur herstellung von tert.-alkyl-hypohalogenitenInfo
- Publication number
- DE3201966A1 DE3201966A1 DE19823201966 DE3201966A DE3201966A1 DE 3201966 A1 DE3201966 A1 DE 3201966A1 DE 19823201966 DE19823201966 DE 19823201966 DE 3201966 A DE3201966 A DE 3201966A DE 3201966 A1 DE3201966 A1 DE 3201966A1
- Authority
- DE
- Germany
- Prior art keywords
- reaction
- tert
- alkyl
- temperature
- hypochlorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 45
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 150000007529 inorganic bases Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- -1 olefin chlorohydrins Chemical class 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- IXZDIALLLMRYOU-UHFFFAOYSA-N tert-butyl hypochlorite Chemical compound CC(C)(C)OCl IXZDIALLLMRYOU-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- GUGRBFQNXVKOGR-UHFFFAOYSA-N butyl hypochlorite Chemical compound CCCCOCl GUGRBFQNXVKOGR-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000003945 chlorohydrins Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical class BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- GEOVEUCEIQCBKH-UHFFFAOYSA-N hypoiodous acid Chemical class IO GEOVEUCEIQCBKH-UHFFFAOYSA-N 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C71/00—Esters of oxyacids of halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23003681A | 1981-01-30 | 1981-01-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3201966A1 true DE3201966A1 (de) | 1982-08-19 |
| DE3201966C2 DE3201966C2 (enrdf_load_stackoverflow) | 1990-02-22 |
Family
ID=22863705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19823201966 Granted DE3201966A1 (de) | 1981-01-30 | 1982-01-22 | Verfahren zur herstellung von tert.-alkyl-hypohalogeniten |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS6030663B2 (enrdf_load_stackoverflow) |
| DE (1) | DE3201966A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2499068B1 (enrdf_load_stackoverflow) |
| GB (1) | GB2092137B (enrdf_load_stackoverflow) |
| NL (1) | NL8200023A (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1184149B (it) * | 1985-03-11 | 1987-10-22 | Montefluos Spa | Processo per la preparazione di fluorossi-alo-composti |
| JPH05176035A (ja) * | 1991-12-25 | 1993-07-13 | Matsushita Electric Ind Co Ltd | ボタン電話装置 |
| RU2446146C2 (ru) * | 2010-04-27 | 2012-03-27 | Открытое акционерное общество "Сибур-Нефтехим" | Способ получения трет-бутилгипохлорита |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1938175A (en) * | 1933-12-05 | Manufacture of alkyl hypohalites | ||
| US3149140A (en) * | 1964-09-15 | Process for preparing tertiary | ||
| US4008133A (en) * | 1974-09-20 | 1977-02-15 | The Lummus Company | Production of epoxy compounds from olefinic compounds |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4342703A (en) * | 1980-09-08 | 1982-08-03 | The Lummus Company | Production of alkyl hypohalites |
-
1982
- 1982-01-06 NL NL8200023A patent/NL8200023A/nl not_active Application Discontinuation
- 1982-01-11 GB GB8200703A patent/GB2092137B/en not_active Expired
- 1982-01-22 DE DE19823201966 patent/DE3201966A1/de active Granted
- 1982-01-28 JP JP1251982A patent/JPS6030663B2/ja not_active Expired
- 1982-01-28 FR FR8201346A patent/FR2499068B1/fr not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1938175A (en) * | 1933-12-05 | Manufacture of alkyl hypohalites | ||
| US3149140A (en) * | 1964-09-15 | Process for preparing tertiary | ||
| US4008133A (en) * | 1974-09-20 | 1977-02-15 | The Lummus Company | Production of epoxy compounds from olefinic compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3201966C2 (enrdf_load_stackoverflow) | 1990-02-22 |
| JPS57144245A (en) | 1982-09-06 |
| FR2499068A1 (fr) | 1982-08-06 |
| GB2092137B (en) | 1984-08-22 |
| JPS6030663B2 (ja) | 1985-07-17 |
| GB2092137A (en) | 1982-08-11 |
| FR2499068B1 (fr) | 1986-05-02 |
| NL8200023A (nl) | 1982-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |