DE3150205C2 - Verfahren zur Herstellung eines Silberkatalysators für die Produktion von Ethylenoxid - Google Patents

Verfahren zur Herstellung eines Silberkatalysators für die Produktion von Ethylenoxid

Info

Publication number
DE3150205C2
DE3150205C2 DE3150205A DE3150205A DE3150205C2 DE 3150205 C2 DE3150205 C2 DE 3150205C2 DE 3150205 A DE3150205 A DE 3150205A DE 3150205 A DE3150205 A DE 3150205A DE 3150205 C2 DE3150205 C2 DE 3150205C2
Authority
DE
Germany
Prior art keywords
catalyst
silver
thallium
alkali metal
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE3150205A
Other languages
German (de)
English (en)
Other versions
DE3150205A1 (de
Inventor
Toshihiko Yokohama Kanagawa Kumazawa
Masashi Mitsuhata
Shin-ichi Tokio/Tokyo Nagase
Takahiko Nakai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Publication of DE3150205A1 publication Critical patent/DE3150205A1/de
Application granted granted Critical
Publication of DE3150205C2 publication Critical patent/DE3150205C2/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE3150205A 1980-12-26 1981-12-18 Verfahren zur Herstellung eines Silberkatalysators für die Produktion von Ethylenoxid Expired DE3150205C2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55183935A JPS57107240A (en) 1980-12-26 1980-12-26 Production of silver catalyst for producing ethylene oxide

Publications (2)

Publication Number Publication Date
DE3150205A1 DE3150205A1 (de) 1982-08-05
DE3150205C2 true DE3150205C2 (de) 1987-02-26

Family

ID=16144375

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3150205A Expired DE3150205C2 (de) 1980-12-26 1981-12-18 Verfahren zur Herstellung eines Silberkatalysators für die Produktion von Ethylenoxid

Country Status (7)

Country Link
US (1) US4389338A (enExample)
JP (1) JPS57107240A (enExample)
BE (1) BE891602A (enExample)
CA (1) CA1165311A (enExample)
DE (1) DE3150205C2 (enExample)
FR (1) FR2497803B1 (enExample)
SE (1) SE451182B (enExample)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774222A (en) * 1982-06-16 1988-09-27 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide and process for preparing the catalyst
BG37835A3 (en) * 1982-06-30 1985-08-15 Hoechst Aktiengesellschaft Method for preparing silver catalyst
US4555501A (en) * 1984-05-14 1985-11-26 The Halcon Sd Group, Inc. Process for preparing silver catalysts
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US4897376A (en) * 1988-06-27 1990-01-30 Scientific Design Company, Inc. Process for preparing a catalyst for oxidation of ethylene to ethylene oxide
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5008413A (en) * 1989-10-23 1991-04-16 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide
US5138077A (en) * 1991-07-29 1992-08-11 Eastman Kodak Company Selective epoxidation of diolefins and aryl olefins
US6184175B1 (en) * 1993-03-01 2001-02-06 Scientic Design Company, Inc. Process for preparing silver catalyst
US5525740A (en) * 1993-03-01 1996-06-11 Scientific Design Company, Inc. Process for preparing silver catalyst and process of using same to produce ethylene oxide
US5504052A (en) * 1994-12-02 1996-04-02 Scientific Design Company, Inc. Silver catalyst preparation
US5602070A (en) * 1995-01-09 1997-02-11 Scientific Design Company, Inc. Process for preparing silver catalyst
US5908942A (en) * 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
DE69919425T2 (de) * 1998-02-20 2005-09-08 Nippon Shokubai Co. Ltd. Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid
US6455713B1 (en) * 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
DE69924453T2 (de) * 1998-11-17 2006-02-16 Nippon Shokubai Co., Ltd. Katalysatorträger zur Verwendung in der Herstellung von Ethylenoxid
US6172245B1 (en) 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
DE60109704D1 (de) 2000-10-25 2005-05-04 Mitsubishi Chem Corp Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
US6388106B1 (en) 2001-05-24 2002-05-14 Eastman Chemical Company Selective epoxidation of conjugated diolefins
EP1354626B1 (en) * 2002-04-04 2005-07-13 Nippon Shokubai Co., Ltd. Alumina-silica supported silver catalyst and use thereof in the production of epoxide
BR0312244B1 (pt) * 2002-06-28 2013-06-25 mÉtodo para melhorar a seletividade de um catalisador e um processo para a epoxidaÇço de uma olefina
RU2005102097A (ru) * 2002-06-28 2005-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
CN101410178A (zh) * 2006-02-03 2009-04-15 国际壳牌研究有限公司 催化剂的处理方法，催化剂和催化剂的用途
CA2685512C (en) 2007-05-09 2016-12-06 Shell Internationale Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
KR101629038B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
WO2009137427A2 (en) 2008-05-07 2009-11-12 Shell Oil Company A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
CN102177145B (zh) * 2008-10-08 2014-07-30 巴斯夫欧洲公司 生产烯化氧的方法
CN102459211B (zh) 2009-06-09 2014-11-26 巴斯夫欧洲公司 结构化催化剂床在制备环氧乙烷中的用途
US8921587B2 (en) 2011-04-14 2014-12-30 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US9079154B2 (en) 2012-05-04 2015-07-14 Basf Se Catalyst for the epoxidation of alkenes
KR20150013704A (ko) 2012-05-04 2015-02-05 바스프 에스이 알켄의 에폭시화용 촉매
US9714227B2 (en) 2013-12-09 2017-07-25 Basf Se Catalyst for the epoxidation of alkenes
JP6425839B2 (ja) * 2016-05-12 2018-11-21 Ｇｒｏｏｖｅ Ｘ株式会社 緊急停止機能を有する自律行動型ロボット
WO2018029189A1 (en) 2016-08-08 2018-02-15 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide
US11801493B2 (en) 2016-12-02 2023-10-31 Shell Usa, Inc. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4012425A (en) * 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
GB1574426A (en) * 1976-03-25 1980-09-10 Shell Int Research Process for preparing modified silver catalysts
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
DE2640540C3 (de) * 1976-09-09 1988-07-28 Basf Ag, 6700 Ludwigshafen Katalysator zur Herstellung von Äthylenoxid
US4066575A (en) * 1976-07-26 1978-01-03 Halcon International, Inc. Process for the preparation of a supported silver catalyst
JPS5929293B2 (ja) * 1977-07-01 1984-07-19 株式会社日本触媒 酸化エチレン製造用銀担持触媒の製造方法
US4169099A (en) * 1978-05-25 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing ethylene oxide
US4267073A (en) * 1978-06-19 1981-05-12 Shell Oil Company Ethylene oxide catalyst

Also Published As

Publication number Publication date
JPS57107240A (en) 1982-07-03
US4389338A (en) 1983-06-21
FR2497803A1 (fr) 1982-07-16
DE3150205A1 (de) 1982-08-05
SE451182B (sv) 1987-09-14
FR2497803B1 (fr) 1985-07-26
JPS6155416B2 (enExample) 1986-11-27
CA1165311A (en) 1984-04-10
SE8107695L (sv) 1982-06-27
BE891602A (fr) 1982-04-16

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
D2 Grant after examination
8364 No opposition during term of opposition