DE3137534A1 - Verfahren zur herstellung von zuckersirup und von daraus stammenden produkten aus pflanzlichen cellulose-substraten - Google Patents
Verfahren zur herstellung von zuckersirup und von daraus stammenden produkten aus pflanzlichen cellulose-substratenInfo
- Publication number
- DE3137534A1 DE3137534A1 DE19813137534 DE3137534A DE3137534A1 DE 3137534 A1 DE3137534 A1 DE 3137534A1 DE 19813137534 DE19813137534 DE 19813137534 DE 3137534 A DE3137534 A DE 3137534A DE 3137534 A1 DE3137534 A1 DE 3137534A1
- Authority
- DE
- Germany
- Prior art keywords
- acid
- vegetable
- phosphoric acid
- conditions
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 23
- 239000001913 cellulose Substances 0.000 title claims description 12
- 229920002678 cellulose Polymers 0.000 title claims description 12
- 239000000758 substrate Substances 0.000 title claims description 12
- 235000013311 vegetables Nutrition 0.000 title claims description 12
- 235000020374 simple syrup Nutrition 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 52
- 235000000346 sugar Nutrition 0.000 claims description 37
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 36
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 36
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 25
- 150000008163 sugars Chemical class 0.000 claims description 24
- 230000007071 enzymatic hydrolysis Effects 0.000 claims description 19
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 15
- 239000010902 straw Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 238000000855 fermentation Methods 0.000 claims description 13
- 230000004151 fermentation Effects 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 4
- 235000005822 corn Nutrition 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 230000003301 hydrolyzing effect Effects 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 239000011260 aqueous acid Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 8
- 239000008103 glucose Substances 0.000 description 8
- 150000002972 pentoses Chemical class 0.000 description 8
- 108010059892 Cellulase Proteins 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000002255 enzymatic effect Effects 0.000 description 7
- 229940088598 enzyme Drugs 0.000 description 7
- 229940106157 cellulase Drugs 0.000 description 6
- 239000003337 fertilizer Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920002488 Hemicellulose Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 238000005903 acid hydrolysis reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000020357 syrup Nutrition 0.000 description 3
- 239000006188 syrup Substances 0.000 description 3
- 241000193401 Clostridium acetobutylicum Species 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229960002685 biotin Drugs 0.000 description 2
- 235000020958 biotin Nutrition 0.000 description 2
- 239000011616 biotin Substances 0.000 description 2
- 229940041514 candida albicans extract Drugs 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000012138 yeast extract Substances 0.000 description 2
- DILISPNYIVRDBP-UHFFFAOYSA-N 2-[3-[2-(2-hydroxypropylamino)pyrimidin-4-yl]-2-naphthalen-2-ylimidazol-4-yl]acetonitrile Chemical compound OC(CNC1=NC=CC(=N1)N1C(=NC=C1CC#N)C1=CC2=CC=CC=C2C=C1)C DILISPNYIVRDBP-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000235646 Cyberlindnera jadinii Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 239000008351 acetate buffer Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000010564 aerobic fermentation Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 235000019728 animal nutrition Nutrition 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000010364 biochemical engineering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001461 cytolytic effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000020774 essential nutrients Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
- C12N1/22—Processes using, or culture media containing, cellulose or hydrolysates thereof
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/14—Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
- C12P7/26—Ketones
- C12P7/28—Acetone-containing products
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Genetics & Genomics (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Medicine (AREA)
- Medicinal Chemistry (AREA)
- Tropical Medicine & Parasitology (AREA)
- Virology (AREA)
- Biomedical Technology (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8020657A FR2490677A1 (fr) | 1980-09-25 | 1980-09-25 | Procede de preparation de jus sucres et de produits derives a partir de substrats vegetaux cellulosiques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3137534A1 true DE3137534A1 (de) | 1982-06-16 |
Family
ID=9246300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813137534 Withdrawn DE3137534A1 (de) | 1980-09-25 | 1981-09-22 | Verfahren zur herstellung von zuckersirup und von daraus stammenden produkten aus pflanzlichen cellulose-substraten |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4378432A (enExample) |
| DE (1) | DE3137534A1 (enExample) |
| ES (1) | ES8206627A1 (enExample) |
| FR (1) | FR2490677A1 (enExample) |
| IT (1) | IT1139456B (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2586429B1 (fr) * | 1985-08-26 | 1989-02-17 | Inst Francais Du Petrole | Procede de production d'acetone et de butanol a partir de composes lignocellulosiques |
| EP0344371A1 (en) * | 1988-05-31 | 1989-12-06 | Uop Inc. | Hydrolysis of corn kernel hulls to monosaccharides |
| US4859474A (en) * | 1987-09-28 | 1989-08-22 | Nabisco/Cetus Food Biotechnology Research Partnership | Method of making an enzyme sweetened cereal product |
| US4857339A (en) * | 1987-09-28 | 1989-08-15 | Nabisco/Cetus Food Biotechnology Research Partnership | Method for making cereal products naturally sweetened with fructose |
| US4834988A (en) * | 1987-09-28 | 1989-05-30 | Nabisco Brands, Inc. | Method for preparing a cereal |
| WO1994008027A1 (en) * | 1992-09-28 | 1994-04-14 | Midwest Research Institute | Fermentation of cellulose and hemicellulose in corn fiber and distillers dried grains with solubles to ethanol |
| WO2011057444A1 (zh) * | 2009-11-13 | 2011-05-19 | 淮北中润生物能源技术开发有限公司 | 纤维素生物质生产人造粮食的方法 |
| CN114540430A (zh) * | 2022-03-23 | 2022-05-27 | 清华大学 | 棕榈空果串的处理方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1007264A (fr) * | 1948-03-12 | 1952-05-05 | Traitement de produits végétaux à haute pression, production de sucres, furfurol, extraits tanniques et aliments pour bétail | |
| US3642580A (en) * | 1970-01-08 | 1972-02-15 | Us Army | Enzymatic saccharification of cellulose |
| US4058411A (en) * | 1976-08-30 | 1977-11-15 | General Electric Company | Decrystallization of cellulose |
| US4201596A (en) * | 1979-01-12 | 1980-05-06 | American Can Company | Continuous process for cellulose saccharification |
| US4342831A (en) * | 1979-07-02 | 1982-08-03 | American Can Company | Fermentable acid hydrolyzates and fermentation process |
-
1980
- 1980-09-25 FR FR8020657A patent/FR2490677A1/fr active Granted
-
1981
- 1981-09-21 IT IT24055/81A patent/IT1139456B/it active
- 1981-09-22 DE DE19813137534 patent/DE3137534A1/de not_active Withdrawn
- 1981-09-24 ES ES505761A patent/ES8206627A1/es not_active Expired
- 1981-09-25 US US06/305,767 patent/US4378432A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES505761A0 (es) | 1982-08-16 |
| ES8206627A1 (es) | 1982-08-16 |
| US4378432A (en) | 1983-03-29 |
| IT1139456B (it) | 1986-09-24 |
| FR2490677B1 (enExample) | 1983-11-18 |
| IT8124055A0 (it) | 1981-09-21 |
| FR2490677A1 (fr) | 1982-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69026499T2 (de) | Verfahren zur herstellung von xylitol aus xylose enthaltenden gemischen | |
| DE69803145T2 (de) | Verbessertes Vorbehandlungs-Verfahren für die Umwandlung von Cellulose in Kraftstoff-Ethanol | |
| DE60217303T2 (de) | Methode zur behandlung von lignin- und zellulosehaltigen beschickungen zur erhöhten produktion von xylose und ethanol | |
| DE2808932A1 (de) | Herstellung von aethanol aus cellulose | |
| DE2541960B2 (de) | Herstellung von Alkohol aus Cellulose | |
| DE2943684A1 (de) | Verfahren zur enzymwiederverwertung | |
| EP0144017B1 (de) | Verfahren zur biotechnologischen Herstellung von Poly-D(-)-3-hydroxybuttersäure | |
| DE3882655T2 (de) | Verfahren zur Herstellung von L-Rhamnose. | |
| DE2712007C2 (enExample) | ||
| DE69221841T2 (de) | Verfahren zur Herstellung von gereinigtem Xanthangummi | |
| DE3137534A1 (de) | Verfahren zur herstellung von zuckersirup und von daraus stammenden produkten aus pflanzlichen cellulose-substraten | |
| DE69116192T2 (de) | Für die Polysaccharidhydrolyse aus einem lignozellulosehaltigen Substrat geeignete Enzymzusammensetzung, ihre Herstellung und Verwendung | |
| DE3418374A1 (de) | Verfahren zur herstellung von cyclopropancarbonsaeuren | |
| DE3443204A1 (de) | Biochemisches verfahren und zusammensetzung | |
| DE2444990A1 (de) | Verfahren zur herabsetzung des nucleinsaeuregehalts von proteinhaltigen materialien | |
| DE69019396T2 (de) | Verfahren zur fermentativen Oxydation reduzierender Disaccharide. | |
| DE2631473A1 (de) | Verfahren zur herstellung eines fermentationsmediums und zur produktion von hefe auf diesem fuer den tierischen bedarf | |
| DE1567323A1 (de) | Verfahren zur Umwandlung von Glucose in Fructose | |
| DE2631047C3 (de) | Verfahren zum Herstellen von biologischen Proteinen Mikroorganismen der Art Prototheca | |
| DE2003981C3 (de) | Verfahren zur Herstellung von Hefeextrakt durch Abbau der Hefen mit zeitsparenden Enzymen von Mikroorganismen | |
| AT392799B (de) | Verfahren zur fermentativen herstellung von zitronensaeure aus kohlehydraten | |
| DE3025098C2 (de) | Vorbehandeln von aus Lignozellulosematerialien gewonnenen Hydrolysaten | |
| DE2704212A1 (de) | Verfahren zur herstellung von l-methionin | |
| DE2408752C2 (de) | Verfahren zur Gewinnung von Cholesterin und Cholesterinestern aus Rückständen der Fettverarbeitung | |
| DE2357345A1 (de) | Verfahren zur biotechnischen herstellung von hefe und deren verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |