DE3122546C2 - - Google Patents
Info
- Publication number
- DE3122546C2 DE3122546C2 DE3122546A DE3122546A DE3122546C2 DE 3122546 C2 DE3122546 C2 DE 3122546C2 DE 3122546 A DE3122546 A DE 3122546A DE 3122546 A DE3122546 A DE 3122546A DE 3122546 C2 DE3122546 C2 DE 3122546C2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- mixture
- layer
- gold
- precious metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 23
- 239000010931 gold Substances 0.000 claims description 23
- 229910052737 gold Inorganic materials 0.000 claims description 23
- 239000010410 layer Substances 0.000 claims description 20
- 239000010970 precious metal Substances 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 238000005034 decoration Methods 0.000 claims description 14
- 239000000919 ceramic Substances 0.000 claims description 13
- 239000011247 coating layer Substances 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229920000180 alkyd Polymers 0.000 claims description 6
- 238000007650 screen-printing Methods 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000002320 enamel (paints) Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 8
- 239000011241 protective layer Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 229940111120 gold preparations Drugs 0.000 description 3
- 238000010304 firing Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/12—Transfer pictures or the like, e.g. decalcomanias
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/175—Transfer using solvent
- B44C1/1752—Decalcomanias provided with a particular decorative layer, e.g. being specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
Landscapes
- Decoration By Transfer Pictures (AREA)
- Printing Methods (AREA)
- Developing Agents For Electrophotography (AREA)
Description
Die Erfindung betrifft die Verwendung einer Mischung für ein einen Träger, eine Bildschicht aus einem Glanzedelmetall-Präparat, eine Schutzschicht und eine Überzugsschicht aufweisendes keramisches Abziehbild.The invention relates to the use of a mixture for a carrier, an image layer made of a shiny precious metal preparation, a protective layer and a ceramic decal having a coating layer.
Für die Herstellung von auf Keramik oder Porzellan eingebrannten Edel metall-Dekorationen werden Glanzedelmetallpräparate, zum Beispiel Glanzgold, Glanzplatin und Glanzpalladium, Polieredelmetallpräparate, zum Beispiel Poliergold, und Edelmetalle in Puderform, zum Beispiel Pudergold, verwendet.For the production of precious baked on ceramics or porcelain metal decorations become shiny precious metal preparations, for example shiny gold, Gloss platinum and gloss palladium, polished precious metal preparations, for example Polished gold, and precious metals in powder form, for example powder gold, are used.
Zum Übertragen der Edelmetallmuster werden häufig Abziehbilder benutzt, deren Bildschicht sowohl aus Glanz- und Polieredelmetallpräparaten als auch aus Edelmetallen in Puderform bestehen kann.Decals are often used to transfer the precious metal samples Image layer made of shiny and polished precious metal preparations as well Precious metals can exist in powder form.
In der deutschen Patentschrift 12 32 168 wird ein Abziehbild für Golddekors aus einem gummierten Papier als Träger, einer Bildschicht aus goldhaltiger Zusammensetzung, einer Schutzschicht aus ein Alkyd-, Phenol-, Harnstoff- oder Epoxidharz, ein trocknendes oder halbtrocknendes Öl enthaltendem Material und einer Überzugsschicht beschrieben. Die goldhaltige Schicht kann aus jedem ge eigneten handelsüblichen "Flüssig-Gold"-Präparat bestehen.In the German patent specification 12 32 168 there is a decal for gold decorations from a rubberized paper as a support, a picture layer from gold-containing Composition, a protective layer of an alkyd, phenol, or urea Epoxy resin, a material containing drying or semi-drying oil and described a coating layer. The gold-containing layer can be from any ge suitable commercial "liquid gold" preparation exist.
Glanzgoldpräparate enthalten 6 bis 20 Gewichts-% Gold in Form des Sulfo resinats und ergeben nach dem Brennen bei 500 bis 900°C hochglänzende Dekora tionen. Bright gold preparations contain 6 to 20% by weight of gold in the form of the sulfo resinats and produce high-gloss decorations after firing at 500 to 900 ° C ions.
Das Poliergold, auch als Mattgold bezeichnet, enthält 15 bis 60 Gewichts-% Gold. Daraus erhaltene Dekorationen erscheinen nach dem Brand matt; nachträgliches Polieren verleiht ihnen ein feines, seidenmattes Aussehen.The polished gold, also known as matt gold, contains 15 to 60 % By weight gold. Decorations obtained from this appear matt after the fire; subsequent polishing gives them a fine, silky matt appearance.
Die aufgrund ihres hohen Gold-Gehaltes kostbarsten Goldpräparate, die Puder golde, führen zu massivgoldenen Dekorationen mit feinem, mattem Aussehen.The most precious gold preparations due to their high gold content, the powder gold, lead to solid gold decorations with a fine, matt appearance.
Um auch mit Hilfe der Glanzgoldpräparate matte Gold-Dekorationen erzielen zu können, ist es bekannt, auf die in einem ersten Brand erzeugten glänzenden Gold-Muster in einem zweiten Brand eine halbtransparente beziehungsweise matte Glasur aufzubringen.In order to achieve matt gold decorations with the help of shiny gold preparations too can, it is known, on the shiny produced in a first fire Gold pattern in a second brand a semi-transparent or matte Apply glaze.
Eine andere Möglichkeit besteht in dem Aufbringen einer sogenannten Mattfarbe auf die Keramik beziehungsweise das Porzellan, auf die nach dem Brennen das Glanzedelmetallpräparat aufgetragen und ebenfalls gebrannt wird.Another possibility is to apply a so-called matt color on the ceramics or porcelain, on which after firing Bright precious metal preparation is applied and also fired.
Es ist die Aufgabe der Erfindung, ein einen Träger, eine Bildschicht aus einem Glanzedelmetallpräparat, eine Schutzschicht und eine Überzugsschicht aufwei sendes keramisches Abziehbild zu schaffen, mit dessen Hilfe durch einmaligen Brand eine matte Edelmetall-Dekoration erzielt wird.It is the object of the invention, a carrier, an image layer from a Glossy precious metal preparation, a protective layer and a coating layer sending ceramic decal, with the help of unique Brand a matt precious metal decoration is achieved.
Die Aufgabe wird erfindungsgemäß durch die Verwendung einer Mischung ausThe object is achieved by using a mixture of
-
a) 65 Gewichts-% einer Mischung aus 50 Gewichts-% Bleiborsilicat-Glasur
fritte und 50 Gewichts-% eines Gemisches aus 65 Gewichts-% Zinn
dioxid, 23 Gewichts-% Zinkoxid, 6 Gewichts-% Aluminiumoxid und 6
Gewichts-% Eisenoxid und Chromoxid
unda) 65% by weight of a mixture of 50% by weight of lead borosilicate glaze and 50% by weight of a mixture of 65% by weight of tin dioxide, 23% by weight of zinc oxide, 6% by weight of aluminum oxide and 6% by weight of iron oxide and Chromium oxide
and - b) 35 Gewichts-% einer Mischung aus 60 Gewichts-% langöligem Alkydharz, 30 Gewichts-% Kohlenwasserstoff-Verdünnungsmittel und 10 Gewichts-% Siebdruckölb) 35% by weight of a mixture of 60% by weight of long oil alkyd resin, 30% by weight hydrocarbon diluent and 10% by weight Screen printing oil
zum Aufdrucken im Siebdruckverfahren einer Unterlageschicht auf den Träger des keramischen Abziehbildes gelöst.for printing in the screen printing process of a base layer on the carrier of the ceramic decal solved.
Vorteilhafte Ausführungsformen der Verwendung gemäß Anspruch 1 sind in den Ansprüchen 2 und 3 angegeben.Advantageous embodiments of the use according to claim 1 are in the Claims 2 and 3 indicated.
Alkydharze mit einem Ölgehalt von 60 bis 70% werden auch als langölige Alkyd harze bezeichnet (Ullmanns Encyklopädie der technischen Chemie Band 19, 1980, Seite 76).Alkyd resins with an oil content of 60 to 70% are also called long oil alkyds referred to as resins (Ullmann's Encyclopedia of Technical Chemistry Volume 19, 1980, Page 76).
"Kohlenwasserstoff-Verdünnungsmittel" und "Siebdrucköle" sind Materialien, die im Handel erhältlich und für den Einsatz auf dem Gebiet der keramischen Farben und der Druckfarben bestimmt sind. "Hydrocarbon thinners" and "screen printing oils" are materials that commercially available and for use in the field of ceramic paints and the printing inks are determined.
Zur Herstellung der Bildschicht eignet sich jedes keramische Glanzedelmetall präparat, das befriedigende Drucke ergibt. Besonders bewährt haben sich Glanzgold-, zum Beispiel Citrongold-, Glanzpalladium- und Glanzplatin präparate.Any shiny ceramic precious metal is suitable for producing the image layer preparation that gives satisfactory prints. Have proven themselves Gloss gold, for example lemon gold, gloss palladium and gloss platinum preparations.
Als Träger dient jedes für keramische Abziehbilder bestimmte gummierte Papier.Each gummed paper intended for ceramic decals serves as a carrier.
Die Schutzschicht ist günstiger Weise entsprechend der in der deutschen Patent schrift 12 32 168 beschriebenen zusammengesetzt.The protective layer is favorably according to that in the German patent Scripture 12 32 168 composed.
Die Überzugsschicht kann aus jedem für diesen Zweck geeigneten Material be stehen. Günstigerweise wird ein Material auf Polyacrylat- beziehungsweise Poly methacrylat-Basis verwendet (siehe deutsche Patentschrift 12 32 168).The coating layer can be made of any material suitable for this purpose stand. A material is favorably made of polyacrylate or poly methacrylate base used (see German Patent 12 32 168).
Die Herstellung des keramischen Abziehbildes für matte Edelmetall-Dekorationen
unter Verwendung der vorgenannten
Mischung wird nun näher beschrieben.The production of the ceramic decal for matt precious metal decorations using the aforementioned
Mixing will now be described in more detail.
Unter Verwendung der Mischung ausUsing the mixture of
-
a) 65 Gewichts-% einer Mischung aus 50 Gewichts-% Bleiborsilicat-Glasur
fritte und 50 Gewichts-% eines Gemisches aus 65 Gewichts-% Zinn
dioxid, 23 Gewichts-% Zinkoxid, 6 Gewichts-% Aluminiumoxid und 6
Gewichts-% Eisenoxid und Chromoxid
unda) 65% by weight of a mixture of 50% by weight of lead borosilicate glaze and 50% by weight of a mixture of 65% by weight of tin dioxide, 23% by weight of zinc oxide, 6% by weight of aluminum oxide and 6% by weight of iron oxide and Chromium oxide
and - b) 35 Gewichts-% einer Mischung aus 60 Gewichts-% langöligem Alkydharz, 30 Gewichts-% Kohlenwasserstoff-Verdünnungsmittel und 10 Gewichts-% Siebdruckölb) 35% by weight of a mixture of 60% by weight of long oil alkyd resin, 30% by weight hydrocarbon diluent and 10% by weight Screen printing oil
wird auf einen Träger aus gummiertem Papier die Unterlageschicht im Siebdruck verfahren aufgedruckt.the base layer is screen-printed on a carrier made of rubberized paper procedure printed.
Die Unterlageschicht kann sowohl flach als auch reliefartig sein.The base layer can be both flat and relief-like.
Nach dem Antrocknen wird, ebenfalls im Siebdruckverfahren, das Glanzedel metallpräparat, zum Beispiel eine Glanzgoldpaste mit einem Gold-Gehalt von 12 Gewichts-%, auf die Unterlageschicht aufgetragen. Ist das Präparat ange trocknet, wird die Schutzschicht und anschließend die Überzugsschicht aufge druckt.After drying, the glossy noble is also screen printed metal preparation, for example a shiny gold paste with a gold content of 12% by weight, applied to the base layer. Is the preparation attached? dries, the protective layer and then the coating layer is applied prints.
In der Fig. 1 ist ein so hergestelltes Abziehbild aus dem Träger 1, der Unterlageschicht 2, der aus dem Glanzedelmetallpräparat bestehenden Bild schicht 3, der Schutzschicht 4 und der Überzugsschicht 5 dargestellt.In Fig. 1 is a so prepared decal from the carrier 1, the underlayer 2, the group consisting of the bright precious metal preparation image layer 3, the protective layer 4 and the coating layer 5 shown.
Es ist auch möglich, eine zusätz lich noch ein keramisches Schmelzfarbenpräparat enthaltende Bildschicht aufzudrucken.It is also possible to add one Lich to print an image layer containing ceramic enamel paint preparation.
In der Fig. 2 ist ein so erhaltenes Abziehbild aus dem Träger 1, der Unter lageschicht 2, der aus dem Glanzedelmetallpräparat E und dem keramischen Schmelzfarbenpräparat K bestehenden Bildschicht 3, der Schutzschicht 4 und der Überzugsschicht 5 dargestellt. In FIG. 2 a thus obtained decal from the carrier 1, the lower the group consisting of the bright precious metal preparation E and the ceramic enamels preparation K image layer 3, the protective layer 4 and the coating layer 5 is clad layer 2, is shown.
Die mit dem unter Verwendung der vorgenannten Mischung für die Unter lageschicht hergestellten Abziehbild erzeugten Edelmetall-Dekorationen weisen nach dem Brand eine feine, matte Oberfläche auf. Die Gold-Dekorationen besitzen das den Pudergold-Dekorationen eigene Aussehen und sind bei relief artig gestalteter Unterlageschicht zusätzlich reliefartig verziert.The one with the using the above mixture for the sub layered decal produced precious metal decorations exhibit after the fire a fine, matt surface. The gold decorations have the look of powder gold decorations and are in relief well-designed base layer additionally decorated in relief.
Es ist auch möglich, sowohl aus matten als auch aus glänzenden Bereichen be stehende Edelmetall-Dekorationen zu erzeugen. Dazu wird die Unterlageschicht in der Weise aufgedruckt, daß die Bereiche des Trägers, die den später glänzenden Bereichen der Dekoration entsprechen, ausgespart bleiben.It is also possible to be made of both matt and glossy areas to produce standing precious metal decorations. This is the backing layer printed in such a way that the areas of the carrier that the later correspond to glossy areas of the decoration, remain spared.
1 1
Claims (4)
- a) 65 Gewichts-% einer Mischung aus 50 Gewichts-% Bleiborsilicat-Glasur
fritte und 50 Gewichts-% eines Gemisches aus 65 Gewichts-% Zinn
dioxid, 23 Gewichts-% Zinkoxid, 6 Gewichts-% Aluminiumoxid und 6
Gewichts-% Eisenoxid und Chromoxid
und - b) 35 Gewichts-% einer Mischung aus 60 Gewichts-% langöligem Alkydharz, 30 Gewichts-% Kohlenwasserstoff-Verdünnungsmittel und 10 Gewichts-% Siebdrucköl
- a) 65% by weight of a mixture of 50% by weight of lead borosilicate glaze and 50% by weight of a mixture of 65% by weight of tin dioxide, 23% by weight of zinc oxide, 6% by weight of aluminum oxide and 6% by weight of iron oxide and Chromium oxide
and - b) 35% by weight of a mixture of 60% by weight of long oil alkyd resin, 30% by weight of hydrocarbon diluent and 10% by weight of screen printing oil
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813122546 DE3122546A1 (en) | 1981-06-06 | 1981-06-06 | "CERAMIC DECAL FOR THE PRODUCTION OF MATS PRECIOUS METAL DECORATIONS" |
| GB8215853A GB2099760B (en) | 1981-06-06 | 1982-06-01 | Decalcomanias |
| IT48586/82A IT1148316B (en) | 1981-06-06 | 1982-06-04 | IMAGE AT CECALCOMANIA CERAMIC FOR THE PRODUCTION OF OPAQUE DECORATIONS OF NOBLE METALS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813122546 DE3122546A1 (en) | 1981-06-06 | 1981-06-06 | "CERAMIC DECAL FOR THE PRODUCTION OF MATS PRECIOUS METAL DECORATIONS" |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3122546A1 DE3122546A1 (en) | 1982-12-23 |
| DE3122546C2 true DE3122546C2 (en) | 1988-01-28 |
Family
ID=6134091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813122546 Granted DE3122546A1 (en) | 1981-06-06 | 1981-06-06 | "CERAMIC DECAL FOR THE PRODUCTION OF MATS PRECIOUS METAL DECORATIONS" |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE3122546A1 (en) |
| GB (1) | GB2099760B (en) |
| IT (1) | IT1148316B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4213041C1 (en) * | 1992-04-21 | 1993-06-09 | W.C. Heraeus Gmbh, 6450 Hanau, De | |
| DE19831141A1 (en) * | 1998-07-11 | 2000-01-27 | Cerdec Ag | Precious metal preparation and its use for the production of precious metal decorations by direct and indirect printing |
| EP1808424A2 (en) | 2006-01-17 | 2007-07-18 | Duravit Ag | Method for manufacturing a ceramic or porcelain article coated with a noble metal layer and article produced by the method |
| WO2012059088A2 (en) | 2010-11-02 | 2012-05-10 | Khwan-Khung Lim | Ceramic hot melt paint composition for producing burned-in decorative designs, method for producing same, and method for producing a decorative coating |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3524912C1 (en) * | 1985-07-12 | 1986-11-13 | Degussa Ag, 6000 Frankfurt | Process for the production of scratch and abrasion resistant precious metal decorations |
| DE3611273C1 (en) * | 1986-04-04 | 1987-06-19 | Degussa | Process for the production of matt precious metal decorations |
| DE4007156C1 (en) * | 1990-03-07 | 1991-09-26 | W.C. Heraeus Gmbh, 6450 Hanau, De | |
| DE4122131C1 (en) * | 1991-07-04 | 1992-07-16 | W.C. Heraeus Gmbh, 6450 Hanau, De | Gold@ prepn., for decoration of glass and ceramics - comprise adding e.g. gold mercaptide deriv. to hot soln. of polyethylene@ wax in non-polar solvent |
| FR2716099B1 (en) * | 1994-02-11 | 1996-04-19 | Deshoulieres F | Method for manufacturing a culinary container which can be heated by induction and container obtained by this method. |
| CN1061017C (en) * | 1997-12-06 | 2001-01-24 | 张淑德 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
| EP0950509A1 (en) * | 1998-02-20 | 1999-10-20 | F. XAVER LEIPOLD GMBH & CO. KG | A multilayer for coating preferably a transparent substrate |
| DE10050949A1 (en) | 2000-10-13 | 2002-04-18 | Dmc2 Degussa Metals Catalysts | Precious metal preparation and its use for the production of precious metal decorations by direct and indirect printing |
| DE102005018672B4 (en) * | 2005-04-21 | 2010-07-15 | W.C. Heraeus Gmbh | Process for the preparation of Ätimimitationen on silicate substrates and use of a medium adapted for this purpose |
| CN113635687A (en) * | 2021-08-17 | 2021-11-12 | 重庆隆发皮革制品有限责任公司 | Gold stamping processing method for cow leather mat |
-
1981
- 1981-06-06 DE DE19813122546 patent/DE3122546A1/en active Granted
-
1982
- 1982-06-01 GB GB8215853A patent/GB2099760B/en not_active Expired
- 1982-06-04 IT IT48586/82A patent/IT1148316B/en active
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4213041C1 (en) * | 1992-04-21 | 1993-06-09 | W.C. Heraeus Gmbh, 6450 Hanau, De | |
| DE19831141A1 (en) * | 1998-07-11 | 2000-01-27 | Cerdec Ag | Precious metal preparation and its use for the production of precious metal decorations by direct and indirect printing |
| DE19831141C2 (en) * | 1998-07-11 | 2003-02-27 | Dmc2 Degussa Metals Catalysts | Precious metal preparation and its use for the production of precious metal decorations by direct and indirect printing |
| EP1808424A2 (en) | 2006-01-17 | 2007-07-18 | Duravit Ag | Method for manufacturing a ceramic or porcelain article coated with a noble metal layer and article produced by the method |
| DE102006002373A1 (en) * | 2006-01-17 | 2007-07-26 | Duravit Ag | A method of making a ceramic or porcelain article coated with a layer of noble metal and a ceramic or porcelain article coated with such a layer |
| DE102006002373B4 (en) * | 2006-01-17 | 2009-06-18 | Duravit Ag | A method of making a ceramic or porcelain article coated with a layer of noble metal and a ceramic or porcelain article coated with such a layer |
| WO2012059088A2 (en) | 2010-11-02 | 2012-05-10 | Khwan-Khung Lim | Ceramic hot melt paint composition for producing burned-in decorative designs, method for producing same, and method for producing a decorative coating |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2099760B (en) | 1984-12-12 |
| IT1148316B (en) | 1986-12-03 |
| GB2099760A (en) | 1982-12-15 |
| DE3122546A1 (en) | 1982-12-23 |
| IT8248586A0 (en) | 1982-06-04 |
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Owner name: W. C. HERAEUS GMBH & CO. KG, 63450 HANAU, DE |