DE2824870C2 - - Google Patents
Info
- Publication number
- DE2824870C2 DE2824870C2 DE2824870A DE2824870A DE2824870C2 DE 2824870 C2 DE2824870 C2 DE 2824870C2 DE 2824870 A DE2824870 A DE 2824870A DE 2824870 A DE2824870 A DE 2824870A DE 2824870 C2 DE2824870 C2 DE 2824870C2
- Authority
- DE
- Germany
- Prior art keywords
- mol
- dielectric
- doped
- composition
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 31
- 239000010936 titanium Substances 0.000 claims description 28
- 239000003990 capacitor Substances 0.000 claims description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 229910052748 manganese Inorganic materials 0.000 claims description 20
- 239000011572 manganese Substances 0.000 claims description 20
- 238000005245 sintering Methods 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000002019 doping agent Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- 239000000919 ceramic Substances 0.000 description 30
- 239000010410 layer Substances 0.000 description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
- H01G4/1209—Ceramic dielectrics characterised by the ceramic dielectric material
- H01G4/1236—Ceramic dielectrics characterised by the ceramic dielectric material based on zirconium oxides or zirconates
- H01G4/1245—Ceramic dielectrics characterised by the ceramic dielectric material based on zirconium oxides or zirconates containing also titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/49—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/008—Selection of materials
- H01G4/0085—Fried electrodes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Insulating Materials (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Ceramic Capacitors (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782824870 DE2824870A1 (de) | 1978-06-07 | 1978-06-07 | Verfahren zur herstellung eines dielektrikums mit perowskitstruktur |
US06/045,554 US4260663A (en) | 1978-06-07 | 1979-06-04 | Method of producing a dielectric having a perowskite structure |
GB7919389A GB2022569B (en) | 1978-06-07 | 1979-06-04 | Ceramic dielectric |
JP6954479A JPS54159657A (en) | 1978-06-07 | 1979-06-05 | Method of producing dielectric and multiilayer capacitor made of same |
NL7904378A NL7904378A (nl) | 1978-06-07 | 1979-06-05 | Werkwijze voor het vervaardigen van een dieelectricum met perowskietstructuur. |
FR7914455A FR2428312B1 (fr) | 1978-06-07 | 1979-06-06 | Procede pour la realisation d'un dielectrique a structure en perowski |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782824870 DE2824870A1 (de) | 1978-06-07 | 1978-06-07 | Verfahren zur herstellung eines dielektrikums mit perowskitstruktur |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2824870A1 DE2824870A1 (de) | 1979-12-20 |
DE2824870C2 true DE2824870C2 (US07754267-20100713-C00017.png) | 1989-07-27 |
Family
ID=6041192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19782824870 Granted DE2824870A1 (de) | 1978-06-07 | 1978-06-07 | Verfahren zur herstellung eines dielektrikums mit perowskitstruktur |
Country Status (6)
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4419713A (en) * | 1981-07-06 | 1983-12-06 | Centre Engineering, Inc. | Multiple electrode series capacitor |
US4514441A (en) * | 1982-11-17 | 1985-04-30 | International Standard Electric Corporation | Dielectric materials |
JPS59184511A (ja) * | 1983-04-04 | 1984-10-19 | 株式会社村田製作所 | セラミツク積層コンデンサ |
JPS60131708A (ja) * | 1983-12-19 | 1985-07-13 | 株式会社村田製作所 | 非還元性温度補償用誘電体磁器組成物 |
JPS60131707A (ja) * | 1983-12-19 | 1985-07-13 | 株式会社村田製作所 | 非還元性温度補償用誘電体磁器組成物 |
JPS6236806A (ja) * | 1985-08-12 | 1987-02-17 | 日本電信電話株式会社 | 積層磁器コンデンサおよびその製造方法 |
JPH0563168A (ja) * | 1991-08-30 | 1993-03-12 | Sharp Corp | アクテイブマトリクス基板 |
US5387459A (en) * | 1992-12-17 | 1995-02-07 | Eastman Kodak Company | Multilayer structure having an epitaxial metal electrode |
JPH0851103A (ja) * | 1994-08-08 | 1996-02-20 | Fuji Electric Co Ltd | 薄膜の生成方法 |
US5731948A (en) * | 1996-04-04 | 1998-03-24 | Sigma Labs Inc. | High energy density capacitor |
CN108569903B (zh) * | 2018-06-15 | 2020-11-17 | 济南大学 | 一种低温烧结ltcc微波介质陶瓷及制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1153302A (fr) * | 1956-05-11 | 1958-03-05 | Plessey Co Ltd | Matière céramique et son procédé de fabrication |
US3153179A (en) * | 1962-08-17 | 1964-10-13 | Clevite Corp | Ceramic capacitor dielectrics |
US3811937A (en) * | 1967-03-27 | 1974-05-21 | Sprague Electric Co | Low temperature fired electrical components and method of making same |
US4030004A (en) * | 1971-04-16 | 1977-06-14 | Nl Industries, Inc. | Dielectric ceramic matrices with end barriers |
GB1406806A (en) * | 1972-01-04 | 1975-09-17 | Gen Electric Co Ltd | Microwave devices |
GB1521137A (en) * | 1974-11-07 | 1978-08-16 | Tdk Electronics Co Ltd | Ceramic dielectric composition |
US3987347A (en) * | 1975-05-29 | 1976-10-19 | Sprague Electric Company | Temperature stable monolithic ceramic capacitor with base metal electrodes |
US4063341A (en) * | 1975-07-09 | 1977-12-20 | E. I. Du Pont De Nemours And Company | Process for making multilayer capacitors |
US4048546A (en) * | 1975-07-09 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Dielectric powder compositions |
US4056654A (en) * | 1975-07-24 | 1977-11-01 | Kkf Corporation | Coating compositions, processes for depositing the same, and articles resulting therefrom |
US4089038A (en) * | 1976-03-30 | 1978-05-09 | E. I. Du Pont De Nemours And Co. | Dielectric compositions of zirconates and/or aluminates and devices thereof |
JPS5324600A (en) * | 1976-08-19 | 1978-03-07 | Murata Manufacturing Co | Nonnreducing dielectric ceramic composition |
-
1978
- 1978-06-07 DE DE19782824870 patent/DE2824870A1/de active Granted
-
1979
- 1979-06-04 US US06/045,554 patent/US4260663A/en not_active Expired - Lifetime
- 1979-06-04 GB GB7919389A patent/GB2022569B/en not_active Expired
- 1979-06-05 NL NL7904378A patent/NL7904378A/xx not_active Application Discontinuation
- 1979-06-05 JP JP6954479A patent/JPS54159657A/ja active Granted
- 1979-06-06 FR FR7914455A patent/FR2428312B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPH0253937B2 (US07754267-20100713-C00017.png) | 1990-11-20 |
FR2428312A1 (fr) | 1980-01-04 |
DE2824870A1 (de) | 1979-12-20 |
NL7904378A (nl) | 1979-12-11 |
GB2022569B (en) | 1982-09-08 |
US4260663A (en) | 1981-04-07 |
JPS54159657A (en) | 1979-12-17 |
FR2428312B1 (fr) | 1986-06-20 |
GB2022569A (en) | 1979-12-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8110 | Request for examination paragraph 44 | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |