DE2657190C2 - Verfahren zur Reinigung von Naßverfahrensphosphorsäure - Google Patents
Verfahren zur Reinigung von NaßverfahrensphosphorsäureInfo
- Publication number
- DE2657190C2 DE2657190C2 DE2657190A DE2657190A DE2657190C2 DE 2657190 C2 DE2657190 C2 DE 2657190C2 DE 2657190 A DE2657190 A DE 2657190A DE 2657190 A DE2657190 A DE 2657190A DE 2657190 C2 DE2657190 C2 DE 2657190C2
- Authority
- DE
- Germany
- Prior art keywords
- primary
- phosphoric acid
- extract
- solvent
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims description 87
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims description 44
- 238000000034 method Methods 0.000 title claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 239000002904 solvent Substances 0.000 claims description 35
- 239000002253 acid Substances 0.000 claims description 31
- 238000000605 extraction Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 13
- 239000011707 mineral Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 230000009290 primary effect Effects 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 description 35
- 235000010755 mineral Nutrition 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical group 0.000 description 5
- 238000010533 azeotropic distillation Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 4
- 235000012255 calcium oxide Nutrition 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000011877 solvent mixture Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 150000008043 acidic salts Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- JOHZPMXAZQZXHR-UHFFFAOYSA-N pipemidic acid Chemical compound N1=C2N(CC)C=C(C(O)=O)C(=O)C2=CN=C1N1CCNCC1 JOHZPMXAZQZXHR-UHFFFAOYSA-N 0.000 description 1
- 229960001732 pipemidic acid Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (24)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2657190A DE2657190C2 (de) | 1976-12-17 | 1976-12-17 | Verfahren zur Reinigung von Naßverfahrensphosphorsäure |
| CH1116477A CH631418A5 (de) | 1976-12-17 | 1977-09-13 | Herstellung von gereinigten waessrigen phosphorsaeure- oder alkaliphosphatloesungen. |
| ES463603A ES463603A1 (es) | 1976-12-17 | 1977-10-27 | Procedimiento para la purificacion de acido fosforico de procedimiento en humedo. |
| SU772547802A SU888812A3 (ru) | 1976-12-17 | 1977-11-30 | Способ очистки экстракционной фосфорной кислоты |
| NLAANVRAGE7713608,A NL184945C (nl) | 1976-12-17 | 1977-12-08 | Werkwijze voor het zuiveren van langs de natte weg bereid fosforzuur. |
| GB51348/77A GB1554379A (en) | 1976-12-17 | 1977-12-09 | Decontamination of wet-processed phosphoric acid |
| US05/859,879 US4200620A (en) | 1976-12-17 | 1977-12-12 | Decontamination of wet-processed phosphoric acid |
| TR19331A TR19331A (tr) | 1976-12-17 | 1977-12-13 | Islak usulle elde edilmis fosforik asidi-n aritilmasina mahsus usul |
| PH20552A PH14335A (en) | 1976-12-17 | 1977-12-14 | Decontamination of wet-processed phosphoric acid |
| EG69277A EG13800A (en) | 1976-12-17 | 1977-12-14 | Decontamination of wet-processed phosphoric acid |
| IT52200/77A IT1090568B (it) | 1976-12-17 | 1977-12-14 | Procedimento ed impianto per depurare acido fosforico di processo ad umido |
| ZA00777470A ZA777470B (en) | 1976-12-17 | 1977-12-15 | Decontamination of wet-processed phosphoric acid |
| DD77202670A DD136258A5 (de) | 1976-12-17 | 1977-12-15 | Verfahren zur reinigung von nassverfahrensphosphorsaeure |
| MX171732A MX146999A (es) | 1976-12-17 | 1977-12-15 | Proceso mejorado para purificar acido fosforico procesado en humedo |
| FI773803A FI65610C (fi) | 1976-12-17 | 1977-12-15 | Foerfarande foer rening av vaotfoerfarande-fosforsyra |
| IL53618A IL53618A0 (en) | 1976-12-17 | 1977-12-15 | Decontamination of wet processed phosphoric acid |
| SE7714259A SE429752B (sv) | 1976-12-17 | 1977-12-15 | Sett for rening av vatframstelld fosforsyra |
| AT898277A AT354978B (de) | 1976-12-17 | 1977-12-15 | Verfahren zur reinigung von nassverfahrens- phosphorsaeure |
| CA293,219A CA1084238A (en) | 1976-12-17 | 1977-12-16 | Decontamination of wet-processed phosphoric acid |
| BR7708375A BR7708375A (pt) | 1976-12-17 | 1977-12-16 | Processo para a purificacao de acido fosforico obtido por via umida |
| FR7738057A FR2374263A1 (fr) | 1976-12-17 | 1977-12-16 | Procede de purification de l'acide phosphorique prepare par voie humide |
| BE183509A BE861920A (fr) | 1976-12-17 | 1977-12-16 | Procede de purification de l'acide phosphorique prepare par voie humide |
| DK562677A DK149229C (da) | 1976-12-17 | 1977-12-16 | Fremgangsmaade til rensning af phosphorsyre fremstillet ved vaadfremgangsmaaden |
| JP15231677A JPS5383993A (en) | 1976-12-17 | 1977-12-16 | Method of purifying wet phosphoric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2657190A DE2657190C2 (de) | 1976-12-17 | 1976-12-17 | Verfahren zur Reinigung von Naßverfahrensphosphorsäure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2657190A1 DE2657190A1 (de) | 1978-06-22 |
| DE2657190C2 true DE2657190C2 (de) | 1982-11-04 |
Family
ID=5995770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2657190A Expired DE2657190C2 (de) | 1976-12-17 | 1976-12-17 | Verfahren zur Reinigung von Naßverfahrensphosphorsäure |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US4200620A (show.php) |
| JP (1) | JPS5383993A (show.php) |
| AT (1) | AT354978B (show.php) |
| BE (1) | BE861920A (show.php) |
| BR (1) | BR7708375A (show.php) |
| CA (1) | CA1084238A (show.php) |
| CH (1) | CH631418A5 (show.php) |
| DD (1) | DD136258A5 (show.php) |
| DE (1) | DE2657190C2 (show.php) |
| DK (1) | DK149229C (show.php) |
| ES (1) | ES463603A1 (show.php) |
| FI (1) | FI65610C (show.php) |
| FR (1) | FR2374263A1 (show.php) |
| GB (1) | GB1554379A (show.php) |
| IL (1) | IL53618A0 (show.php) |
| IT (1) | IT1090568B (show.php) |
| MX (1) | MX146999A (show.php) |
| NL (1) | NL184945C (show.php) |
| PH (1) | PH14335A (show.php) |
| SE (1) | SE429752B (show.php) |
| SU (1) | SU888812A3 (show.php) |
| TR (1) | TR19331A (show.php) |
| ZA (1) | ZA777470B (show.php) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4197280A (en) * | 1978-10-02 | 1980-04-08 | Stauffer Chemical Company | Wet process phosphoric acid purification |
| DE2909572A1 (de) * | 1979-03-12 | 1980-09-25 | Hoechst Ag | Verfahren zur ueberfuehrung von extraktionsrueckstaenden aus der phosphorsaeurereinigung in feste deponieprodukte |
| DE2926943A1 (de) * | 1979-07-04 | 1981-01-29 | Hoechst Ag | Verfahren zur reinigung von nassverfahrensphosphorsaeure |
| US4751066A (en) * | 1986-05-08 | 1988-06-14 | Fmc Corporation | Process for preparing alkali metal phosphate |
| GB9124353D0 (en) * | 1991-11-15 | 1992-01-08 | Albright & Wilson | Immobilisation of metal contaminants from a liquid to a solid metal |
| IL211043A0 (en) * | 2010-02-06 | 2011-04-28 | Aharon Eyal | A method for the separation of a non-volatile strong acid from a salt thereof and compositions produced thereby |
| MX2015009680A (es) * | 2013-01-28 | 2016-04-25 | Solex Water Ltd | Metodos y sistemas para recuperacion de agua. |
| CN114031057B (zh) * | 2021-12-17 | 2022-06-21 | 四川大学 | 湿法磷酸生产工业磷酸及联产聚磷酸铵或固体磷酸的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE884358C (de) * | 1951-09-20 | 1953-07-27 | Gerardo Collardin | Verfahren zur Reinigung von technischer Phosphorsaeure |
| BE757550A (fr) * | 1969-10-16 | 1971-03-16 | Giulini Gmbh Geb | Procede de preparation de phosphates purs a partir d'acides phosphoriques impurs |
| US3956465A (en) * | 1970-06-12 | 1976-05-11 | Azote Et Produits Chimiques S.A. | Solvent purification of wet process phosphoric acid |
| FR2093372A5 (en) * | 1970-06-12 | 1972-01-28 | Azote & Prod Chim | Purification of wet-process phosphoric acid - by extraction - with part water-misc organic solvent |
| SE366972B (show.php) * | 1970-06-12 | 1974-05-13 | Azote & Prod Chim | |
| FR2128968A6 (en) * | 1971-03-10 | 1972-10-27 | Azote & Prod Chim | Purification of wet-process phosphoric acid - by extraction - with part water-misc organic solvent |
| DE2029564C3 (de) * | 1970-06-16 | 1978-06-22 | Giulini Chemie Gmbh, 6700 Ludwigshafen | Verfahren zur Herstellung von reinen Alkaliphosphaten aus Rohphosphorsäure |
| US3684439A (en) * | 1970-09-22 | 1972-08-15 | Monsanto Co | Handling of raffinates from wet phosphoric acid purification |
| DE2321751C3 (de) * | 1973-04-30 | 1981-11-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Reinigung von Naßphosphorsäure |
| DE2605106C2 (de) * | 1976-02-10 | 1984-06-14 | Hoechst Ag, 6230 Frankfurt | Verfahren und Vorrichtung zur Herstellung von alkoholischen Phosphorsäurelösungen aus sauren Phosphaten |
-
1976
- 1976-12-17 DE DE2657190A patent/DE2657190C2/de not_active Expired
-
1977
- 1977-09-13 CH CH1116477A patent/CH631418A5/de not_active IP Right Cessation
- 1977-10-27 ES ES463603A patent/ES463603A1/es not_active Expired
- 1977-11-30 SU SU772547802A patent/SU888812A3/ru active
- 1977-12-08 NL NLAANVRAGE7713608,A patent/NL184945C/xx not_active IP Right Cessation
- 1977-12-09 GB GB51348/77A patent/GB1554379A/en not_active Expired
- 1977-12-12 US US05/859,879 patent/US4200620A/en not_active Expired - Lifetime
- 1977-12-13 TR TR19331A patent/TR19331A/xx unknown
- 1977-12-14 PH PH20552A patent/PH14335A/en unknown
- 1977-12-14 IT IT52200/77A patent/IT1090568B/it active
- 1977-12-15 AT AT898277A patent/AT354978B/de active
- 1977-12-15 SE SE7714259A patent/SE429752B/sv not_active IP Right Cessation
- 1977-12-15 ZA ZA00777470A patent/ZA777470B/xx unknown
- 1977-12-15 MX MX171732A patent/MX146999A/es unknown
- 1977-12-15 IL IL53618A patent/IL53618A0/xx not_active IP Right Cessation
- 1977-12-15 DD DD77202670A patent/DD136258A5/xx unknown
- 1977-12-15 FI FI773803A patent/FI65610C/fi not_active IP Right Cessation
- 1977-12-16 BR BR7708375A patent/BR7708375A/pt unknown
- 1977-12-16 FR FR7738057A patent/FR2374263A1/fr active Granted
- 1977-12-16 JP JP15231677A patent/JPS5383993A/ja active Granted
- 1977-12-16 DK DK562677A patent/DK149229C/da not_active IP Right Cessation
- 1977-12-16 CA CA293,219A patent/CA1084238A/en not_active Expired
- 1977-12-16 BE BE183509A patent/BE861920A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA777470B (en) | 1978-11-29 |
| JPS5383993A (en) | 1978-07-24 |
| IL53618A0 (en) | 1978-03-10 |
| FR2374263A1 (fr) | 1978-07-13 |
| ATA898277A (de) | 1979-07-15 |
| DD136258A5 (de) | 1979-06-27 |
| FI65610C (fi) | 1984-06-11 |
| ES463603A1 (es) | 1978-07-16 |
| FR2374263B1 (show.php) | 1982-10-08 |
| JPS5734203B2 (show.php) | 1982-07-21 |
| FI65610B (fi) | 1984-02-29 |
| TR19331A (tr) | 1978-12-07 |
| CA1084238A (en) | 1980-08-26 |
| DK149229C (da) | 1986-08-18 |
| DK149229B (da) | 1986-03-24 |
| NL7713608A (nl) | 1978-06-20 |
| AT354978B (de) | 1980-02-11 |
| DE2657190A1 (de) | 1978-06-22 |
| SU888812A3 (ru) | 1981-12-07 |
| FI773803A7 (fi) | 1978-06-18 |
| NL184945C (nl) | 1989-12-18 |
| GB1554379A (en) | 1979-10-17 |
| BR7708375A (pt) | 1978-08-08 |
| US4200620A (en) | 1980-04-29 |
| SE429752B (sv) | 1983-09-26 |
| BE861920A (fr) | 1978-06-16 |
| DK562677A (da) | 1978-06-18 |
| CH631418A5 (de) | 1982-08-13 |
| NL184945B (nl) | 1989-07-17 |
| MX146999A (es) | 1982-09-22 |
| SE7714259L (sv) | 1978-06-18 |
| IT1090568B (it) | 1985-06-26 |
| PH14335A (en) | 1981-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8339 | Ceased/non-payment of the annual fee |