DE2554699C3 - Verfahren zur rauchfreien Rückgewinnung von Chemikalien - Google Patents
Verfahren zur rauchfreien Rückgewinnung von ChemikalienInfo
- Publication number
- DE2554699C3 DE2554699C3 DE2554699A DE2554699A DE2554699C3 DE 2554699 C3 DE2554699 C3 DE 2554699C3 DE 2554699 A DE2554699 A DE 2554699A DE 2554699 A DE2554699 A DE 2554699A DE 2554699 C3 DE2554699 C3 DE 2554699C3
- Authority
- DE
- Germany
- Prior art keywords
- absorption
- ammonia
- flue gas
- aqueous solution
- smoke
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 51
- 239000000126 substance Substances 0.000 title claims description 17
- 238000011084 recovery Methods 0.000 title claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 63
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 47
- 238000010521 absorption reaction Methods 0.000 claims description 47
- 229910021529 ammonia Inorganic materials 0.000 claims description 30
- 239000003546 flue gas Substances 0.000 claims description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 15
- 238000010411 cooking Methods 0.000 claims description 14
- 239000002699 waste material Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 11
- 230000029087 digestion Effects 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000000779 smoke Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 4
- ZETCGWYACBNPIH-UHFFFAOYSA-N azane;sulfurous acid Chemical compound N.OS(O)=O ZETCGWYACBNPIH-UHFFFAOYSA-N 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- WMBMKLURAIJZGS-UHFFFAOYSA-N azanium hydrogen sulfite sulfurous acid Chemical compound [NH4+].OS(O)=O.OS([O-])=O WMBMKLURAIJZGS-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 33
- 230000002745 absorbent Effects 0.000 description 18
- 239000002250 absorbent Substances 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 13
- 239000007788 liquid Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 230000003321 amplification Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003199 nucleic acid amplification method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000010803 wood ash Substances 0.000 description 2
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- SPEMQUPJTGQFIM-UHFFFAOYSA-N triazanium;hydrogen sulfite;sulfite Chemical compound [NH4+].[NH4+].[NH4+].OS([O-])=O.[O-]S([O-])=O SPEMQUPJTGQFIM-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Cookers (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/534,498 US4004966A (en) | 1974-12-19 | 1974-12-19 | Fume control for sulfur dioxide ammonia absorption systems |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2554699A1 DE2554699A1 (de) | 1976-07-01 |
| DE2554699B2 DE2554699B2 (de) | 1980-04-03 |
| DE2554699C3 true DE2554699C3 (de) | 1980-12-11 |
Family
ID=24130319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2554699A Expired DE2554699C3 (de) | 1974-12-19 | 1975-12-05 | Verfahren zur rauchfreien Rückgewinnung von Chemikalien |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4004966A (en, 2012) |
| JP (1) | JPS5187175A (en, 2012) |
| BR (1) | BR7508277A (en, 2012) |
| CA (1) | CA1047232A (en, 2012) |
| DE (1) | DE2554699C3 (en, 2012) |
| FI (1) | FI58595C (en, 2012) |
| FR (1) | FR2294742A1 (en, 2012) |
| IT (1) | IT1057918B (en, 2012) |
| NO (2) | NO144323C (en, 2012) |
| SE (1) | SE7514071L (en, 2012) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5330472A (en) * | 1976-09-01 | 1978-03-22 | Chiyoda Chem Eng & Constr Co Ltd | Desulfurizing method for exhaust combustion gas |
| US4590048A (en) * | 1983-07-07 | 1986-05-20 | Milpat Corporation | Removal of sulfur oxides from gas streams with ammonium sulfite |
| DE3441442A1 (de) * | 1984-11-13 | 1986-05-15 | Knauf-Research-Cottrell GmbH & Co Umwelttechnik KG, 8715 Iphofen | Verfahren zur umsetzung von gasen mit suspensionen |
| IL103918A (en) * | 1992-11-29 | 1996-10-16 | Hamit Energy As | Method for reducing atmospheric pollution caused by SO2 |
| US6066304A (en) * | 1998-08-06 | 2000-05-23 | Delores Pircon | Process for removing sulfur dioxide out of a gas |
| US10556204B2 (en) * | 2012-01-09 | 2020-02-11 | Robert George RICHARDSON | Processes and methods using chlorine dioxide to remove NOx, SOx, organic compounds, and particulate matter from marine exhaust |
| US9873080B2 (en) * | 2012-01-09 | 2018-01-23 | ScioTech LLC | Processes and methods using chlorine dioxide to remove NOx and SOx from marine exhaust |
| CN103041682B (zh) * | 2012-10-02 | 2016-05-11 | 云南云天化国际化工股份有限公司 | 一种精脱硫在硫酸尾吸中的应用方法 |
| EP4157491A4 (en) | 2020-05-26 | 2023-11-22 | Thiosolv, LLC | METHOD FOR REMOVING SULFUR DIOXIDE AND AMMONIA FROM A VENTILATION GAS STREAM |
| CN112569746A (zh) * | 2020-11-27 | 2021-03-30 | 东华工程科技股份有限公司 | 一种与氨法脱硫系统耦合的处理气化、变换工段含氨尾气的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2233841A (en) * | 1936-08-07 | 1941-03-04 | Cons Mining & Smelting Company | Process for recovery of sulphur dioxide from gases |
| US2161055A (en) * | 1936-08-24 | 1939-06-06 | Commw Edison Co | Recovery of so2 from ammonium sulphite solutions |
| US2676090A (en) * | 1953-01-26 | 1954-04-20 | Texas Gulf Sulphur Co | Recovery of sulfur dioxide contained in waste gases |
| FR1388690A (fr) * | 1963-04-29 | 1965-02-12 | Azote Office Nat Ind | Fixation et valorisation de l'anhydride sulfureux rejeté dans l'atmosphère par leseffluents industriels |
| DE1544094A1 (de) * | 1964-12-19 | 1969-07-10 | Hugo Petersen Fa | Verfahren zur Entfernung von Schwefeldioxyd aus Gasstroemen |
| DE1769125B2 (de) * | 1968-04-06 | 1973-11-29 | Gottfried Bischof Bau Kompletter Gasreinigungsund Wasserr | Verfahren und Vorrichtung zum Aus waschen von Schwefeloxyden aus Rauchgasen |
| JPS4843416A (en, 2012) * | 1971-10-01 | 1973-06-23 | ||
| US3843789A (en) * | 1973-02-26 | 1974-10-22 | Air Prod & Chem | Removal of sulfur oxides from stack gas |
-
1974
- 1974-12-19 US US05/534,498 patent/US4004966A/en not_active Expired - Lifetime
-
1975
- 1975-11-24 CA CA240,319A patent/CA1047232A/en not_active Expired
- 1975-11-26 FI FI753340A patent/FI58595C/fi not_active IP Right Cessation
- 1975-12-04 FR FR7537071A patent/FR2294742A1/fr active Granted
- 1975-12-05 DE DE2554699A patent/DE2554699C3/de not_active Expired
- 1975-12-12 BR BR7508277*A patent/BR7508277A/pt unknown
- 1975-12-12 SE SE7514071A patent/SE7514071L/ not_active Application Discontinuation
- 1975-12-12 IT IT52654/75A patent/IT1057918B/it active
- 1975-12-18 NO NO754310A patent/NO144323C/no unknown
- 1975-12-19 JP JP50150746A patent/JPS5187175A/ja active Pending
-
1980
- 1980-08-29 NO NO802556A patent/NO802556L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO144323C (no) | 1981-08-12 |
| NO144323B (no) | 1981-05-04 |
| DE2554699B2 (de) | 1980-04-03 |
| SE7514071L (sv) | 1976-06-21 |
| IT1057918B (it) | 1982-03-30 |
| FR2294742B1 (en, 2012) | 1982-04-09 |
| DE2554699A1 (de) | 1976-07-01 |
| FI58595B (fi) | 1980-11-28 |
| FR2294742A1 (fr) | 1976-07-16 |
| FI58595C (fi) | 1981-03-10 |
| CA1047232A (en) | 1979-01-30 |
| NO754310L (en, 2012) | 1976-06-22 |
| NO802556L (no) | 1976-06-22 |
| US4004966A (en) | 1977-01-25 |
| FI753340A7 (en, 2012) | 1976-06-20 |
| JPS5187175A (en, 2012) | 1976-07-30 |
| BR7508277A (pt) | 1976-09-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |