DE2554355A1 - Verfahren zur herstellung von cyclohexanderivaten - Google Patents

Verfahren zur herstellung von cyclohexanderivaten

Info

Publication number
DE2554355A1
DE2554355A1 DE19752554355 DE2554355A DE2554355A1 DE 2554355 A1 DE2554355 A1 DE 2554355A1 DE 19752554355 DE19752554355 DE 19752554355 DE 2554355 A DE2554355 A DE 2554355A DE 2554355 A1 DE2554355 A1 DE 2554355A1
Authority
DE
Germany
Prior art keywords
acid
catalyst
sio
benzene
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19752554355
Other languages
German (de)
English (en)
Other versions
DE2554355C2 (enExample
Inventor
Seikichi Matsuhisa
Masaki Nishino
Yutaka Yasuhara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP49062844A external-priority patent/JPS511445A/ja
Priority to JP49062844A priority Critical patent/JPS511445A/ja
Priority claimed from JP12752374A external-priority patent/JPS5640128B2/ja
Priority to JP12752374A priority patent/JPS5640128B2/ja
Priority to US05/581,788 priority patent/US4067915A/en
Priority to FR7517386A priority patent/FR2273783A1/fr
Priority to NLAANVRAGE7514054,A priority patent/NL185074C/xx
Priority to DE19752554355 priority patent/DE2554355A1/de
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of DE2554355A1 publication Critical patent/DE2554355A1/de
Priority to US06/095,956 priority patent/US4508918A/en
Publication of DE2554355C2 publication Critical patent/DE2554355C2/de
Application granted granted Critical
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE19752554355 1974-06-05 1975-12-03 Verfahren zur herstellung von cyclohexanderivaten Granted DE2554355A1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP49062844A JPS511445A (enExample) 1974-06-05 1974-06-05
JP12752374A JPS5640128B2 (enExample) 1974-11-07 1974-11-07
US05/581,788 US4067915A (en) 1974-06-05 1975-05-29 Method for producing cyclohexane derivatives directly from aromatic hydrocarbons
FR7517386A FR2273783A1 (fr) 1974-06-05 1975-06-04 Procede de production de derives de cyclohexane directement a partir d'hydrocarbures aromatiques et nouveaux produits ainsi obtenus
NLAANVRAGE7514054,A NL185074C (nl) 1974-06-05 1975-12-02 Werkwijze voor het bereiden van een cyclohexylchloride uit een aromatische koolwaterstof.
DE19752554355 DE2554355A1 (de) 1974-06-05 1975-12-03 Verfahren zur herstellung von cyclohexanderivaten
US06/095,956 US4508918A (en) 1974-06-05 1979-11-20 Method of producing cyclohexane derivatives directly from aromatic hydrocarbons

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP49062844A JPS511445A (enExample) 1974-06-05 1974-06-05
JP12752374A JPS5640128B2 (enExample) 1974-11-07 1974-11-07
NLAANVRAGE7514054,A NL185074C (nl) 1974-06-05 1975-12-02 Werkwijze voor het bereiden van een cyclohexylchloride uit een aromatische koolwaterstof.
DE19752554355 DE2554355A1 (de) 1974-06-05 1975-12-03 Verfahren zur herstellung von cyclohexanderivaten

Publications (2)

Publication Number Publication Date
DE2554355A1 true DE2554355A1 (de) 1977-06-08
DE2554355C2 DE2554355C2 (enExample) 1988-07-21

Family

ID=27432048

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19752554355 Granted DE2554355A1 (de) 1974-06-05 1975-12-03 Verfahren zur herstellung von cyclohexanderivaten

Country Status (4)

Country Link
US (2) US4067915A (enExample)
DE (1) DE2554355A1 (enExample)
FR (1) FR2273783A1 (enExample)
NL (1) NL185074C (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4067915A (en) * 1974-06-05 1978-01-10 Toray Industries, Inc. Method for producing cyclohexane derivatives directly from aromatic hydrocarbons
JPS54122253A (en) * 1978-03-13 1979-09-21 Shin Etsu Chem Co Ltd Preparation of cis-alkylcyclohexanol
NL7905781A (nl) * 1979-07-26 1981-01-28 Stamicarbon Werkwijze voor het bereiden van cyclohexanol.
IT1217317B (it) * 1987-05-05 1990-03-22 Montedison Spa Procedimento per l'idrogenazione di bisfenoli
DE69009682T2 (de) * 1989-11-13 1994-10-06 Firmenich & Cie Verfahren zur Herstellung von Cyclohexanolderivaten.
US5100851A (en) * 1990-09-04 1992-03-31 Exxon Research And Engineering Company Stationary aqueous acid phase transition metal catalysts for reduction of aromatics
US6156946A (en) * 1996-04-12 2000-12-05 Exxon Research And Engineering Company Biological activation of aromatics for chemical processing and/or upgrading of aromatic compounds, petroleum, coal, resid, bitumen and other petrochemical streams
US6013847A (en) * 1998-12-31 2000-01-11 Phillips Petroleum Company Hydrogenation of benzene in the presence of water
DE10135490A1 (de) * 2001-07-20 2003-01-30 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen mit Restgas enthaltendem Wasserstoff
ATE415447T1 (de) * 2001-09-25 2008-12-15 Exxonmobil Chem Patents Inc Weich-polyvinylchlorid
DE10209701A1 (de) * 2002-03-06 2003-09-18 Basf Ag Verfahren zur Herstellung von Cyclohexanol aus Benzol
US7229487B2 (en) * 2004-01-14 2007-06-12 Sanford, L.P. Writing instruments with eradicable inks and eradicating fluids
DE102007004351A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
CN103304370B (zh) * 2013-06-03 2015-02-04 安徽中草香料有限公司 一种5-甲基-2-异丙基氯代环己烷的合成方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391206A (en) * 1964-04-08 1968-07-02 Stamicarbon Preparation of cyclic alkenes
DE2221137A1 (de) * 1971-04-29 1972-11-09 Du Pont Selektive Hydrierung von aromatischen Kohlenwasserstoffen zu Cycloolefinen
US3793383A (en) * 1972-07-13 1974-02-19 Phillips Petroleum Co Selective hydrogenation of aromatics

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1960977A (en) * 1928-01-13 1934-05-29 Ig Farbenindustrie Ag Production of hydroaromatic hydrocarbons
US2238594A (en) * 1936-05-14 1941-04-15 Standard Oil Dev Co Catalytic treatment of hydrocarbons
US2573695A (en) * 1945-10-03 1951-11-06 Publicker Ind Inc Hydrohalogenation of olefins
US3493605A (en) * 1966-12-19 1970-02-03 Gulf Research Development Co Alkanoic acid esters by oxidation of alkyl-aromatic hydrocarbons with a group viii noble metal alkanoate
US3547982A (en) * 1967-03-13 1970-12-15 Union Carbide Corp Benzylic oxidation process for preparation of arylalkyl esters
US4067915A (en) * 1974-06-05 1978-01-10 Toray Industries, Inc. Method for producing cyclohexane derivatives directly from aromatic hydrocarbons

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391206A (en) * 1964-04-08 1968-07-02 Stamicarbon Preparation of cyclic alkenes
DE2221137A1 (de) * 1971-04-29 1972-11-09 Du Pont Selektive Hydrierung von aromatischen Kohlenwasserstoffen zu Cycloolefinen
US3793383A (en) * 1972-07-13 1974-02-19 Phillips Petroleum Co Selective hydrogenation of aromatics

Also Published As

Publication number Publication date
US4067915A (en) 1978-01-10
FR2273783B1 (enExample) 1977-12-09
NL185074C (nl) 1990-01-16
FR2273783A1 (fr) 1976-01-02
NL7514054A (nl) 1977-06-06
US4508918A (en) 1985-04-02
DE2554355C2 (enExample) 1988-07-21

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8125 Change of the main classification

Ipc: C07B 29/00

8126 Change of the secondary classification

Free format text: C07C 69/06 C07C 69/24 C07C 35/08 C07C 23/10

8125 Change of the main classification

Ipc: C07C 23/10

D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee