DE2542737C3 - Strahlungshärtbare Tinte - Google Patents
Strahlungshärtbare TinteInfo
- Publication number
- DE2542737C3 DE2542737C3 DE2542737A DE2542737A DE2542737C3 DE 2542737 C3 DE2542737 C3 DE 2542737C3 DE 2542737 A DE2542737 A DE 2542737A DE 2542737 A DE2542737 A DE 2542737A DE 2542737 C3 DE2542737 C3 DE 2542737C3
- Authority
- DE
- Germany
- Prior art keywords
- ink
- radiation
- curable
- metal
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000005855 radiation Effects 0.000 title description 15
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
- 229910052709 silver Inorganic materials 0.000 claims description 15
- 239000004332 silver Substances 0.000 claims description 15
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 150000002739 metals Chemical class 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 51
- 229920005989 resin Polymers 0.000 description 38
- 239000011347 resin Substances 0.000 description 38
- 239000011230 binding agent Substances 0.000 description 20
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- 239000000758 substrate Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- 239000004793 Polystyrene Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000003504 photosensitizing agent Substances 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- -1 allyl ethers Chemical class 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000011231 conductive filler Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 229920006295 polythiol Polymers 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- QCCDLTOVEPVEJK-UHFFFAOYSA-N phenylacetone Chemical compound CC(=O)CC1=CC=CC=C1 QCCDLTOVEPVEJK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 2
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- ZWAJLVLEBYIOTI-OLQVQODUSA-N (1s,6r)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCC[C@@H]2O[C@@H]21 ZWAJLVLEBYIOTI-OLQVQODUSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- MIOKJIDWWJEJDE-UHFFFAOYSA-N (4-dodecyl-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(CCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 MIOKJIDWWJEJDE-UHFFFAOYSA-N 0.000 description 1
- MIKUGQGSVJRVAM-UHFFFAOYSA-N 1-[2-(hydroxymethyl)phenyl]-2-phenyl-2-propan-2-yloxyethanone Chemical compound C(C)(C)OC(C(C1=C(C=CC=C1)CO)=O)C1=CC=CC=C1 MIKUGQGSVJRVAM-UHFFFAOYSA-N 0.000 description 1
- VUBUXALTYMBEQO-UHFFFAOYSA-N 2,2,3,3,3-pentafluoro-1-phenylpropan-1-one Chemical compound FC(F)(F)C(F)(F)C(=O)C1=CC=CC=C1 VUBUXALTYMBEQO-UHFFFAOYSA-N 0.000 description 1
- QYXHDJJYVDLECA-UHFFFAOYSA-N 2,5-diphenylcyclohexa-2,5-diene-1,4-dione Chemical compound O=C1C=C(C=2C=CC=CC=2)C(=O)C=C1C1=CC=CC=C1 QYXHDJJYVDLECA-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- DBBSWURSQHDBEQ-UHFFFAOYSA-N 2-butan-2-yloxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC(C)CC)C(=O)C1=CC=CC=C1 DBBSWURSQHDBEQ-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- RBHIUNHSNSQJNG-UHFFFAOYSA-N 6-methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2(C)OC2CC1C1(C)CO1 RBHIUNHSNSQJNG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N o-dihydroxy-benzene Natural products OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000005510 radiation hardening Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
- H05K1/095—Dispersed materials, e.g. conductive pastes or inks for polymer thick films, i.e. having a permanent organic polymeric binder
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Conductive Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Parts Printed On Printed Circuit Boards (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/509,822 US3968056A (en) | 1974-09-27 | 1974-09-27 | Radiation curable inks |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2542737A1 DE2542737A1 (de) | 1976-04-22 |
| DE2542737B2 DE2542737B2 (de) | 1979-02-15 |
| DE2542737C3 true DE2542737C3 (de) | 1979-10-18 |
Family
ID=24028213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2542737A Expired DE2542737C3 (de) | 1974-09-27 | 1975-09-25 | Strahlungshärtbare Tinte |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3968056A (enExample) |
| JP (1) | JPS5619045B2 (enExample) |
| BE (1) | BE833857A (enExample) |
| CA (1) | CA1072802A (enExample) |
| DE (1) | DE2542737C3 (enExample) |
| GB (1) | GB1519298A (enExample) |
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE30274E (en) * | 1974-09-27 | 1980-05-13 | General Electric Company | Method for making a circuit board and article made thereby |
| US4049844A (en) * | 1974-09-27 | 1977-09-20 | General Electric Company | Method for making a circuit board and article made thereby |
| FR2328558A1 (fr) * | 1975-10-24 | 1977-05-20 | Charbonnages Ste Chimique | Procede de fabrication de films antistatiques de polymeres synthetiques et produits obtenus |
| US4088801A (en) * | 1976-04-29 | 1978-05-09 | General Electric Company | U.V. Radiation curable electrically conductive ink and circuit boards made therewith |
| US4282682A (en) * | 1976-12-07 | 1981-08-11 | Societe Des Plastiques De Carmaux Scasar | Method of mulching with antistatic synthetic polymer film |
| US4155896A (en) * | 1977-07-27 | 1979-05-22 | Rockwell International Corporation | Organic coatings and paints having unique electrical properties |
| US4243455A (en) * | 1977-07-29 | 1981-01-06 | Nippon Graphite Industries, Ltd. | Method of forming electrode connector for liquid crystal display device |
| JPS5534211A (en) * | 1978-08-31 | 1980-03-10 | Toppan Printing Co Ltd | Calcining ink composition |
| FR2441647A1 (fr) * | 1978-12-08 | 1980-06-13 | Fujikura Kasei Kk | Procede pour la preparation de particules d'argent agglomerees, et d'une composition de revetement conductrice d'electricite et photodurcissable les contenant |
| US4250203A (en) * | 1979-08-30 | 1981-02-10 | American Can Company | Cationically polymerizable compositions containing sulfonium salt photoinitiators and odor suppressants and method of polymerization using same |
| US4306953A (en) * | 1979-11-05 | 1981-12-22 | American Can Company | Cationically polymerizable compositions containing sulfonium salt photoinitiators and stable free radicals as odor suppressants and _method of polymerization using same |
| US4290747A (en) * | 1979-11-09 | 1981-09-22 | General Electric Company | Photoflash lamp array circuit board having radiation sensitive fuse elements |
| US4290748A (en) * | 1979-11-09 | 1981-09-22 | General Electric Company | Photoflash lamp array circuit board having radiation sensitive fuse elements |
| US4289595A (en) * | 1979-11-26 | 1981-09-15 | American Can Company | Ambient temperature curing photopolymerizable epoxide compositions utilizing epoxide ethers and methods |
| US4318787A (en) * | 1980-02-22 | 1982-03-09 | Conoco Inc. | Sacrificial anode composition in cathodic protection process |
| US4549948A (en) * | 1980-08-22 | 1985-10-29 | Conoco Inc. | Sacrificial anode composition |
| US4419279A (en) * | 1980-09-15 | 1983-12-06 | Potters Industries, Inc. | Conductive paste, electroconductive body and fabrication of same |
| US4496475A (en) * | 1980-09-15 | 1985-01-29 | Potters Industries, Inc. | Conductive paste, electroconductive body and fabrication of same |
| US4499010A (en) * | 1980-09-19 | 1985-02-12 | Toyama Prefecture | Conductive paint |
| US4406826A (en) * | 1981-03-05 | 1983-09-27 | W. R. Grace & Co. | Heat curable conductive ink |
| US4443495A (en) * | 1981-03-05 | 1984-04-17 | W. R. Grace & Co. | Heat curable conductive ink |
| JPS57196765A (en) * | 1981-05-28 | 1982-12-02 | Tdk Electronics Co Ltd | Magnetic head reinforcing material |
| US4425263A (en) * | 1981-06-03 | 1984-01-10 | E. I. Du Pont De Nemours & Co. | Flexible screen-printable conductive composition |
| GB2111072A (en) * | 1981-12-08 | 1983-06-29 | Johnson Matthey Plc | Ultra violet-curable ink or paint containing electrically conductive metal particles |
| US4371459A (en) * | 1981-12-17 | 1983-02-01 | E. I. Du Pont De Nemours And Company | Flexible screen-printable conductor composition |
| JPS5919209A (ja) * | 1982-07-21 | 1984-01-31 | Tdk Corp | 磁気ヘツド用補強材 |
| CA1218839A (en) * | 1982-10-28 | 1987-03-10 | Tokuzo Kanbe | Shielding material of electromagnetic waves |
| DE3474740D1 (en) * | 1983-07-07 | 1988-11-24 | Philips Nv | Improved electrically conductive materials for devices |
| US4566186A (en) * | 1984-06-29 | 1986-01-28 | Tektronix, Inc. | Multilayer interconnect circuitry using photoimageable dielectric |
| US4575432A (en) * | 1984-07-09 | 1986-03-11 | W. R. Grace & Co. | Conductive thermosetting compositions and process for using same |
| US4581158A (en) * | 1984-09-26 | 1986-04-08 | W. R. Grace & Co. | Conductive thermosetting compositions and process for using same |
| US4725478A (en) * | 1985-09-04 | 1988-02-16 | W. R. Grace & Co. | Heat-miniaturizable printed circuit board |
| US4959178A (en) * | 1987-01-27 | 1990-09-25 | Advanced Products Inc. | Actinic radiation-curable conductive polymer thick film compositions and their use thereof |
| US5036128A (en) * | 1987-02-06 | 1991-07-30 | Key-Tech, Inc. | Printed circuit board |
| US4960614A (en) * | 1987-02-06 | 1990-10-02 | Key-Tech, Inc. | Printed circuit board |
| US5089350A (en) * | 1988-04-28 | 1992-02-18 | Ncr Corporation | Thermal transfer ribbon |
| US4857233A (en) * | 1988-05-26 | 1989-08-15 | Potters Industries, Inc. | Nickel particle plating system |
| US5180523A (en) * | 1989-11-14 | 1993-01-19 | Poly-Flex Circuits, Inc. | Electrically conductive cement containing agglomerate, flake and powder metal fillers |
| GB2239244B (en) * | 1989-11-14 | 1994-06-01 | David Durand | Moisture resistant electrically conductive cements and methods for making and using same |
| DK0432093T3 (da) * | 1989-12-07 | 1995-11-20 | Sicpa Holding Sa | Højreaktive trykfarver |
| US5283104A (en) * | 1991-03-20 | 1994-02-01 | International Business Machines Corporation | Via paste compositions and use thereof to form conductive vias in circuitized ceramic substrates |
| FR2693268B1 (fr) * | 1992-07-02 | 1994-09-30 | Microondes Syst Sa | Procédé et dispositif de contrôle du chauffage par micro-ondes d'un produit à une température et pendant un temps déterminés, support de marquage et récipient pour produit destiné à un tel contrôle. |
| DE4307766C1 (de) * | 1993-03-11 | 1994-09-15 | Zeller & Gmelin Gmbh & Co | UV-Flexodruckfarbe, Verfahren zu deren Herstellung und Verwendung |
| JP2965815B2 (ja) * | 1993-04-05 | 1999-10-18 | アルプス電気株式会社 | 半田付け可能な塗膜形成用導電性ペースト |
| DE19631015A1 (de) * | 1995-08-11 | 1997-02-13 | Illinois Tool Works | UV-gehärtete wärmeaktivierte Labels für Substrate und Verfahren zu deren Herstellung |
| US5854298A (en) * | 1997-09-29 | 1998-12-29 | Lockheed Martin Corporation | Photocurable low observable aircraft materials |
| WO1999020685A1 (en) * | 1997-10-17 | 1999-04-29 | The Dow Chemical Company | Compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers |
| US6169125B1 (en) * | 1999-01-11 | 2001-01-02 | Dymax Corporation | Electrically conductive resinous material and radiation curable formulation for producing the same |
| US6218446B1 (en) * | 1999-01-11 | 2001-04-17 | Dymax Corporation | Radiation curable formulation for producing electrically conductive resinous material, method of use, and article produced |
| US7157507B2 (en) * | 1999-04-14 | 2007-01-02 | Allied Photochemical, Inc. | Ultraviolet curable silver composition and related method |
| US6290881B1 (en) | 1999-04-14 | 2001-09-18 | Allied Photochemical, Inc. | Ultraviolet curable silver composition and related method |
| MXPA02003152A (es) * | 1999-10-06 | 2003-08-20 | Uv Specialties Inc | Composicion curable por luz uv, para producir revestimientos electroluminiscentes. |
| US6767577B1 (en) | 1999-10-06 | 2004-07-27 | Allied Photochemical, Inc. | Uv curable compositions for producing electroluminescent coatings |
| US6500877B1 (en) | 1999-11-05 | 2002-12-31 | Krohn Industries, Inc. | UV curable paint compositions and method of making and applying same |
| US6509389B1 (en) | 1999-11-05 | 2003-01-21 | Uv Specialties, Inc. | UV curable compositions for producing mar resistant coatings and method for depositing same |
| US6805917B1 (en) | 1999-12-06 | 2004-10-19 | Roy C. Krohn | UV curable compositions for producing decorative metallic coatings |
| WO2001040386A2 (en) | 1999-12-06 | 2001-06-07 | Krohn Industries, Inc. | Uv curable compositions for producing multilayer pain coatings |
| EP1252238A2 (en) * | 1999-12-06 | 2002-10-30 | Slidekote, Inc. | Uv curable compositions |
| US20060100302A1 (en) * | 1999-12-06 | 2006-05-11 | Krohn Roy C | UV curable compositions for producing multilayer paint coatings |
| CA2396978C (en) * | 2000-01-13 | 2009-04-07 | Uv Specialties, Inc. | Uv curable transparent conductive compositions |
| EP1263891A1 (en) * | 2000-01-13 | 2002-12-11 | UV Specialties, Inc. | Uv curable ferromagnetic compositions |
| US7323499B2 (en) * | 2000-09-06 | 2008-01-29 | Allied Photochemical, Inc. | UV curable silver chloride compositions for producing silver coatings |
| US6906114B2 (en) * | 2000-09-06 | 2005-06-14 | Allied Photochemical, Inc. | UV curable silver chloride compositions for producing silver coatings |
| DE10323374A1 (de) * | 2003-05-21 | 2004-12-09 | Basf Drucksysteme Gmbh | Metallic-Druckfarbe und deren Verwendung zur Veredelung von Drucken |
| US20050244587A1 (en) * | 2003-09-09 | 2005-11-03 | Shirlin Jack W | Heating elements deposited on a substrate and related method |
| US6946628B2 (en) * | 2003-09-09 | 2005-09-20 | Klai Enterprises, Inc. | Heating elements deposited on a substrate and related method |
| US20050101686A1 (en) * | 2003-11-07 | 2005-05-12 | Krohn Roy C. | UV curable composition for forming dielectric coatings and related method |
| US20050101685A1 (en) * | 2003-11-07 | 2005-05-12 | Allied Photochemical, Inc. | UV curable composition for forming dielectric coatings and related method |
| US20050176841A1 (en) * | 2003-12-30 | 2005-08-11 | Krohn Roy C. | UV curable ink compositions |
| TW200643124A (en) * | 2005-06-08 | 2006-12-16 | Yung-Shu Yang | The radiation hardening conductive ink and the manufacturing method of conductive substrate by using radiation hardening conductive ink |
| US20090173919A1 (en) * | 2005-11-22 | 2009-07-09 | Ndsu Researcvh Foundation | Conductive Ink Compositions |
| JP2007197641A (ja) * | 2006-01-30 | 2007-08-09 | Yung-Shu Yang | 放射線硬化型導電性インキ及び放射線硬化型導電性インキを用いた導電基板の製造方法 |
| EP1832632A1 (en) | 2006-03-07 | 2007-09-12 | DSM IP Assets B.V. | Conductive ink |
| US20140097002A1 (en) * | 2012-10-05 | 2014-04-10 | Tyco Electronics Amp Gmbh | Electrical components and methods and systems of manufacturing electrical components |
| WO2015061332A1 (en) | 2013-10-23 | 2015-04-30 | Heilux, Llc | High powered led light module with a balanced matrix circuit |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3280741A (en) * | 1958-12-31 | 1966-10-25 | Burroughs Corp | Electrostatic recording |
| US3412043A (en) * | 1966-08-05 | 1968-11-19 | Dexter Corp | Electrically conductive resinous compositions |
| US3661614A (en) * | 1969-12-11 | 1972-05-09 | Sun Chemical Corp | Radiation-curable ink compositions |
| US3673140A (en) * | 1971-01-06 | 1972-06-27 | Inmont Corp | Actinic radiation curing compositions and method of coating and printing using same |
| US3746662A (en) * | 1971-08-09 | 1973-07-17 | Du Pont | Conductive systems |
| US3875094A (en) * | 1974-02-22 | 1975-04-01 | Gen Electric | Radiation curable polyester |
-
1974
- 1974-09-27 US US05/509,822 patent/US3968056A/en not_active Expired - Lifetime
-
1975
- 1975-08-08 JP JP9596975A patent/JPS5619045B2/ja not_active Expired
- 1975-09-03 CA CA234,723A patent/CA1072802A/en not_active Expired
- 1975-09-09 GB GB37014/75A patent/GB1519298A/en not_active Expired
- 1975-09-25 DE DE2542737A patent/DE2542737C3/de not_active Expired
- 1975-09-26 BE BE160401A patent/BE833857A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1519298A (en) | 1978-07-26 |
| DE2542737A1 (de) | 1976-04-22 |
| JPS5619045B2 (enExample) | 1981-05-02 |
| JPS5142606A (enExample) | 1976-04-10 |
| BE833857A (fr) | 1976-01-16 |
| US3968056A (en) | 1976-07-06 |
| DE2542737B2 (de) | 1979-02-15 |
| CA1072802A (en) | 1980-03-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2542737C3 (de) | Strahlungshärtbare Tinte | |
| DE2542669B2 (de) | Schaltungsplatte, Verfahren zu deren Herstellung und deren Verwendung | |
| USRE31411E (en) | Radiation curable inks | |
| CA1049254A (en) | Radiation curable inks | |
| DE2346424C2 (de) | Strahlungshärtbare, nicht gelierte Massen | |
| DE2518639C3 (de) | Härtbare Zusammensetzungen | |
| DE60033801T2 (de) | Uv-härtbare silberzusammensetzung und zugehöriges verfahren | |
| US3989644A (en) | Radiation curable inks | |
| DE68912018T2 (de) | UV-härtbare Polymerzusammensetzung. | |
| DE69716051T2 (de) | Durch licht polymerisierbare zusammensetzung, druckempfindlicher flammgeschützter klebstoff und klebstoffschichten | |
| DE2734508C3 (de) | Verfahren zur Herstellung einer Flachdruckplatte bzw. eines Flachdruckblattes | |
| DE2436186A1 (de) | Verfahren zur herstellung von kunststoffschichtueberzuegen | |
| DE112009000690T5 (de) | Tintenstrahldruckfarbenzusammensetzung für Ätzresists | |
| DE3717199A1 (de) | Photohaertbare resist-harzmasse zum stromlosen plattieren und ihre verwendung zur herstellung von gedruckten schaltungen | |
| DE2411398A1 (de) | Verfahren zur herstellung einer photohaertbaren zusammensetzung fuer den siebdruck | |
| DE2458959A1 (de) | Verfahren zur herstellung eines durch ultraviolettstrahlung oder ionisierende strahlung haertbaren praepolymeren | |
| DE69734510T2 (de) | Lichtempfindliche zusammensetzung und weisse beschichtung | |
| DE112017002573T5 (de) | Tintenstrahlharzzusammensetzung und gedruckte Leiterplatte, die dieselbe verwendet | |
| DE4209708A1 (de) | Verfahren zur Verbesserung der Haftfestigkeit von stromlos abgeschiedenen Metallschichten | |
| DE1570748A1 (de) | Photopolymer | |
| DE4142735A1 (de) | Durch strahlung polymerisierbares gemisch und verfahren zur herstellung einer loetstoppmaske | |
| DE2949349A1 (de) | Durch belichten haertbare, elektrisch leitfaehige beschichtungsmasse und verfahren zur herstellung von silberaggregatteilchen fuer eine solche masse | |
| DE2407301C3 (de) | Härtbare Beschichtungszusammensetzung und Verfahren zu ihrer Herstellung | |
| DE112017002537T5 (de) | Verfahren zur Herstellung einer Tintenstrahlharzzusammensetzung | |
| DE69218341T2 (de) | Verfahren zur Herstellung einer Lötstopmaske |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |