DE2532417A1 - Schlichtmittel fuer glasfasern - Google Patents
Schlichtmittel fuer glasfasernInfo
- Publication number
- DE2532417A1 DE2532417A1 DE19752532417 DE2532417A DE2532417A1 DE 2532417 A1 DE2532417 A1 DE 2532417A1 DE 19752532417 DE19752532417 DE 19752532417 DE 2532417 A DE2532417 A DE 2532417A DE 2532417 A1 DE2532417 A1 DE 2532417A1
- Authority
- DE
- Germany
- Prior art keywords
- sizing agent
- weight
- gamma
- ethylenediamine
- propyltrialkoxysilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003795 chemical substances by application Substances 0.000 title claims description 32
- 239000003365 glass fiber Substances 0.000 title claims description 15
- 238000004513 sizing Methods 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 12
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 10
- 239000011118 polyvinyl acetate Substances 0.000 claims description 10
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- DDMBMMPGQMWNTI-UHFFFAOYSA-N ethane-1,2-diamine;trimethoxy(propyl)silane Chemical compound NCCN.CCC[Si](OC)(OC)OC DDMBMMPGQMWNTI-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 2
- FYDNFZPPZJDFRY-UHFFFAOYSA-K chromium(3+);2-methylprop-2-enoate Chemical compound [Cr+3].CC(=C)C([O-])=O.CC(=C)C([O-])=O.CC(=C)C([O-])=O FYDNFZPPZJDFRY-UHFFFAOYSA-K 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000011152 fibreglass Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 229920001225 polyester resin Polymers 0.000 description 5
- 239000004645 polyester resin Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000013065 commercial product Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 210000002445 nipple Anatomy 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- -1 methacrylic acid compound Chemical class 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- GHLZUHZBBNDWHW-UHFFFAOYSA-N nonanamide Chemical compound CCCCCCCCC(N)=O GHLZUHZBBNDWHW-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- ZKSPHENWXBWOPM-UHFFFAOYSA-N 2-methylprop-2-enoic acid oxochromium Chemical compound CC(=C)C(=O)O.O=[Cr] ZKSPHENWXBWOPM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- VVNCNSJFMMFHPL-VKHMYHEASA-N D-penicillamine Chemical group CC(C)(S)[C@@H](N)C(O)=O VVNCNSJFMMFHPL-VKHMYHEASA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- NHWGPUVJQFTOQX-UHFFFAOYSA-N ethyl-[2-[2-[ethyl(dimethyl)azaniumyl]ethyl-methylamino]ethyl]-dimethylazanium Chemical compound CC[N+](C)(C)CCN(C)CC[N+](C)(C)CC NHWGPUVJQFTOQX-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000004001 thioalkyl group Chemical group 0.000 description 1
- 125000005000 thioaryl group Chemical group 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30261172A | 1972-10-31 | 1972-10-31 | |
| US05/491,730 US3933711A (en) | 1972-10-31 | 1974-07-23 | Forming size of aqueous polyvinylacetate |
| US05/605,577 US4027071A (en) | 1972-10-31 | 1975-08-18 | Forming size for glass fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2532417A1 true DE2532417A1 (de) | 1976-02-05 |
Family
ID=27404886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752532417 Withdrawn DE2532417A1 (de) | 1972-10-31 | 1975-07-19 | Schlichtmittel fuer glasfasern |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US3933711A (enExample) |
| BE (1) | BE831599A (enExample) |
| DE (1) | DE2532417A1 (enExample) |
| FR (1) | FR2279688A1 (enExample) |
| NL (1) | NL7507665A (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4347278A (en) * | 1977-03-02 | 1982-08-31 | Owens-Corning Fiberglas Corporation | Polytetrafluoroethylene fluorocarbon resin dispersion-containing coating composition for glass fibers, glass fibers, and glass fiber fabric coated therewith |
| US4473618A (en) * | 1983-05-13 | 1984-09-25 | Owens-Corning Fiberglas Corporation | Chrome-free sizing composition containing titanium acetyl acetonate for glass fiber gun roving |
| WO1986001811A1 (en) * | 1984-09-24 | 1986-03-27 | Owens-Corning Fiberglas Corporation | Chrome-free sizing for glass fiber gun roving |
| US5120780A (en) * | 1990-09-13 | 1992-06-09 | National Starch And Chemical Investment Holding Corporation | Glass fiber size composition and synthetic organosilane lubricants used therein |
| US5237083A (en) * | 1990-09-13 | 1993-08-17 | National Starch And Chemical Investment Holding Corporation | Synthetic organosilane compounds useful as lubricants in glass sizing compositions |
| US5491182A (en) * | 1994-07-27 | 1996-02-13 | National Starch And Chemical Investment Holding Corporation | Glass fiber sizing compositions and methods of using same |
| US5700574A (en) * | 1994-08-17 | 1997-12-23 | Owens-Corning Fiberglas Technology, Inc. | Sizing composition for glass roving |
| FR2730726B1 (fr) * | 1995-02-16 | 1997-04-30 | Quartz & Silice | Composition d'ensimage ceramifiable pour fils continus mineraux, fils revetus de cette composition et procede d'ensimage et de traitement thermique mettant en oeuvre cette composition |
| US5904797A (en) * | 1996-02-12 | 1999-05-18 | E. I. Du Pont De Nemours And Company | Adhesion improvement with methylacrylate-chromium complexes and poly(vinyl alcohol) |
| FR2864072B1 (fr) | 2003-12-17 | 2006-01-27 | Saint Gobain Vetrotex | Fils de verre ensimes destines au renforcement de matieres polymeres, notamment par moulage |
| US20050276960A1 (en) * | 2004-06-15 | 2005-12-15 | Lee Jerry H C | Fatty amide composition for wet use chopped strand glass fibers |
| CN105254190B (zh) * | 2015-09-24 | 2017-08-15 | 南京春辉科技实业有限公司 | 一种多组分玻璃光纤用浸润剂及其制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL290742A (enExample) * | 1962-04-03 | 1900-01-01 | ||
| US3454515A (en) * | 1966-03-28 | 1969-07-08 | Ferro Corp | Sizing composition for glass fibers |
| US3655353A (en) * | 1969-05-21 | 1972-04-11 | Ppg Industries Inc | Glass fiber size |
| US3817898A (en) * | 1971-11-15 | 1974-06-18 | Owens Corning Fiberglass Corp | Sizing composition and glass fibers treated therewith |
| US3850869A (en) * | 1973-01-02 | 1974-11-26 | Johns Manville | Glass fiber sizing composition and resultant product with high resistance to abrasion |
-
1974
- 1974-07-23 US US05/491,730 patent/US3933711A/en not_active Expired - Lifetime
-
1975
- 1975-06-27 NL NL7507665A patent/NL7507665A/xx not_active Application Discontinuation
- 1975-07-19 DE DE19752532417 patent/DE2532417A1/de not_active Withdrawn
- 1975-07-22 FR FR7522804A patent/FR2279688A1/fr active Granted
- 1975-07-22 BE BE158492A patent/BE831599A/xx not_active IP Right Cessation
- 1975-08-18 US US05/605,577 patent/US4027071A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL7507665A (nl) | 1976-01-27 |
| US4027071A (en) | 1977-05-31 |
| US3933711A (en) | 1976-01-20 |
| FR2279688A1 (fr) | 1976-02-20 |
| FR2279688B1 (enExample) | 1980-09-26 |
| BE831599A (fr) | 1976-01-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8130 | Withdrawal |