DE2461104C3 - Verfahren zum Abführen von Wärme während der Methylmethacrylat-Massepolymerisation und Vorrichtung zur Durchführung des Verfahrens - Google Patents
Verfahren zum Abführen von Wärme während der Methylmethacrylat-Massepolymerisation und Vorrichtung zur Durchführung des VerfahrensInfo
- Publication number
- DE2461104C3 DE2461104C3 DE2461104A DE2461104A DE2461104C3 DE 2461104 C3 DE2461104 C3 DE 2461104C3 DE 2461104 A DE2461104 A DE 2461104A DE 2461104 A DE2461104 A DE 2461104A DE 2461104 C3 DE2461104 C3 DE 2461104C3
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- polymerization
- stirrer
- polymerization mixture
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 29
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title claims description 13
- 238000012662 bulk polymerization Methods 0.000 title claims description 6
- 230000008569 process Effects 0.000 title description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 85
- 239000000203 mixture Substances 0.000 claims description 52
- 239000000178 monomer Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 description 25
- 238000001816 cooling Methods 0.000 description 24
- 239000012808 vapor phase Substances 0.000 description 22
- 239000000498 cooling water Substances 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 15
- 238000010992 reflux Methods 0.000 description 11
- 238000001704 evaporation Methods 0.000 description 10
- 230000008020 evaporation Effects 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000003756 stirring Methods 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000017525 heat dissipation Effects 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- -1 diamine salt Chemical class 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241000589614 Pseudomonas stutzeri Species 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/86—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis co-operating with deflectors or baffles fixed to the receptacle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2215/00—Auxiliary or complementary information in relation with mixing
- B01F2215/04—Technical information in relation with mixing
- B01F2215/0413—Numerical information
- B01F2215/0418—Geometrical information
- B01F2215/0427—Numerical distance values, e.g. separation, position
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2215/00—Auxiliary or complementary information in relation with mixing
- B01F2215/04—Technical information in relation with mixing
- B01F2215/0413—Numerical information
- B01F2215/0418—Geometrical information
- B01F2215/0431—Numerical size values, e.g. diameter of a hole or conduit, area, volume, length, width, or ratios thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00083—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP95074A JPS5546403B2 (enExample) | 1973-12-28 | 1973-12-28 | |
| JP7280574A JPS512789A (en) | 1974-06-27 | 1974-06-27 | Jugonetsuno jokyohoho |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2461104A1 DE2461104A1 (de) | 1975-07-03 |
| DE2461104B2 DE2461104B2 (de) | 1980-01-31 |
| DE2461104C3 true DE2461104C3 (de) | 1980-09-18 |
Family
ID=26334064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2461104A Expired DE2461104C3 (de) | 1973-12-28 | 1974-12-23 | Verfahren zum Abführen von Wärme während der Methylmethacrylat-Massepolymerisation und Vorrichtung zur Durchführung des Verfahrens |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3968090A (enExample) |
| DE (1) | DE2461104C3 (enExample) |
| FR (1) | FR2256177B1 (enExample) |
| GB (1) | GB1477189A (enExample) |
| IT (1) | IT1028033B (enExample) |
| NL (1) | NL157321B (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4175176A (en) * | 1977-06-03 | 1979-11-20 | Asahi Kasei Kogyo Kabusihiki Kaisha | Solvent resistant acrylic resin composition |
| DE3803406C2 (de) * | 1988-02-05 | 1997-02-13 | Roehm Gmbh | Verfahren zur Trennung von Methanol-Methylmethacrylat-Mischungen |
| JPH0676448B2 (ja) * | 1988-06-25 | 1994-09-28 | 三菱レイヨン株式会社 | 改質されたメタクリル系樹脂成形材料の製造方法 |
| JPH06501510A (ja) * | 1990-11-08 | 1994-02-17 | ザ ダウ ケミカル カンパニー | 溶液重合法用のフォーム剪断手段を有する反応器 |
| US5120805A (en) * | 1991-06-05 | 1992-06-09 | The Dow Chemical Company | Reactor with surface agitator for solution polymerization process |
| TW366351B (en) * | 1994-12-26 | 1999-08-11 | Mitsui Chemicals Inc | Production process of acrylonitrile (co)polymers |
| CA2167247A1 (en) * | 1995-01-24 | 1996-07-25 | Chi-Wai Hui | Method for controlling reaction temperature |
| AU2003271645A1 (en) * | 2002-09-25 | 2004-04-19 | Shell Internationale Research Maatschappij B.V. | Process for making a linear alpha-olefin oligomer using a heat exchanger |
| EP1542946A1 (en) * | 2002-09-25 | 2005-06-22 | Shell Internationale Researchmaatschappij B.V. | Process for making a linear alpha-olefin oligomer using a heat exchanger |
| JP6441211B2 (ja) | 2013-03-11 | 2018-12-19 | 住友精化株式会社 | 吸水性樹脂の製造装置 |
| SG11201705239SA (en) | 2014-12-29 | 2017-07-28 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| WO2016109265A1 (en) | 2014-12-29 | 2016-07-07 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| KR102034973B1 (ko) * | 2015-09-29 | 2019-10-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 스파이럴 열교환기를 사용하는 중합 |
| CN105251428A (zh) * | 2015-10-30 | 2016-01-20 | 蓝龙飞 | 反应釜 |
| EP4139031B1 (en) * | 2020-04-20 | 2025-10-08 | Metso Finland Oy | Mixing arrangement, mixer settler unit and use |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3439065A (en) * | 1961-03-15 | 1969-04-15 | Shell Oil Co | Bulk polymerization of vinyl aromatic compounds in presence of a minor amount of water |
-
1974
- 1974-12-23 NL NL7416767.A patent/NL157321B/xx not_active IP Right Cessation
- 1974-12-23 DE DE2461104A patent/DE2461104C3/de not_active Expired
- 1974-12-23 US US05/535,489 patent/US3968090A/en not_active Expired - Lifetime
- 1974-12-24 IT IT7431000A patent/IT1028033B/it active
- 1974-12-24 GB GB5581674A patent/GB1477189A/en not_active Expired
- 1974-12-30 FR FR7443304A patent/FR2256177B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2256177B1 (enExample) | 1978-12-08 |
| DE2461104A1 (de) | 1975-07-03 |
| IT1028033B (it) | 1979-01-30 |
| GB1477189A (en) | 1977-06-22 |
| DE2461104B2 (de) | 1980-01-31 |
| NL157321B (nl) | 1978-07-17 |
| NL7416767A (nl) | 1975-07-01 |
| US3968090A (en) | 1976-07-06 |
| FR2256177A1 (enExample) | 1975-07-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |