DE2456813A1 - Hydrophiler schaumstoff auf polyurethanbasis - Google Patents
Hydrophiler schaumstoff auf polyurethanbasisInfo
- Publication number
- DE2456813A1 DE2456813A1 DE19742456813 DE2456813A DE2456813A1 DE 2456813 A1 DE2456813 A1 DE 2456813A1 DE 19742456813 DE19742456813 DE 19742456813 DE 2456813 A DE2456813 A DE 2456813A DE 2456813 A1 DE2456813 A1 DE 2456813A1
- Authority
- DE
- Germany
- Prior art keywords
- polyurethane
- foam
- water
- diisocyanate
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000006260 foam Substances 0.000 title claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 11
- 239000011496 polyurethane foam Substances 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- 238000005299 abrasion Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- -1 polytetramethylene Polymers 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 229940035437 1,3-propanediol Drugs 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 229940093476 ethylene glycol Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/60—Compositions for foaming; Foamed or intumescent coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/901—Cellular polymer containing a carbodiimide structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/273—Coating or impregnation provides wear or abrasion resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/647—Including a foamed layer or component
- Y10T442/652—Nonwoven fabric is coated, impregnated, or autogenously bonded
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Laminated Bodies (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742456813 DE2456813A1 (de) | 1974-11-30 | 1974-11-30 | Hydrophiler schaumstoff auf polyurethanbasis |
| ZA00756131A ZA756131B (en) | 1974-11-30 | 1975-09-26 | Hydrophilic polyurethane foam material |
| AU85299/75A AU491468B2 (en) | 1974-11-30 | 1975-09-30 | Hydrophilic foam material onthe basis of polyurethane |
| ES441541A ES441541A1 (es) | 1974-11-30 | 1975-10-07 | Procedimiento de obtencion de material de espuma hidrofilo abase de poliuretano. |
| AR260791A AR210336A1 (es) | 1974-11-30 | 1975-10-14 | Material espumoso hidrofilo a base de polieretano |
| GB46979/75A GB1530909A (en) | 1974-11-30 | 1975-11-14 | Polyurethane foam |
| US05/635,185 US4181770A (en) | 1974-11-30 | 1975-11-25 | Isocyanate-terminated branched polyethylene glycol and polyester polyurethane foams |
| JP50141526A JPS5177697A (enExample) | 1974-11-30 | 1975-11-26 | |
| FR7536596A FR2292723A1 (fr) | 1974-11-30 | 1975-11-28 | Mousse hydrophile a base de polyurethanne, et articles planiformes formes a partir de cette mousse |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742456813 DE2456813A1 (de) | 1974-11-30 | 1974-11-30 | Hydrophiler schaumstoff auf polyurethanbasis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2456813A1 true DE2456813A1 (de) | 1976-06-10 |
Family
ID=5932233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742456813 Ceased DE2456813A1 (de) | 1974-11-30 | 1974-11-30 | Hydrophiler schaumstoff auf polyurethanbasis |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4181770A (enExample) |
| JP (1) | JPS5177697A (enExample) |
| AR (1) | AR210336A1 (enExample) |
| DE (1) | DE2456813A1 (enExample) |
| ES (1) | ES441541A1 (enExample) |
| FR (1) | FR2292723A1 (enExample) |
| GB (1) | GB1530909A (enExample) |
| ZA (1) | ZA756131B (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1087800A (en) * | 1975-07-18 | 1980-10-14 | Nelson S. Marans | Biodegradable hydrophilic polyurethane foams and method |
| US4254177A (en) * | 1979-05-07 | 1981-03-03 | W. R. Grace & Co. | Fire-retardant product and method of making |
| US4314034A (en) * | 1980-12-29 | 1982-02-02 | W. R. Grace & Co. | Polyurea polyurethane foamed sponge with high wet strength |
| US4439473A (en) * | 1982-09-30 | 1984-03-27 | Jerry Lippman | Hydrophobic foam fabric coating |
| US4756316A (en) * | 1985-08-12 | 1988-07-12 | Philip Morris Incorporated | Method for producing a cigarette filter rod |
| GB9022194D0 (en) * | 1990-10-12 | 1990-11-28 | Ici Plc | Method for preparing polyurea-polyurethane flexible foams |
| US5104693A (en) * | 1990-12-20 | 1992-04-14 | The Dow Chemical Company | Polyurethane carpet-backing process based on soft segment prepolymers of diphenylmethane diisocyanate (MDI) |
| CN1176137C (zh) * | 2002-01-15 | 2004-11-17 | 泛亚生物技术有限公司 | 多臂树杈型功能化聚乙二醇制备方法及它在药物中的应用 |
| US7144978B2 (en) * | 2002-01-15 | 2006-12-05 | Pan Asia Bio Co., Ltd. | Multidrop tree branching functional polyethylene glycol, methods of preparing and using same |
| DE102015005089A1 (de) * | 2015-04-22 | 2016-10-27 | Carl Freudenberg Kg | Thermisch fixierbares Flächengebilde |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3152162A (en) * | 1959-07-29 | 1964-10-06 | Bayer Ag | Polyisocyanate-carbodiimide adducts and process for the production thereof |
| CH433740A (fr) * | 1964-10-14 | 1967-04-15 | Elekal Societe Anonyme | Procédé de fabrication d'une mousse hydrophile de polyuréthane |
| US3454530A (en) * | 1966-03-07 | 1969-07-08 | Leslie C Case | Novel polyols which are reaction products of a monoepoxide and a cyclic monoanhydride |
| US3806473A (en) * | 1968-08-14 | 1974-04-23 | Inter Polymer Res Corp | Polyurethane foams based on liquid poly(e-caprolactone)polyester polyols |
| US3806474A (en) * | 1970-11-23 | 1974-04-23 | Princeton Polymer Sponge Corp | Hydrophilic polyester urethane foam |
| US3748217A (en) * | 1971-02-24 | 1973-07-24 | Burlington Industries Inc | Lined textile fabric and method of manufacture |
| DE2127502A1 (de) * | 1971-06-03 | 1972-12-28 | Bayer | Verfahren zur Herstellung von gegebenenfalls zellförmigen Isocyanuratgruppen aufweisenden Kunststoffen |
| US3775354A (en) * | 1972-02-29 | 1973-11-27 | Inter Polymer Res Corp | Polyurethane elastomers based on poly(epsilon-caprolactone)polyols |
| CA1042600A (en) * | 1972-05-03 | 1978-11-14 | Louis L. Wood | Crosslinked hydrophilic polyurethane foams |
| US3962512A (en) * | 1972-05-22 | 1976-06-08 | Industrie Pirelli S.P.A. | Composite laminar structure and relative manufacturing process |
| US3778390A (en) * | 1972-07-17 | 1973-12-11 | Procter & Gamble | Hydrolytically unstable polyurethane foams |
| GB1406511A (en) * | 1973-01-19 | 1975-09-17 | Ici Ltd | Cellular polyurethanes |
| US3859162A (en) * | 1973-05-11 | 1975-01-07 | Minnesota Mining & Mfg | Pre-preg materials, chemically integral composite foam structures prepared therefrom, and methods of preparation |
| US3929730A (en) * | 1973-12-28 | 1975-12-30 | Inter Polymer Res Corp | Process for preparing polyurethanes employing a mixture of butanediol and phenylene diethanolamine as a chain extender |
| US4006122A (en) * | 1974-03-11 | 1977-02-01 | The Upjohn Company | Polyester-amides prepared from polymalonates and isocyanates |
| DE2441843C3 (de) * | 1974-05-22 | 1980-12-04 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von, zur Herstellung von hydrophilen Polyurethanschaumstoffen geeigneten, modifizierten, Ammoniumgruppen aufweisenden Polyisocyanaten und deren Verwendung |
-
1974
- 1974-11-30 DE DE19742456813 patent/DE2456813A1/de not_active Ceased
-
1975
- 1975-09-26 ZA ZA00756131A patent/ZA756131B/xx unknown
- 1975-10-07 ES ES441541A patent/ES441541A1/es not_active Expired
- 1975-10-14 AR AR260791A patent/AR210336A1/es active
- 1975-11-14 GB GB46979/75A patent/GB1530909A/en not_active Expired
- 1975-11-25 US US05/635,185 patent/US4181770A/en not_active Expired - Lifetime
- 1975-11-26 JP JP50141526A patent/JPS5177697A/ja active Pending
- 1975-11-28 FR FR7536596A patent/FR2292723A1/fr not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| AR210336A1 (es) | 1977-07-29 |
| ZA756131B (en) | 1976-09-29 |
| FR2292723A1 (fr) | 1976-06-25 |
| ES441541A1 (es) | 1977-08-16 |
| AU8529975A (en) | 1977-04-21 |
| JPS5177697A (enExample) | 1976-07-06 |
| US4181770A (en) | 1980-01-01 |
| GB1530909A (en) | 1978-11-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8131 | Rejection |