DE2456329C2 - Verfahren zur Entmetallisierung von Kohlenwasserstoffrückstandsölen - Google Patents
Verfahren zur Entmetallisierung von KohlenwasserstoffrückstandsölenInfo
- Publication number
- DE2456329C2 DE2456329C2 DE2456329A DE2456329A DE2456329C2 DE 2456329 C2 DE2456329 C2 DE 2456329C2 DE 2456329 A DE2456329 A DE 2456329A DE 2456329 A DE2456329 A DE 2456329A DE 2456329 C2 DE2456329 C2 DE 2456329C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- weight
- demetallization
- parts
- vanadium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 29
- 239000003921 oil Substances 0.000 title claims description 11
- 125000001183 hydrocarbyl group Chemical group 0.000 title claims description 7
- 239000003054 catalyst Substances 0.000 claims description 151
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 74
- 239000011148 porous material Substances 0.000 claims description 50
- 239000000463 material Substances 0.000 claims description 47
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 46
- 239000000377 silicon dioxide Substances 0.000 claims description 37
- 235000012239 silicon dioxide Nutrition 0.000 claims description 34
- 229910052720 vanadium Inorganic materials 0.000 claims description 30
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 150000002739 metals Chemical class 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 230000003197 catalytic effect Effects 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 238000004523 catalytic cracking Methods 0.000 claims description 2
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 description 19
- 229910052681 coesite Inorganic materials 0.000 description 16
- 229910052906 cristobalite Inorganic materials 0.000 description 16
- 238000001035 drying Methods 0.000 description 16
- 229910052682 stishovite Inorganic materials 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 229910052905 tridymite Inorganic materials 0.000 description 16
- 230000000694 effects Effects 0.000 description 10
- 238000001354 calcination Methods 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000007717 exclusion Effects 0.000 description 5
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 3
- 229940010552 ammonium molybdate Drugs 0.000 description 3
- 235000018660 ammonium molybdate Nutrition 0.000 description 3
- 239000011609 ammonium molybdate Substances 0.000 description 3
- 238000005029 sieve analysis Methods 0.000 description 3
- 238000002336 sorption--desorption measurement Methods 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000005287 vanadyl group Chemical group 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3196672 | 1972-07-07 | ||
| GB1052873*[A GB1438645A (en) | 1972-07-07 | 1973-03-05 | Hydrocarbon conversion process |
| NLAANVRAGE7316396,A NL177609C (nl) | 1972-07-07 | 1973-11-30 | Verbeterde werkwijze voor het katalytisch omzetten van een residuale koolwaterstofolie, waarbij de olie voor de katalytische omzetting eerst katalytisch wordt gedemetalliseerd. |
| NL7410162A NL7410162A (en) | 1972-07-07 | 1974-07-29 | Demetallisation of residual oils - with metal-silica catalysts with specified pore characteristics and a low loss on ignition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2456329A1 DE2456329A1 (de) | 1975-06-05 |
| DE2456329C2 true DE2456329C2 (de) | 1987-03-26 |
Family
ID=27448050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2456329A Expired DE2456329C2 (de) | 1972-07-07 | 1974-11-28 | Verfahren zur Entmetallisierung von Kohlenwasserstoffrückstandsölen |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE822444R (pt) |
| DE (1) | DE2456329C2 (pt) |
| FR (1) | FR2253080B2 (pt) |
| GB (1) | GB1458755A (pt) |
-
1974
- 1974-11-21 BE BE1006288A patent/BE822444R/xx active
- 1974-11-28 FR FR7439045A patent/FR2253080B2/fr not_active Expired
- 1974-11-28 GB GB5156374A patent/GB1458755A/en not_active Expired
- 1974-11-28 DE DE2456329A patent/DE2456329C2/de not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2253080A2 (pt) | 1975-06-27 |
| GB1458755A (en) | 1976-12-15 |
| DE2456329A1 (de) | 1975-06-05 |
| BE822444R (nl) | 1975-05-21 |
| FR2253080B2 (pt) | 1979-06-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69521993T2 (de) | Hochaktive katalysatoren | |
| DE69423106T2 (de) | Wasserstoffbehandlungskatalysator und seine verwendung | |
| DE2930357C2 (pt) | ||
| DE3446038C2 (pt) | ||
| DE3125339C2 (pt) | ||
| DE2246703C2 (de) | Katalysator und seine Verwendung zur Hydrobehandlung oder Hydroentschwefelung | |
| DE69732660T2 (de) | Katalysator zur wasserstoffbehandlung von schwerölen, verfahren zu seiner herstellung, sowie verwendung des katalysators in einem wasserstoffbehandlungsverfahren | |
| DE2164562A1 (de) | Hydroraffinierungskatalysator, Verfahren zu dessen Herstellung und dessen Verwendung | |
| DE69005191T2 (de) | Wasserstoffbehandlungsverfahren. | |
| DE68921025T2 (de) | Hydrierungskatalysator, seine Herstellung und seine Verwendung. | |
| DE2827747A1 (de) | Grossporiger hydro-demetallisierungskatalysator und verfahren unter verwendung desselben | |
| DE2330385A1 (de) | Verfahren zum hydrierenden entschwefeln von rohoel, abgetopptem rohoel oder schwerem gasoel | |
| DE2252332A1 (de) | Katalysator aus einem oder mehreren hydrierungsaktiven metallen auf einem traegermaterial, verfahren zu seiner herstellung und seine verwendung | |
| DE69504657T2 (de) | Mehrschicht katalysatorbed anordnung für tiefhydroentschwefelung | |
| DE69112016T2 (de) | Träger-Katalysatoren für Hydrierung und Wasserstoffbehandlung und Verfahren. | |
| DE3440669A1 (de) | Formgestaltete katalysatorteilchen zur verwendung bei der hydrierenden verarbeitung von erdoelen | |
| DE2512294C2 (pt) | ||
| DE2541306C2 (pt) | ||
| DD140894A5 (de) | Verfahren zur hydrobehandlung von schweren kohlenwasserstoffstroemen | |
| DE2511202A1 (de) | Katalysatoren fuer die hydrierende entschwefelung von kohlenwasserstoffen | |
| DE2515919C2 (de) | Verfahren zur katalytischen hydrierenden Entschwefelung von Vanadium und Nickel enthaltenden Kohlenwasserstoff- Rückstandsölen ohne Katalysatornachbeschickung | |
| DE3314192A1 (de) | Verfahren zur herstellung eines hydrocrackkatalysators | |
| DE2739869C2 (pt) | ||
| DE2456329C2 (de) | Verfahren zur Entmetallisierung von Kohlenwasserstoffrückstandsölen | |
| DE2334293C2 (de) | Verfahren zur katalytischen Entmetallisierung von Kohlenwasserstoffrückstandsölen und anschließende katalytische Hydrospaltung, katalytische hydrierende Entschwefelung oder katalytische Spaltung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8126 | Change of the secondary classification |
Ipc: C10M 11/00 |
|
| AF | Is addition to no. |
Ref country code: DE Ref document number: 2334293 Format of ref document f/p: P |
|
| 8110 | Request for examination paragraph 44 | ||
| 8162 | Independent application | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |