DE2442537A1 - Kathodenmaterial - Google Patents
KathodenmaterialInfo
- Publication number
- DE2442537A1 DE2442537A1 DE2442537A DE2442537A DE2442537A1 DE 2442537 A1 DE2442537 A1 DE 2442537A1 DE 2442537 A DE2442537 A DE 2442537A DE 2442537 A DE2442537 A DE 2442537A DE 2442537 A1 DE2442537 A1 DE 2442537A1
- Authority
- DE
- Germany
- Prior art keywords
- hexaboride
- work function
- phase
- cathode material
- electron emission
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010406 cathode material Substances 0.000 title claims description 21
- 239000000463 material Substances 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 229910052727 yttrium Inorganic materials 0.000 description 18
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000010894 electron beam technology Methods 0.000 description 8
- 229910052746 lanthanum Inorganic materials 0.000 description 8
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052693 Europium Inorganic materials 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- -1 yttrium ions Chemical class 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 108010083687 Ion Pumps Proteins 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- PXMLGXWGOVHNQX-UHFFFAOYSA-N [Y].[Eu] Chemical compound [Y].[Eu] PXMLGXWGOVHNQX-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910002059 quaternary alloy Inorganic materials 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- FERAQKHYRHQYKD-UHFFFAOYSA-N yttrium(3+);borate Chemical compound [Y+3].[O-]B([O-])[O-] FERAQKHYRHQYKD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/14—Solid thermionic cathodes characterised by the material
- H01J1/148—Solid thermionic cathodes characterised by the material with compounds having metallic conductive properties, e.g. lanthanum boride, as an emissive material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/30—Cold cathodes, e.g. field-emissive cathode
- H01J1/304—Field-emissive cathodes
Landscapes
- Solid Thermionic Cathode (AREA)
- Cold Cathode And The Manufacture (AREA)
- Ceramic Products (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9923173A JPS5249305B2 (cg-RX-API-DMAC10.html) | 1973-09-05 | 1973-09-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2442537A1 true DE2442537A1 (de) | 1975-05-07 |
Family
ID=14241888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2442537A Pending DE2442537A1 (de) | 1973-09-05 | 1974-09-05 | Kathodenmaterial |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3932314A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5249305B2 (cg-RX-API-DMAC10.html) |
| DE (1) | DE2442537A1 (cg-RX-API-DMAC10.html) |
| NL (1) | NL7411822A (cg-RX-API-DMAC10.html) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4055780A (en) * | 1975-04-10 | 1977-10-25 | National Institute For Researches In Inorganic Materials | Thermionic emission cathode having a tip of a single crystal of lanthanum hexaboride |
| US4054946A (en) * | 1976-09-28 | 1977-10-18 | Bell Telephone Laboratories, Incorporated | Electron source of a single crystal of lanthanum hexaboride emitting surface of (110) crystal plane |
| US4200555A (en) * | 1978-07-27 | 1980-04-29 | Bell Telephone Laboratories, Incorporated | Low work function hexaboride electron source |
| US4260525A (en) * | 1978-11-27 | 1981-04-07 | Rca Corporation | Single-crystal hexaborides and method of preparation |
| US4885211A (en) * | 1987-02-11 | 1989-12-05 | Eastman Kodak Company | Electroluminescent device with improved cathode |
| JPH0736361B2 (ja) * | 1989-03-22 | 1995-04-19 | 株式会社村田製作所 | 抵抗材料、その製造方法およびそれを用いた抵抗ペースト |
| US20050208218A1 (en) * | 1999-08-21 | 2005-09-22 | Ibadex Llc. | Method for depositing boron-rich coatings |
| US8501136B2 (en) * | 2006-02-06 | 2013-08-06 | The University Of North Carolina At Chapel Hill | Synthesis and processing of rare-earth boride nanowires as electron emitters |
| CN112723891B (zh) * | 2021-01-27 | 2023-07-25 | 合肥工业大学 | 一种镧钙复合六硼化物多晶阴极材料及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3312856A (en) * | 1963-03-26 | 1967-04-04 | Gen Electric | Rhenium supported metallic boride cathode emitters |
| GB1232523A (cg-RX-API-DMAC10.html) * | 1968-07-16 | 1971-05-19 |
-
1973
- 1973-09-05 JP JP9923173A patent/JPS5249305B2/ja not_active Expired
-
1974
- 1974-09-05 DE DE2442537A patent/DE2442537A1/de active Pending
- 1974-09-05 NL NL7411822A patent/NL7411822A/xx unknown
- 1974-09-05 US US05/503,471 patent/US3932314A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3932314A (en) | 1976-01-13 |
| JPS5249305B2 (cg-RX-API-DMAC10.html) | 1977-12-16 |
| NL7411822A (nl) | 1975-03-07 |
| JPS5050856A (cg-RX-API-DMAC10.html) | 1975-05-07 |
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