DE2433772C3 - Druckempfindliches Durchschreibpapier - Google Patents
Druckempfindliches DurchschreibpapierInfo
- Publication number
- DE2433772C3 DE2433772C3 DE19742433772 DE2433772A DE2433772C3 DE 2433772 C3 DE2433772 C3 DE 2433772C3 DE 19742433772 DE19742433772 DE 19742433772 DE 2433772 A DE2433772 A DE 2433772A DE 2433772 C3 DE2433772 C3 DE 2433772C3
- Authority
- DE
- Germany
- Prior art keywords
- acid
- paper
- pressure
- parts
- electron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 26
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 21
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 15
- 239000011247 coating layer Substances 0.000 claims description 11
- 239000003094 microcapsule Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 150000001299 aldehydes Chemical class 0.000 claims description 7
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 7
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 7
- 235000006408 oxalic acid Nutrition 0.000 claims description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 239000001361 adipic acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 33
- -1 aromatic carboxylic acids Chemical class 0.000 description 26
- 239000000203 mixture Substances 0.000 description 23
- 239000010410 layer Substances 0.000 description 22
- 229960004889 salicylic acid Drugs 0.000 description 21
- 239000002253 acid Substances 0.000 description 20
- 230000002378 acidificating effect Effects 0.000 description 19
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000007787 solid Substances 0.000 description 13
- 239000008199 coating composition Substances 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 11
- 150000002739 metals Chemical class 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000004927 clay Substances 0.000 description 7
- 239000000376 reactant Substances 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 239000002174 Styrene-butadiene Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000011115 styrene butadiene Substances 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- AKEUNCKRJATALU-UHFFFAOYSA-N 2,6-dihydroxybenzoic acid Chemical compound OC(=O)C1=C(O)C=CC=C1O AKEUNCKRJATALU-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000004679 hydroxides Chemical class 0.000 description 4
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 3
- WHSXTWFYRGOBGO-UHFFFAOYSA-N 3-methylsalicylic acid Chemical compound CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- LULAYUGMBFYYEX-UHFFFAOYSA-N 3-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1 LULAYUGMBFYYEX-UHFFFAOYSA-N 0.000 description 2
- JWQFKVGACKJIAV-UHFFFAOYSA-N 5-[(3-carboxy-4-hydroxyphenyl)methyl]-2-hydroxybenzoic acid Chemical compound C1=C(O)C(C(=O)O)=CC(CC=2C=C(C(O)=CC=2)C(O)=O)=C1 JWQFKVGACKJIAV-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- LCPDWSOZIOUXRV-UHFFFAOYSA-N phenoxyacetic acid Chemical compound OC(=O)COC1=CC=CC=C1 LCPDWSOZIOUXRV-UHFFFAOYSA-N 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 1
- HVDYZXLLPNGAGU-UHFFFAOYSA-N 1,4-bis(dimethylamino)-3-phenylnaphthalene-2-carboxylic acid Chemical compound CN(C)C=1C2=CC=CC=C2C(N(C)C)=C(C(O)=O)C=1C1=CC=CC=C1 HVDYZXLLPNGAGU-UHFFFAOYSA-N 0.000 description 1
- QAOJBHRZQQDFHA-UHFFFAOYSA-N 2,3-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1Cl QAOJBHRZQQDFHA-UHFFFAOYSA-N 0.000 description 1
- YKMDNKRCCODWMG-UHFFFAOYSA-N 2,5-dinitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC=C1[N+]([O-])=O YKMDNKRCCODWMG-UHFFFAOYSA-N 0.000 description 1
- CGVQQJFDFFCHLV-UHFFFAOYSA-N 2-(4-methylbenzoyl)-6-nitrobenzoic acid Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC([N+]([O-])=O)=C1C(O)=O CGVQQJFDFFCHLV-UHFFFAOYSA-N 0.000 description 1
- XRXMNWGCKISMOH-UHFFFAOYSA-N 2-bromobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1Br XRXMNWGCKISMOH-UHFFFAOYSA-N 0.000 description 1
- VQEKSOLICHLCHS-UHFFFAOYSA-N 2-chloro-5-phenylbenzoic acid Chemical compound C1=C(Cl)C(C(=O)O)=CC(C=2C=CC=CC=2)=C1 VQEKSOLICHLCHS-UHFFFAOYSA-N 0.000 description 1
- IKCLCGXPQILATA-UHFFFAOYSA-N 2-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1Cl IKCLCGXPQILATA-UHFFFAOYSA-N 0.000 description 1
- VETYJSJUELVXQU-UHFFFAOYSA-N 2-hydroxy-3-methyl-5-phenylbenzoic acid Chemical compound OC(=O)C1=C(O)C(C)=CC(C=2C=CC=CC=2)=C1 VETYJSJUELVXQU-UHFFFAOYSA-N 0.000 description 1
- ZJWUEJOPKFYFQD-UHFFFAOYSA-N 2-hydroxy-3-phenylbenzoic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1O ZJWUEJOPKFYFQD-UHFFFAOYSA-N 0.000 description 1
- UQKVQPWUSGPMCO-UHFFFAOYSA-N 2-hydroxy-4-(4-nitrophenyl)benzoic acid Chemical compound C1=C(O)C(C(=O)O)=CC=C1C1=CC=C([N+]([O-])=O)C=C1 UQKVQPWUSGPMCO-UHFFFAOYSA-N 0.000 description 1
- ILQOWJVBLNBGAF-UHFFFAOYSA-N 2-hydroxy-5-(3-methylbutyl)benzoic acid Chemical compound CC(C)CCC1=CC=C(O)C(C(O)=O)=C1 ILQOWJVBLNBGAF-UHFFFAOYSA-N 0.000 description 1
- UPHOPMSGKZNELG-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=C(O)C=CC2=C1 UPHOPMSGKZNELG-UHFFFAOYSA-N 0.000 description 1
- CJNZAXGUTKBIHP-UHFFFAOYSA-N 2-iodobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1I CJNZAXGUTKBIHP-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- VYWYYJYRVSBHJQ-UHFFFAOYSA-N 3,5-dinitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 VYWYYJYRVSBHJQ-UHFFFAOYSA-N 0.000 description 1
- BUEUCOZZVOFJIF-UHFFFAOYSA-N 3-(3-carboxy-2-nitrophenyl)-2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC(C=2C(=C(C(O)=O)C=CC=2)[N+]([O-])=O)=C1[N+]([O-])=O BUEUCOZZVOFJIF-UHFFFAOYSA-N 0.000 description 1
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- RRZWUACTOVQIJX-UHFFFAOYSA-N 3-[(3-carboxyphenyl)methyl]-2-nitrobenzoic acid Chemical compound OC(=O)c1cccc(Cc2cccc(C(O)=O)c2[N+]([O-])=O)c1 RRZWUACTOVQIJX-UHFFFAOYSA-N 0.000 description 1
- VOIZNVUXCQLQHS-UHFFFAOYSA-N 3-bromobenzoic acid Chemical compound OC(=O)C1=CC=CC(Br)=C1 VOIZNVUXCQLQHS-UHFFFAOYSA-N 0.000 description 1
- KVBWBCRPWVKFQT-UHFFFAOYSA-N 3-iodobenzoic acid Chemical compound OC(=O)C1=CC=CC(I)=C1 KVBWBCRPWVKFQT-UHFFFAOYSA-N 0.000 description 1
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N 3-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1 AFPHTEQTJZKQAQ-UHFFFAOYSA-N 0.000 description 1
- ZNEHUMUKYCBTFA-UHFFFAOYSA-N 4-(3-carboxy-2-hydroxyphenyl)-3-hydroxynaphthalene-2-carboxylic acid Chemical compound OC(=O)C1=CC=CC(C=2C3=CC=CC=C3C=C(C=2O)C(O)=O)=C1O ZNEHUMUKYCBTFA-UHFFFAOYSA-N 0.000 description 1
- NHIVYACMROFPGR-UHFFFAOYSA-N 4-(4-carboxy-3-hydroxyphenyl)-2-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=C(O)C(C(=O)O)=CC=C1C1=CC(O)=C(C(O)=O)C2=CC=CC=C12 NHIVYACMROFPGR-UHFFFAOYSA-N 0.000 description 1
- QBHDSQZASIBAAI-UHFFFAOYSA-N 4-acetylbenzoic acid Chemical compound CC(=O)C1=CC=C(C(O)=O)C=C1 QBHDSQZASIBAAI-UHFFFAOYSA-N 0.000 description 1
- QDELZOMAWUALGF-UHFFFAOYSA-N 4-benzoyl-3-hydroxynaphthalene-2-carboxylic acid Chemical compound OC=1C(C(=O)O)=CC2=CC=CC=C2C=1C(=O)C1=CC=CC=C1 QDELZOMAWUALGF-UHFFFAOYSA-N 0.000 description 1
- IHYOYFVKBXZDJE-UHFFFAOYSA-N 4-benzyl-3-hydroxynaphthalene-2-carboxylic acid Chemical compound OC=1C(C(=O)O)=CC2=CC=CC=C2C=1CC1=CC=CC=C1 IHYOYFVKBXZDJE-UHFFFAOYSA-N 0.000 description 1
- TUXYZHVUPGXXQG-UHFFFAOYSA-N 4-bromobenzoic acid Chemical compound OC(=O)C1=CC=C(Br)C=C1 TUXYZHVUPGXXQG-UHFFFAOYSA-N 0.000 description 1
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- GHICCUXQJBDNRN-UHFFFAOYSA-N 4-iodobenzoic acid Chemical compound OC(=O)C1=CC=C(I)C=C1 GHICCUXQJBDNRN-UHFFFAOYSA-N 0.000 description 1
- BBEWSMNRCUXQRF-UHFFFAOYSA-N 4-methyl-3-nitrobenzoic acid Chemical compound CC1=CC=C(C(O)=O)C=C1[N+]([O-])=O BBEWSMNRCUXQRF-UHFFFAOYSA-N 0.000 description 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 1
- WVADEHDXGNQZNV-UHFFFAOYSA-N 4-tert-butyl-2-nitrobenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C([N+]([O-])=O)=C1 WVADEHDXGNQZNV-UHFFFAOYSA-N 0.000 description 1
- GORPNMWQWXIJAM-UHFFFAOYSA-N 5-(4-chlorophenyl)-2-hydroxybenzoic acid Chemical compound C1=C(O)C(C(=O)O)=CC(C=2C=CC(Cl)=CC=2)=C1 GORPNMWQWXIJAM-UHFFFAOYSA-N 0.000 description 1
- NSBHWABWQYIQND-UHFFFAOYSA-N 5-(4-tert-butylphenyl)-2-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=CC(C(C)(C)C)=CC=C1C1=CC=CC2=C(C(O)=O)C(O)=CC=C12 NSBHWABWQYIQND-UHFFFAOYSA-N 0.000 description 1
- ZARJMPAWIJHLJS-UHFFFAOYSA-N 5-benzoyl-2-hydroxy-4-phenylbenzoic acid Chemical compound C=1C=CC=CC=1C=1C=C(O)C(C(=O)O)=CC=1C(=O)C1=CC=CC=C1 ZARJMPAWIJHLJS-UHFFFAOYSA-N 0.000 description 1
- AFIMKCDXMUVHON-UHFFFAOYSA-N 5-benzyl-2-hydroxybenzoic acid Chemical compound C1=C(O)C(C(=O)O)=CC(CC=2C=CC=CC=2)=C1 AFIMKCDXMUVHON-UHFFFAOYSA-N 0.000 description 1
- QAYNSPOKTRVZRC-UHFFFAOYSA-N 99-60-5 Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1Cl QAYNSPOKTRVZRC-UHFFFAOYSA-N 0.000 description 1
- YIDWDEDWGHUHEB-UHFFFAOYSA-N C#C.OC(=O)C1=CC=CC=C1O Chemical group C#C.OC(=O)C1=CC=CC=C1O YIDWDEDWGHUHEB-UHFFFAOYSA-N 0.000 description 1
- ZOJPPRIZOABVIJ-UHFFFAOYSA-N C(=O)(O)C1=C2C=CC=C(C2=CC=C1)C1=C2C=CC(=C(C2=CC=C1)C(=O)O)O Chemical compound C(=O)(O)C1=C2C=CC=C(C2=CC=C1)C1=C2C=CC(=C(C2=CC=C1)C(=O)O)O ZOJPPRIZOABVIJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JSQJRLDAGVZSRD-UHFFFAOYSA-N OC1=C(C(=C(C2=CC=CC=C12)O)C(C1=CC=CC=C1)=O)C(=O)O Chemical compound OC1=C(C(=C(C2=CC=CC=C12)O)C(C1=CC=CC=C1)=O)C(=O)O JSQJRLDAGVZSRD-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- VUBQYTCIOHLJGQ-UHFFFAOYSA-N acetylene;4-tert-butylphenol Chemical group C#C.CC(C)(C)C1=CC=C(O)C=C1 VUBQYTCIOHLJGQ-UHFFFAOYSA-N 0.000 description 1
- JEKQWTHOOMAFFN-UHFFFAOYSA-N acetylene;benzoic acid Chemical group C#C.OC(=O)C1=CC=CC=C1 JEKQWTHOOMAFFN-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229960004909 aminosalicylic acid Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZCLVNIZJEKLGFA-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxalumolan-2-yl) oxalate Chemical compound [Al+3].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZCLVNIZJEKLGFA-UHFFFAOYSA-H 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- UMGLBLXWFVODRF-UHFFFAOYSA-N formaldehyde;4-phenylphenol Chemical compound O=C.C1=CC(O)=CC=C1C1=CC=CC=C1 UMGLBLXWFVODRF-UHFFFAOYSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- YWPOLRBWRRKLMW-UHFFFAOYSA-M sodium;naphthalene-2-sulfonate Chemical group [Na+].C1=CC=CC2=CC(S(=O)(=O)[O-])=CC=C21 YWPOLRBWRRKLMW-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/155—Colour-developing components, e.g. acidic compounds; Additives or binders therefor; Layers containing such colour-developing components, additives or binders
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Color Printing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7960073A JPS5314006B2 (enrdf_load_stackoverflow) | 1973-07-14 | 1973-07-14 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2433772A1 DE2433772A1 (de) | 1975-01-30 |
| DE2433772B2 DE2433772B2 (de) | 1979-11-15 |
| DE2433772C3 true DE2433772C3 (de) | 1984-01-26 |
Family
ID=13694488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742433772 Expired DE2433772C3 (de) | 1973-07-14 | 1974-07-13 | Druckempfindliches Durchschreibpapier |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS5314006B2 (enrdf_load_stackoverflow) |
| DE (1) | DE2433772C3 (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5841760B2 (ja) * | 1976-05-29 | 1983-09-14 | 神崎製紙株式会社 | 呈色剤の製造方法 |
| ZA786238B (en) * | 1978-01-17 | 1979-10-31 | Mead Corp | Production of pressure-sensitive carbonless record sheets using dioic acid hot melt systems and products thereof |
| JP2639748B2 (ja) * | 1990-10-31 | 1997-08-13 | 富士写真フイルム株式会社 | 感光性エレメントおよびその製造法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2972547A (en) * | 1957-08-05 | 1961-02-21 | Antioch College | Acyl hydrazine compositions and methods of producing color therewith |
| GB1330984A (en) * | 1970-09-28 | 1973-09-19 | Fuji Photo Film Co Ltd | Colour-developer compositions |
-
1973
- 1973-07-14 JP JP7960073A patent/JPS5314006B2/ja not_active Expired
-
1974
- 1974-07-13 DE DE19742433772 patent/DE2433772C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5314006B2 (enrdf_load_stackoverflow) | 1978-05-15 |
| JPS5030615A (enrdf_load_stackoverflow) | 1975-03-26 |
| DE2433772A1 (de) | 1975-01-30 |
| DE2433772B2 (de) | 1979-11-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2800485C2 (enrdf_load_stackoverflow) | ||
| DE2152763C3 (de) | Farbentwickler und diesen enthaltender Aufzeichnungsbogen | |
| DE2348639A1 (de) | Sensibilisiertes blatt fuer ein druckempfindliches kopiersystem und verfahren zu seiner herstellung | |
| EP0016730B1 (de) | Farbentwicklermasse zur Herstellung eines druckempfindlichen Aufzeichnungsmaterials; Farbentwicklungsblatt für druckempfindliches Aufzeichnungsmaterial; druckempfindliches Aufzeichnungsmaterial und Verfahren zu seiner Herstellung | |
| DE2335747C2 (enrdf_load_stackoverflow) | ||
| DE2822961C2 (de) | Druckempfindliches Kopiermaterial | |
| CH628575A5 (de) | Farbentwicklerblatt. | |
| DE3019591A1 (de) | Waermeempfindliches aufzeichnungsmaterial und seine herstellung | |
| EP0171810B1 (de) | Wärmeempfindliches Aufzeichnungsblatt | |
| DE69301527T2 (de) | Wärmeempfindliches Aufzeichnungsblatt | |
| DE2820462C3 (de) | Selbstaufzeichnendes druckempfindliches Papier | |
| DE3843681A1 (de) | Deckueberzugszusammensetzung fuer waermeempfindliche aufzeichnungsmaterialien | |
| DE2433772C3 (de) | Druckempfindliches Durchschreibpapier | |
| DE69023818T2 (de) | Wärmeempfindliches Aufzeichnungsmaterial. | |
| DE2023152C3 (de) | Druckempfindliches Aufzeichnungsmaterial | |
| DE2543598A1 (de) | Aufzeichnungsmaterial | |
| DE2512948B2 (de) | Akzeptormateriai und dieses enthaltendes Kopierpapier | |
| CH658864A5 (de) | Chromogenes fluoranderivat. | |
| DE4124063C2 (de) | Kohlenstofffreies, druckempfindliches Durchschreibpapier | |
| CH666001A5 (de) | Aufzeichnungsmaterial. | |
| DE2152765C3 (de) | Farbentwickler und diesen enthaltender Aufzeichnungsbogen | |
| DE2120920C3 (de) | Sensibilisierter Bogen für druckempfindliche Aufzeichnungsmaterialien | |
| EP0066813B1 (de) | Wärmeempfindliches Aufzeichnungsblatt | |
| DE2407622A1 (de) | Aufzeichnungsbogen | |
| DE69307362T2 (de) | Thermische Aufzeichnungsschicht |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8281 | Inventor (new situation) |
Free format text: TSUCHIYA, HIROSHI, IBARAGI, JP KOUNO, JUJIRO, TAKATSUKI, OSAKA, JP OKAMOTO, TOSAKU, OSAKA, JP |
|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |