DE2428821C3 - Wear-resistant cast iron alloy with lamellar to nodular graphite precipitation - Google Patents
Wear-resistant cast iron alloy with lamellar to nodular graphite precipitationInfo
- Publication number
- DE2428821C3 DE2428821C3 DE19742428821 DE2428821A DE2428821C3 DE 2428821 C3 DE2428821 C3 DE 2428821C3 DE 19742428821 DE19742428821 DE 19742428821 DE 2428821 A DE2428821 A DE 2428821A DE 2428821 C3 DE2428821 C3 DE 2428821C3
- Authority
- DE
- Germany
- Prior art keywords
- wear
- cast iron
- iron alloy
- lamellar
- resistant cast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/10—Cast-iron alloys containing aluminium or silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Heat Treatment Of Articles (AREA)
Description
dadurch gekennzeichnet, daß die Legierung zusätzlich 0,1 bis 2,0% Aluminium und 0,1 bis 4,0% Niob und/oder Tantal enthält.characterized in that the alloy additionally 0.1 to 2.0% aluminum and 0.1 to Contains 4.0% niobium and / or tantalum.
2. Verschleißfeste Gußeisenlegierung nach Anspruch 1, dadurch gekennzeichnet, daß das Verhältnis Siliziumgehalt zu Kohlenstoffgehalt gleich oder größer als 1 ist2. Wear-resistant cast iron alloy according to claim 1, characterized in that the ratio Silicon content to carbon content is equal to or greater than 1
3. Verschleißfeste Gußeisenlegierung nach den Ansprüchen 1 und Z dadurch gekennzeichnet, daß die Summe der Gehalte an Molybdän, Wolfram und' oder Mangan zwischen 0,2 und 10% liegt.3. Wear-resistant cast iron alloy according to claims 1 and Z, characterized in that the sum of the contents of molybdenum, tungsten and 'or manganese is between 0.2 and 10%.
4. Verschleißfeste Gußeisenlegierung nach den .Ansprüchen ! bis 3, dadurch gekennzeichnet, daß die Summe der Gehalte an Chrom, Vanadium, Tantal und/oder Niob zwischen 1 und 10% liegt.4. Wear-resistant cast iron alloy according to the requirements! to 3, characterized in that the The sum of the chromium, vanadium, tantalum and / or niobium contents is between 1 and 10%.
5. Verschleißfeste Gußeisenlegierung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Legierung Bor, Wismut, Zirkonium und/oder seltene Erden bis zu einer Summe von 0,5 Prozent enthält. 5. Wear-resistant cast iron alloy according to one of claims 1 to 4, characterized in that the alloy contains boron, bismuth, zirconium and / or rare earths up to a total of 0.5 percent.
6. Verschleißfeste Gußeisenlegierung nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Legierung durch Glühen oberhalb 700° C, durch Abschrecken auf unter 500°C und anschließend durch Anlassen bis zu einer Temperatur von 700° C wärmebehandelt ist.6. Wear-resistant cast iron alloy according to one of claims 1 to 5, characterized in that the alloy by annealing above 700 ° C, by quenching to below 500 ° C and then is heat-treated by tempering up to a temperature of 700 ° C.
7. Verwendung einer Gußeisenlegierung nach einem der Ansprüche 1 bis 6 als Werkstoff zur Herstellung von hoch auf Reibung beanspruchte Maschinenteile wie Kolbenringe von Verbrennungskraftmaschinen, insbesondere Feuerringe und Dichtleisten von Rotationskolbenmotoren.7. Use of a cast iron alloy according to one of claims 1 to 6 as a material for production Machine parts subject to high friction such as piston rings of internal combustion engines, in particular fire rings and sealing strips of rotary piston engines.
Die Erfindung betrifft eine hochverschleißfeste, Gußeisenlegierung mit lamellarer bis knötchenförmiger Graphitausscheidung.The invention relates to a highly wear-resistant cast iron alloy with lamellar to nodular graphite precipitation.
Reibend beanspruchte Maschinenelemente werden sowohl verschleißmiißig als auch thermisch stark belastet, so daß iin ihre Werkstoffe besonders hohe Anforderungen gestellt werden müssen. Bestimmte Maschinenelemente, wie beispielsweise Kolbenringe von Verbrennungskraftmaschinen, und zwar insbesondere Feuerringe, aber auch Dichtleistcn von Rotationskolbenmaschinen, stehen darüber hinaus unter besonders starker Belastung. Die Erfahrung hat gezeigt, daß diesen hohen Beanspruchungen nur sehr teure und kompliziert hergestellte Werkstoffe gewachsen sind. Dabei handelt es sich üblicherweise um Sinterhartmetalle, denen ganz definierte Legierungselemente zugegeben worden sind.Machine elements that are subjected to frictional loads are subject to high wear and tear as well as high thermal loads, so that their materials have to meet particularly high requirements must be asked. Certain machine elements, such as piston rings in internal combustion engines, in particular fire rings, but also sealing strips of rotary piston machines, are also under particularly heavy loads. Experience has shown that this high Only very expensive and complexly manufactured materials can cope with stresses. It is about usually sintered carbides to which very defined alloying elements have been added.
Die bisher erprobten Gußeisensorten sind aber für diese hochbeanspruchten Maschinenteile nicht einscizbar. Es ist bekannt, die Verschleißfestigkeit von GuBcisensorten durch Zugabe von Legicrungselcmcntcn zu steigern. Diese Elemente jedoch bilden beim Erstarren des Gußeisens relativ grobkörnige und sehr harte Karbide, die dann auf den Gegenlaufflächen unter Riefenbildung Zerstörungen hervorrufen. Gleichzeitig wird durch die Karbidbildung der größte Teil des Kohlenstoffes verbraucht, so daß diesen Legierungen der für den Notlauf dieser Maschinenelemente notwendige Graphit im Gefüge fehlt Weiterhin sind diese Werkstoffe so spröde, daß sie auch mechanischen Beanspruchungen nicht gewachsen sind und brechen.The cast iron grades that have been tried out so far cannot, however, be scaled for these highly stressed machine parts. The wear resistance of GuBcisensorten is known to be increased by the addition of legalization elements. However, these elements form upon solidification relatively coarse-grained and very hard carbides of cast iron, which then cause destruction by scoring on the mating surfaces. At the same time will most of the carbon is consumed by the carbide formation, so that these alloys are the most suitable for The graphite required for the emergency running of these machine elements is missing in the structure. These materials are also used so brittle that they can withstand mechanical stress have not grown and break.
Es ist daher die Aufgabe der vorliegenden Erfindung, eine Gußeisenlegierung zu Finden, die verschleißfest genug gegen erhöhte Reibungsbeanspruchung ist und dabei mit dem Gegenwerkstoff eine ausreichende Verträglichkeit besitzt, die Graphitausscheidungen aufweist und die bei mechanischer Beanspruchung nicht spröde ist uud nicht brichtIt is therefore the object of the present invention To find a cast iron alloy that is wear-resistant enough against increased frictional stress and at the same time has sufficient compatibility with the mating material that exhibits graphite precipitates and which is not brittle under mechanical stress and does not break
Diese Aufgabe wird durch eine verschleißfeste Gußeisenlegierung gelöst, deren ungebundener Kohlenstoff in lamellarer bis vorwiegend knötchenförmiger Ausscheidungvorliegt und die eine große Anzahl von Karbiden beziehungsweise auch Nitriden und/oder Boridcn in fein kristalliner Ausscheidungsform besitzt.This problem is solved by a wear-resistant cast iron alloy whose unbound carbon present in lamellar to predominantly nodular excretion and a large number of carbides or nitrides and / or borides possesses in finely crystalline precipitate form.
Derartige Legierungen haben dann die folgenden Zusammensetzungen in GewichisproEeni:Such alloys then have the following compositions in GewichisproEeni:
1,5 bis 4,0% Kohlenstoff1.5 to 4.0% carbon
I^ bis 6,0% SiliziumI ^ to 6.0% silicon
weniger als 02% Schwefel
weniger als 23% Phosphorless than 02% sulfur
less than 23% phosphorus
1,0 bis 7,0% Kupfer1.0 to 7.0% copper
0,4 bis 3,2% Nickel und/oder Kobalt0.4 to 3.2% nickel and / or cobalt
0,1 bis 1,8% Zinn und/oder Antimon0.1 to 1.8% tin and / or antimony
0,1 bis 4,0% Molybdän
0,1 bis 4,0% Wolfram0.1 to 4.0% molybdenum
0.1 to 4.0% tungsten
0,05 bis 23% Mangan0.05 to 23% manganese
03 bis 23% Chrom03 to 23% chromium
03 bis 4,0% Vanadium03 to 4.0% vanadium
03 bis 2,0% Titan
0,1 bis 4,0% Niob und/oder Tantal03 to 2.0% titanium
0.1 to 4.0% niobium and / or tantalum
0,1 bis 2,0% Aluminium0.1 to 2.0% aluminum
Rest EisenRemainder iron
Bevorzugte Ausführungsformen des Anmeldungsgcgenstandes ergeben sich aus den Unteransprüchen 2 bis 6.Preferred embodiments of the subject matter of the application emerge from the subclaims 2 to 6th
Dabei ist es zweckmäßig, daß die Summe der Elemente Kohlenstoff und Silizium gleich oder größer als 3,0 Gewichtsprozent ist, und daß das Verhältnis Silizium zu ω Kohlenstoff gleich oder größer als I ist.It is useful that the sum of the elements carbon and silicon is equal to or greater than 3.0 Is weight percent, and that the ratio of silicon to ω carbon is equal to or greater than I.
Außerdem ist es zweckmäßig, daß die Summe der Elemente Molybdän, Wolfram und Mangan zwischen 0.2 und 10 Gewichtsprozent liegt, während sich die Summe der Elemente Chrom. Vanadium, Tantal und/oder b5 Niob zwischen I und 10 Gewichtsprozent bewegt.It is also useful that the sum of the elements molybdenum, tungsten and manganese between 0.2 and 10 percent by weight is while the sum of the elements chrome. Vanadium, tantalum and / or b5 niobium moved between 1 and 10 percent by weight.
Es hat sich zusätzlich erwiesen, daß zur Verfeinerung der Ausbildungsform der einzelnen Gefügcbcstancltuilc, wie insbesondere des Graphits beziehungsweise der Ni-It has also been shown that to refine the form of the individual structure, like in particular graphite or Ni
tride, die Elemente Bor, Wismut, Zirkonium, Magnesium und/oder die Metalle der seltenen Erden zugegeben sein können. Ihre Gesamtkonzentration darf jedoch den Wert 0,5 Gewichtsprozent nicht übersteigen.tride, the elements boron, bismuth, zirconium, magnesium and / or the rare earth metals may be added. However, their total concentration may be Do not exceed the value of 0.5 percent by weight.
Durch Wärmebehandlung über 7000C mit nachfolgender Abschreckung in beispielsweise Luft oder einem Sulzbad auf eine Temperatur von unter 500°C und anschließendes Anlassen bis zu einer Temperatur von 700" C wird die Verschleißfestigkeit und Verträglichkeit mit dem Gegenwerkstoff erheblich gesteigertBy heat treatment above 700 0 C with subsequent quenching in, for example, air or a Sulzbad to a temperature of below 500 ° C and subsequent tempering to a temperature of 700 "C, the wear resistance and compatibility is increased significantly with the mating material
Die erfindungsgemäßen Legierungen zeigen ein bainitischcs bis martensitisches Grundgefüge. Die Graphitausscheidungen sind lamellar bis knötchenförmig, die Karbidausscheidungen punkt- bis kugelförmig. Die Härte dieses Werkstoffes liegt bei HV 5550 bis 920 kp/ mm2. Das Material ist nicht spröde, und gegossene Dichtleisten für Kreiskolbenmaschinen sind verschleißfest und zeigen im Testlauf eine sehr gute Verträglichkeit mit der Trochoidenlauffläche des Kreiskolbenmotors. The alloys according to the invention show a bainitic to martensitic basic structure. The graphite precipitates are lamellar to nodular, the carbide precipitates point to spherical. The hardness of this material is HV 5550 to 920 kp / mm 2 . The material is not brittle, and cast sealing strips for rotary piston engines are wear-resistant and show very good compatibility with the trochoid contact surface of the rotary piston engine in the test run.
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Claims (1)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19742428821 DE2428821C3 (en) | 1974-06-14 | 1974-06-14 | Wear-resistant cast iron alloy with lamellar to nodular graphite precipitation |
IT2275875A IT1037649B (en) | 1974-06-14 | 1975-04-24 | WEAR RESISTANT CAST IRON ALLOY WITH LAMELLAR GRAPHITE SEPARATION UNTIL NODULAR |
FR7515849A FR2274703A1 (en) | 1974-06-14 | 1975-05-21 | GRAPHITE CAST IRON ALLOY FROM LAMELLAR TO NODULAR STATE, RESISTANT TO WEAR |
GB2436775A GB1482724A (en) | 1974-06-14 | 1975-06-06 | Wear-resistant cast-iron alloy |
SE7506829A SE430701B (en) | 1974-06-14 | 1975-06-13 | NUT PROTECTIVE MOLDING ALLOY |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19742428821 DE2428821C3 (en) | 1974-06-14 | 1974-06-14 | Wear-resistant cast iron alloy with lamellar to nodular graphite precipitation |
Publications (3)
Publication Number | Publication Date |
---|---|
DE2428821A1 DE2428821A1 (en) | 1975-12-18 |
DE2428821B2 DE2428821B2 (en) | 1977-02-24 |
DE2428821C3 true DE2428821C3 (en) | 1985-11-14 |
Family
ID=5918163
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19742428821 Expired DE2428821C3 (en) | 1974-06-14 | 1974-06-14 | Wear-resistant cast iron alloy with lamellar to nodular graphite precipitation |
Country Status (5)
Country | Link |
---|---|
DE (1) | DE2428821C3 (en) |
FR (1) | FR2274703A1 (en) |
GB (1) | GB1482724A (en) |
IT (1) | IT1037649B (en) |
SE (1) | SE430701B (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1650028C2 (en) * | 1967-12-06 | 1974-01-10 | Goetzewerke Friedrich Goetze Ag, 5673 Burscheid | Piston ring made of gray cast iron |
-
1974
- 1974-06-14 DE DE19742428821 patent/DE2428821C3/en not_active Expired
-
1975
- 1975-04-24 IT IT2275875A patent/IT1037649B/en active
- 1975-05-21 FR FR7515849A patent/FR2274703A1/en active Granted
- 1975-06-06 GB GB2436775A patent/GB1482724A/en not_active Expired
- 1975-06-13 SE SE7506829A patent/SE430701B/en not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
---|---|
SE7506829L (en) | 1975-12-15 |
SE430701B (en) | 1983-12-05 |
DE2428821A1 (en) | 1975-12-18 |
FR2274703B1 (en) | 1980-03-28 |
DE2428821B2 (en) | 1977-02-24 |
IT1037649B (en) | 1979-11-20 |
FR2274703A1 (en) | 1976-01-09 |
GB1482724A (en) | 1977-08-10 |
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