DE2417510A1 - Verfahren zur extraktion von metallen aus waessrigen loesungen mit sauren phosphorverbindungen - Google Patents
Verfahren zur extraktion von metallen aus waessrigen loesungen mit sauren phosphorverbindungenInfo
- Publication number
- DE2417510A1 DE2417510A1 DE2417510A DE2417510A DE2417510A1 DE 2417510 A1 DE2417510 A1 DE 2417510A1 DE 2417510 A DE2417510 A DE 2417510A DE 2417510 A DE2417510 A DE 2417510A DE 2417510 A1 DE2417510 A1 DE 2417510A1
- Authority
- DE
- Germany
- Prior art keywords
- extraction
- salts
- metals
- acidic phosphorus
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000605 extraction Methods 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 14
- 150000003018 phosphorus compounds Chemical class 0.000 title claims description 10
- 239000007864 aqueous solution Substances 0.000 title claims description 7
- 239000002184 metal Substances 0.000 title description 23
- 229910052751 metal Inorganic materials 0.000 title description 23
- 150000002739 metals Chemical class 0.000 title description 12
- 239000002253 acid Substances 0.000 title description 3
- 150000003839 salts Chemical class 0.000 claims description 23
- 230000002378 acidificating effect Effects 0.000 claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- -1 phosphorus compound Chemical class 0.000 claims description 8
- 230000007935 neutral effect Effects 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- 235000019270 ammonium chloride Nutrition 0.000 claims 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 2
- 235000011152 sodium sulphate Nutrition 0.000 claims 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- 239000001110 calcium chloride Substances 0.000 claims 1
- 229910001628 calcium chloride Inorganic materials 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 claims 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 13
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 13
- 239000012071 phase Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- YTMRJBAHYSIRMZ-UHFFFAOYSA-N dioctylphosphinic acid Chemical compound CCCCCCCCP(O)(=O)CCCCCCCC YTMRJBAHYSIRMZ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- NCQKSUNJAAZVJW-UKTHLTGXSA-N (2e)-2-(2-phenylethylhydrazinylidene)propanoic acid Chemical compound OC(=O)C(/C)=N/NCCC1=CC=CC=C1 NCQKSUNJAAZVJW-UKTHLTGXSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- FKIQYJKMNFKPFA-UHFFFAOYSA-N 2-ethyl-3-hydroxy-1-propylpyridin-4-one Chemical compound CCCN1C=CC(=O)C(O)=C1CC FKIQYJKMNFKPFA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 101000650863 Homo sapiens SH2 domain-containing protein 1A Proteins 0.000 description 1
- 102100027720 SH2 domain-containing protein 1A Human genes 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- GSKLVALWHWEMRR-UHFFFAOYSA-N dibutyl hydrogen phosphate;phosphoric acid Chemical compound OP(O)(O)=O.CCCCOP(O)(=O)OCCCC GSKLVALWHWEMRR-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003799 water insoluble solvent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/385—Thiophosphoric acids, or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3842—Phosphinic acid, e.g. H2P(O)(OH)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3844—Phosphonic acid, e.g. H2P(O)(OH)2
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/387—Cyclic or polycyclic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2417510A DE2417510A1 (de) | 1974-04-10 | 1974-04-10 | Verfahren zur extraktion von metallen aus waessrigen loesungen mit sauren phosphorverbindungen |
| NO751058A NO751058L (enExample) | 1974-04-10 | 1975-03-26 | |
| NL7504124A NL7504124A (nl) | 1974-04-10 | 1975-04-07 | Werkwijze voor het extraheren van polyvalente metaalionen uit water bevattende oplossingen of suspensies van de zouten ervan. |
| LU72237A LU72237A1 (enExample) | 1974-04-10 | 1975-04-08 | |
| JP50041924A JPS50141579A (enExample) | 1974-04-10 | 1975-04-08 | |
| BE155231A BE827731A (fr) | 1974-04-10 | 1975-04-09 | Extraction d'ions metalliques polyvalents avec des composes acides et phosphore et des chlorures et/ou sulfates neutres |
| ZA00752252A ZA752252B (en) | 1974-04-10 | 1975-04-09 | Extracting polyvalent metal ions with acid phosphorus and neutral chlorides and/or sulfates |
| SE7504086A SE388129B (sv) | 1974-04-10 | 1975-04-09 | Sett att extrahera polyvalenta metalljoner fran vattenlosningar eller suspensioner av deras salter medelst sura fosforforeningar |
| FR7511270A FR2267380A1 (en) | 1974-04-10 | 1975-04-10 | Extracting polyvalent metal ions from aqs. soln. - with phosphorus acid cpds. in presence of a neutral sulphate of chloride salt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2417510A DE2417510A1 (de) | 1974-04-10 | 1974-04-10 | Verfahren zur extraktion von metallen aus waessrigen loesungen mit sauren phosphorverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2417510A1 true DE2417510A1 (de) | 1975-10-30 |
Family
ID=5912685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2417510A Pending DE2417510A1 (de) | 1974-04-10 | 1974-04-10 | Verfahren zur extraktion von metallen aus waessrigen loesungen mit sauren phosphorverbindungen |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS50141579A (enExample) |
| BE (1) | BE827731A (enExample) |
| DE (1) | DE2417510A1 (enExample) |
| FR (1) | FR2267380A1 (enExample) |
| LU (1) | LU72237A1 (enExample) |
| NL (1) | NL7504124A (enExample) |
| NO (1) | NO751058L (enExample) |
| SE (1) | SE388129B (enExample) |
| ZA (1) | ZA752252B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4246240A (en) * | 1978-07-24 | 1981-01-20 | Nippon Mining Co., Ltd. | Process for separating cobalt and nickel from a solution containing cobalt and nickel |
| DE3140380A1 (de) * | 1981-10-10 | 1983-04-28 | Gebrüder Sulzer AG, 8401 Winterthur | "verfahren zum herstellen von nickel, hochreinem magnesiumoxid und zement" |
| DE3523624A1 (de) * | 1984-07-03 | 1986-01-09 | Outokumpu Oy, Helsinki | Verfahren zur entfernung und rueckgewinnung von metallen aus waessrigen loesungen durch extraktion |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4053552A (en) * | 1976-03-15 | 1977-10-11 | General Mills Chemicals Co. | Solvent extraction of zinc from sulfite-bisulfite solution |
| FR2462481A1 (fr) * | 1979-07-30 | 1981-02-13 | British Petroleum Co | Procede d'extraction liquide-liquide de metaux en solution aqueuse au moyen de derives organophosphores |
| MA19258A1 (fr) * | 1980-08-28 | 1982-04-01 | Canada Cyanamid | Procede de separation selective de cobalt (ii) de solutions aqueuses . |
| FR2562059B1 (fr) * | 1984-04-02 | 1989-12-01 | Rhone Poulenc Spec Chim | Procede de separation des terres rares par extraction liquide-liquide |
| CA2964645C (en) | 2014-10-17 | 2024-01-16 | Merck Patent Gmbh | Alkenyl(perfluoroalkyl)phosphinic acids |
-
1974
- 1974-04-10 DE DE2417510A patent/DE2417510A1/de active Pending
-
1975
- 1975-03-26 NO NO751058A patent/NO751058L/no unknown
- 1975-04-07 NL NL7504124A patent/NL7504124A/xx unknown
- 1975-04-08 LU LU72237A patent/LU72237A1/xx unknown
- 1975-04-08 JP JP50041924A patent/JPS50141579A/ja active Pending
- 1975-04-09 SE SE7504086A patent/SE388129B/xx unknown
- 1975-04-09 ZA ZA00752252A patent/ZA752252B/xx unknown
- 1975-04-09 BE BE155231A patent/BE827731A/xx unknown
- 1975-04-10 FR FR7511270A patent/FR2267380A1/fr active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4246240A (en) * | 1978-07-24 | 1981-01-20 | Nippon Mining Co., Ltd. | Process for separating cobalt and nickel from a solution containing cobalt and nickel |
| DE3140380A1 (de) * | 1981-10-10 | 1983-04-28 | Gebrüder Sulzer AG, 8401 Winterthur | "verfahren zum herstellen von nickel, hochreinem magnesiumoxid und zement" |
| DE3523624A1 (de) * | 1984-07-03 | 1986-01-09 | Outokumpu Oy, Helsinki | Verfahren zur entfernung und rueckgewinnung von metallen aus waessrigen loesungen durch extraktion |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2267380A1 (en) | 1975-11-07 |
| ZA752252B (en) | 1976-03-31 |
| LU72237A1 (enExample) | 1976-03-17 |
| FR2267380B1 (enExample) | 1979-03-09 |
| SE388129B (sv) | 1976-09-27 |
| BE827731A (fr) | 1975-10-09 |
| SE7504086L (sv) | 1975-10-13 |
| NL7504124A (nl) | 1975-10-14 |
| NO751058L (enExample) | 1975-10-13 |
| JPS50141579A (enExample) | 1975-11-14 |
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