DE2401617C2 - Verfahren zur Herstellung eines methanhaltigen Gases im Rahmen einer Niedrigtemperatur-Dampf-Reformierung - Google Patents
Verfahren zur Herstellung eines methanhaltigen Gases im Rahmen einer Niedrigtemperatur-Dampf-ReformierungInfo
- Publication number
- DE2401617C2 DE2401617C2 DE19742401617 DE2401617A DE2401617C2 DE 2401617 C2 DE2401617 C2 DE 2401617C2 DE 19742401617 DE19742401617 DE 19742401617 DE 2401617 A DE2401617 A DE 2401617A DE 2401617 C2 DE2401617 C2 DE 2401617C2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- nickel
- catalysts
- solid solution
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 32
- 238000000629 steam reforming Methods 0.000 title claims description 30
- 239000003054 catalyst Substances 0.000 claims description 112
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 66
- 239000006104 solid solution Substances 0.000 claims description 46
- 239000000395 magnesium oxide Substances 0.000 claims description 35
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 35
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 24
- 239000011777 magnesium Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 20
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 20
- 238000001354 calcination Methods 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims description 17
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000007858 starting material Substances 0.000 claims description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- -1 hydrogen-activated nickel- and magnesium Chemical class 0.000 claims description 3
- 229910003465 moissanite Inorganic materials 0.000 claims description 3
- 238000002407 reforming Methods 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910021489 α-quartz Inorganic materials 0.000 claims description 3
- 229910052774 Proactinium Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 description 18
- 239000002244 precipitate Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 230000000977 initiatory effect Effects 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 229910002642 NiO-MgO Inorganic materials 0.000 description 4
- 101100311330 Schizosaccharomyces pombe (strain 972 / ATCC 24843) uap56 gene Proteins 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 101150018444 sub2 gene Proteins 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 150000001339 alkali metal compounds Chemical class 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- BXNFVPMHMPQBRO-UHFFFAOYSA-N magnesium nickel(2+) oxygen(2-) Chemical compound [O--].[O--].[Mg++].[Ni++] BXNFVPMHMPQBRO-UHFFFAOYSA-N 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000006057 reforming reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3283673A JPS538682B2 (enrdf_load_stackoverflow) | 1973-03-22 | 1973-03-22 | |
| JP6871873A JPS5328881B2 (enrdf_load_stackoverflow) | 1973-06-20 | 1973-06-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2401617A1 DE2401617A1 (de) | 1974-10-03 |
| DE2401617C2 true DE2401617C2 (de) | 1987-04-16 |
Family
ID=26371420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742401617 Expired DE2401617C2 (de) | 1973-03-22 | 1974-01-14 | Verfahren zur Herstellung eines methanhaltigen Gases im Rahmen einer Niedrigtemperatur-Dampf-Reformierung |
Country Status (8)
| Country | Link |
|---|---|
| AU (1) | AU474004B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1014978A (enrdf_load_stackoverflow) |
| DE (1) | DE2401617C2 (enrdf_load_stackoverflow) |
| ES (1) | ES422275A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2222423B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1451862A (enrdf_load_stackoverflow) |
| IT (1) | IT1009083B (enrdf_load_stackoverflow) |
| NL (1) | NL173391C (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2144446A (en) * | 1983-08-04 | 1985-03-06 | Veg Gasinstituut Nv | Process for the production of methane rich gases |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2083795A (en) * | 1933-04-17 | 1937-06-15 | Ig Farbenindustrie Ag | Production of hydrogen |
| US2094210A (en) * | 1936-03-09 | 1937-09-28 | Gen Mills Inc | Advertising display device |
| US3404100A (en) * | 1963-10-21 | 1968-10-01 | Exxon Research Engineering Co | Methane production using a promoted catalyst |
| FR1415014A (fr) * | 1964-10-14 | 1965-10-22 | Japan Gasoline | Procédé de réformation des hydrocarbures par la vapeur d'eau et catalyseur pour samise en oeuvre |
| FR1479857A (fr) * | 1965-05-18 | 1967-05-05 | Basf Ag | Procédé de préparation de catalyseurs pour le craquage d'hydrocarbures gazeux ou d'hydrocarbures liquides volatils |
| DE1259496B (de) * | 1966-02-08 | 1968-01-25 | Koppers Gmbh Heinrich | Verfahren zur Erzeugung von Industriegasen |
| US3576899A (en) * | 1967-04-27 | 1971-04-27 | Japan Gasoline | Method for manufacturing high purity methane |
| FR2094210A5 (enrdf_load_stackoverflow) * | 1970-05-05 | 1972-02-04 | Pechiney Saint Gobain |
-
1973
- 1973-12-27 AU AU63934/73A patent/AU474004B2/en not_active Expired
-
1974
- 1974-01-07 IT IT6701874A patent/IT1009083B/it active
- 1974-01-14 ES ES422275A patent/ES422275A1/es not_active Expired
- 1974-01-14 DE DE19742401617 patent/DE2401617C2/de not_active Expired
- 1974-01-14 NL NL7400499A patent/NL173391C/xx not_active IP Right Cessation
- 1974-01-15 FR FR7401310A patent/FR2222423B1/fr not_active Expired
- 1974-01-15 GB GB184274A patent/GB1451862A/en not_active Expired
- 1974-01-30 CA CA189,420A patent/CA1014978A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL173391B (nl) | 1983-08-16 |
| IT1009083B (it) | 1976-12-10 |
| AU6393473A (en) | 1975-07-03 |
| GB1451862A (enrdf_load_stackoverflow) | 1976-10-06 |
| NL173391C (nl) | 1984-01-16 |
| NL7400499A (enrdf_load_stackoverflow) | 1974-09-24 |
| CA1014978A (en) | 1977-08-02 |
| AU474004B2 (en) | 1976-07-08 |
| FR2222423B1 (enrdf_load_stackoverflow) | 1978-12-08 |
| FR2222423A1 (enrdf_load_stackoverflow) | 1974-10-18 |
| ES422275A1 (es) | 1976-08-01 |
| DE2401617A1 (de) | 1974-10-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OGA | New person/name/address of the applicant | ||
| OD | Request for examination | ||
| 8125 | Change of the main classification |
Ipc: C10G 47/32 |
|
| 8172 | Supplementary division/partition in: |
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| AH | Division in |
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| Q171 | Divided out to: |
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| 8128 | New person/name/address of the agent |
Representative=s name: HENKEL, G., DR.PHIL. FEILER, L., DR.RER.NAT. HAENZ |
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| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |