DE2363273A1 - Verfahren zur entfernung von jod aus salpetersaeureloesungen - Google Patents
Verfahren zur entfernung von jod aus salpetersaeureloesungenInfo
- Publication number
- DE2363273A1 DE2363273A1 DE19732363273 DE2363273A DE2363273A1 DE 2363273 A1 DE2363273 A1 DE 2363273A1 DE 19732363273 DE19732363273 DE 19732363273 DE 2363273 A DE2363273 A DE 2363273A DE 2363273 A1 DE2363273 A1 DE 2363273A1
- Authority
- DE
- Germany
- Prior art keywords
- solution
- iodine
- nitric acid
- distillation
- radioactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052740 iodine Inorganic materials 0.000 title claims description 42
- 239000011630 iodine Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 25
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 title claims description 6
- 239000002253 acid Substances 0.000 title 1
- 239000000243 solution Substances 0.000 claims description 43
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 41
- 230000002285 radioactive effect Effects 0.000 claims description 29
- 238000004821 distillation Methods 0.000 claims description 25
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 16
- 229910017604 nitric acid Inorganic materials 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 11
- 238000010926 purge Methods 0.000 claims description 10
- 238000011010 flushing procedure Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000007865 diluting Methods 0.000 claims 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 8
- 239000000446 fuel Substances 0.000 description 5
- 230000000155 isotopic effect Effects 0.000 description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000001784 detoxification Methods 0.000 description 2
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 2
- 150000004694 iodide salts Chemical class 0.000 description 2
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052778 Plutonium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- WIITVKVYCUQKMA-UHFFFAOYSA-N [I].[N+](=O)(O)[O-] Chemical compound [I].[N+](=O)(O)[O-] WIITVKVYCUQKMA-UHFFFAOYSA-N 0.000 description 1
- OGIIWTRTOXDWEH-UHFFFAOYSA-N [O].[O-][O+]=O Chemical compound [O].[O-][O+]=O OGIIWTRTOXDWEH-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IWCHCNIUMDAMDJ-UHFFFAOYSA-N methyl iodite Chemical compound COI=O IWCHCNIUMDAMDJ-UHFFFAOYSA-N 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/08—Processing by evaporation; by distillation
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00317455A US3803295A (en) | 1972-03-06 | 1972-12-21 | Method for removing iodine from nitric acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2363273A1 true DE2363273A1 (de) | 1974-06-27 |
Family
ID=23233732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19732363273 Pending DE2363273A1 (de) | 1972-12-21 | 1973-12-19 | Verfahren zur entfernung von jod aus salpetersaeureloesungen |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS4989099A (enrdf_load_stackoverflow) |
| DE (1) | DE2363273A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2211723B3 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4116388C1 (enrdf_load_stackoverflow) * | 1991-05-18 | 1993-01-14 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De | |
| DE102005048789A1 (de) * | 2005-10-12 | 2007-04-19 | Technocon Gmbh | Verfahren zur Rückgewinnung von elementarem Jod aus jodorganischen Verbindungen |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2951339C2 (de) * | 1979-12-20 | 1985-11-21 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zum Desorbieren von Spaltjod aus salpetersaurer Brennstofflösung |
-
1973
- 1973-12-06 JP JP13850473A patent/JPS4989099A/ja active Pending
- 1973-12-18 FR FR7345269A patent/FR2211723B3/fr not_active Expired
- 1973-12-19 DE DE19732363273 patent/DE2363273A1/de active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4116388C1 (enrdf_load_stackoverflow) * | 1991-05-18 | 1993-01-14 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De | |
| DE102005048789A1 (de) * | 2005-10-12 | 2007-04-19 | Technocon Gmbh | Verfahren zur Rückgewinnung von elementarem Jod aus jodorganischen Verbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2211723A1 (enrdf_load_stackoverflow) | 1974-07-19 |
| JPS4989099A (enrdf_load_stackoverflow) | 1974-08-26 |
| FR2211723B3 (enrdf_load_stackoverflow) | 1976-10-15 |
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