DE2306222A1 - Verfahren zur asymmetrischen reduktion von ketonen unter bildung optisch aktiver alkohole - Google Patents

Verfahren zur asymmetrischen reduktion von ketonen unter bildung optisch aktiver alkohole

Info

Publication number
DE2306222A1
DE2306222A1 DE2306222A DE2306222A DE2306222A1 DE 2306222 A1 DE2306222 A1 DE 2306222A1 DE 2306222 A DE2306222 A DE 2306222A DE 2306222 A DE2306222 A DE 2306222A DE 2306222 A1 DE2306222 A1 DE 2306222A1
Authority
DE
Germany
Prior art keywords
optically active
metal
phosphine
ligand
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE2306222A
Other languages
German (de)
English (en)
Inventor
Arthur John Solodar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of DE2306222A1 publication Critical patent/DE2306222A1/de
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE2306222A 1972-02-09 1973-02-08 Verfahren zur asymmetrischen reduktion von ketonen unter bildung optisch aktiver alkohole Ceased DE2306222A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US224971A US3883580A (en) 1972-02-09 1972-02-09 Asymmetric reduction of ketones to form optically active alcohols

Publications (1)

Publication Number Publication Date
DE2306222A1 true DE2306222A1 (de) 1973-08-23

Family

ID=22843002

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2306222A Ceased DE2306222A1 (de) 1972-02-09 1973-02-08 Verfahren zur asymmetrischen reduktion von ketonen unter bildung optisch aktiver alkohole

Country Status (7)

Country Link
US (1) US3883580A (enExample)
JP (1) JPS5522455B2 (enExample)
CA (1) CA1000719A (enExample)
CH (1) CH570948A5 (enExample)
DE (1) DE2306222A1 (enExample)
FR (1) FR2171312B1 (enExample)
GB (1) GB1423224A (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4165330A (en) * 1972-07-31 1979-08-21 Exxon Research & Engineering Co. Asymmetric synthesis via optically active chelating agents
US4024193A (en) * 1973-10-19 1977-05-17 Ici United States Inc. Homogeneous hydrogenation process
US4115417A (en) * 1975-10-16 1978-09-19 Hoffmann-La Roche Inc. Asymmetric hydrogenation catalyzed by rhodium complexes of chiral tertiary phosphines
US4321414A (en) * 1980-08-26 1982-03-23 The Halcon Sd Group, Inc. Catalytic hydrogenation of glycolaldehyde to produce ethylene glycol
US4343741A (en) * 1981-04-22 1982-08-10 Hoffmann-La Roche Inc. Chiral phosphines
JPS59181140U (ja) * 1983-05-20 1984-12-03 タニタ伸銅株式会社 軒樋受金具
ATE66666T1 (de) * 1986-08-04 1991-09-15 Ciba Geigy Ag Verfahren zur herstellung von optisch aktiven sekundaeren arylaminen.
JPH064543B2 (ja) * 1987-06-18 1994-01-19 高砂香料工業株式会社 光学活性アルコ−ルの製造法
US5099067A (en) * 1988-08-05 1992-03-24 Northwestern University Use of ammonium formate as a hydrogen transfer reagent for reduction of chiral nitro compounds with retention of configuration
JPH06329679A (ja) * 1993-01-20 1994-11-29 Nissan Chem Ind Ltd 光学活性β−アミノアルコキシボラン錯体
JPH0812690A (ja) * 1994-07-01 1996-01-16 Takasago Internatl Corp 光学活性ヒドロキシアルキルホスホン酸類の製造方法
EP0916637B1 (en) * 1995-12-06 2005-04-20 Japan Science and Technology Agency Process for preparating optically active compounds
DE19647892A1 (de) * 1996-11-20 1998-06-04 Forschungszentrum Juelich Gmbh Verfahren zur katalytischen, enantioselektiven Reduktion von Ketonen
DE19709069C2 (de) * 1997-03-06 2000-04-06 Asta Medica Ag Enantiomerenreine 3-Hydroxyoctandisäurediester, Verfahren zur Herstellung derselben durch asymmetrische katalytische Hydrierung sowie Verfahren zur Herstellung von R-(+)- und S-(-)-alpha-Liponsäure
US20040030199A1 (en) * 2002-01-29 2004-02-12 Maughon Robert R. Process for reducing alpha-haloketones to secondary alpha-haloalcohols

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1138601A (en) * 1964-12-15 1969-01-01 Geoffrey Wilkinson Improvements in catalytic reactions

Also Published As

Publication number Publication date
FR2171312B1 (enExample) 1977-02-04
GB1423224A (en) 1976-02-04
US3883580A (en) 1975-05-13
JPS4886806A (enExample) 1973-11-15
JPS5522455B2 (enExample) 1980-06-17
FR2171312A1 (enExample) 1973-09-21
CA1000719A (en) 1976-11-30
CH570948A5 (enExample) 1975-12-31

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Legal Events

Date Code Title Description
OD Request for examination
8131 Rejection