DE2258663A1 - Schwerentflammbare thermoplastische polyester - Google Patents
Schwerentflammbare thermoplastische polyesterInfo
- Publication number
- DE2258663A1 DE2258663A1 DE19722258663 DE2258663A DE2258663A1 DE 2258663 A1 DE2258663 A1 DE 2258663A1 DE 19722258663 DE19722258663 DE 19722258663 DE 2258663 A DE2258663 A DE 2258663A DE 2258663 A1 DE2258663 A1 DE 2258663A1
- Authority
- DE
- Germany
- Prior art keywords
- molding
- polyester
- weight
- carbon atoms
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims description 30
- 229920001169 thermoplastic Polymers 0.000 title claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 24
- 238000000465 moulding Methods 0.000 claims description 23
- 239000003063 flame retardant Substances 0.000 claims description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000000748 compression moulding Methods 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- -1 polyethylene terephthalate Polymers 0.000 description 22
- 229920000139 polyethylene terephthalate Polymers 0.000 description 15
- 239000005020 polyethylene terephthalate Substances 0.000 description 15
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 description 6
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000007706 flame test Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- VCUVETGKTILCLC-UHFFFAOYSA-N 5,5-dimethyl-1-pyrroline N-oxide Chemical compound CC1(C)CCC=[N+]1[O-] VCUVETGKTILCLC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- BHBRSNQBODBPND-UHFFFAOYSA-N chloro-[chloromethyl(methyl)phosphoryl]methane Chemical compound ClCP(=O)(C)CCl BHBRSNQBODBPND-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000009347 mechanical transmission Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical class [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5397—Phosphine oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722258663 DE2258663A1 (de) | 1972-11-30 | 1972-11-30 | Schwerentflammbare thermoplastische polyester |
| NL7316049A NL7316049A (en:Method) | 1972-11-30 | 1973-11-23 | |
| GB5521773A GB1447785A (en) | 1972-11-30 | 1973-11-28 | Flame resistand polyesters |
| ZA00739049A ZA739049B (en) | 1972-11-30 | 1973-11-28 | Flame resistant thermoplastic polyesters |
| US419528A US3883474A (en) | 1972-11-30 | 1973-11-28 | Flame resistant thermoplastic polyesters |
| JP48132821A JPS4987743A (en:Method) | 1972-11-30 | 1973-11-28 | |
| IT31775/73A IT1002005B (it) | 1972-11-30 | 1973-11-28 | Poliesteri termoplastici difficil mente infiammabili |
| AT1001673A AT335741B (de) | 1972-11-30 | 1973-11-29 | Schwerentflammbare thermoplastische polyesterformmasse und die herstellung von formkorpern, folien, fasern und faden hieraus |
| FR7342727A FR2208932B1 (en:Method) | 1972-11-30 | 1973-11-30 | |
| BE138402A BE808079A (fr) | 1972-11-30 | 1973-11-30 | Polyesters thermoplastiques peu inflammables |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722258663 DE2258663A1 (de) | 1972-11-30 | 1972-11-30 | Schwerentflammbare thermoplastische polyester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2258663A1 true DE2258663A1 (de) | 1974-06-06 |
Family
ID=5863142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722258663 Pending DE2258663A1 (de) | 1972-11-30 | 1972-11-30 | Schwerentflammbare thermoplastische polyester |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS4987743A (en:Method) |
| AT (1) | AT335741B (en:Method) |
| BE (1) | BE808079A (en:Method) |
| DE (1) | DE2258663A1 (en:Method) |
| FR (1) | FR2208932B1 (en:Method) |
| GB (1) | GB1447785A (en:Method) |
| IT (1) | IT1002005B (en:Method) |
| NL (1) | NL7316049A (en:Method) |
| ZA (1) | ZA739049B (en:Method) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8513454B2 (en) * | 2011-12-08 | 2013-08-20 | E I Du Pont De Nemours And Company | Preparation of (phosphonyl) aromatic diesters and acids |
-
1972
- 1972-11-30 DE DE19722258663 patent/DE2258663A1/de active Pending
-
1973
- 1973-11-23 NL NL7316049A patent/NL7316049A/xx unknown
- 1973-11-28 JP JP48132821A patent/JPS4987743A/ja active Pending
- 1973-11-28 IT IT31775/73A patent/IT1002005B/it active
- 1973-11-28 GB GB5521773A patent/GB1447785A/en not_active Expired
- 1973-11-28 ZA ZA00739049A patent/ZA739049B/xx unknown
- 1973-11-29 AT AT1001673A patent/AT335741B/de not_active IP Right Cessation
- 1973-11-30 BE BE138402A patent/BE808079A/xx unknown
- 1973-11-30 FR FR7342727A patent/FR2208932B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE808079A (fr) | 1974-05-30 |
| FR2208932A1 (en:Method) | 1974-06-28 |
| ZA739049B (en) | 1975-01-29 |
| GB1447785A (en) | 1976-09-02 |
| ATA1001673A (de) | 1976-07-15 |
| JPS4987743A (en:Method) | 1974-08-22 |
| NL7316049A (en:Method) | 1974-06-04 |
| IT1002005B (it) | 1976-05-20 |
| FR2208932B1 (en:Method) | 1977-08-12 |
| AT335741B (de) | 1977-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2252258A1 (de) | Schwerentflammbare thermoplastische polyester | |
| DE2454189C3 (de) | Verfahren zur Herstellung von schwer entflammbaren linearen Polyestern | |
| DE2255971C2 (de) | Neue cyclische Phosphonatester, Verfahren zu deren Herstellung und deren Verwendung als Flammverzögerungsmittel | |
| DE2331826A1 (de) | Thermoplastische massen | |
| DE2242509C2 (de) | Nicht-tropfende, flammhemmende, mit Glas verstärkte Polyesterharze und Verfahren zu ihrer Herstellung | |
| JPS59202240A (ja) | 難燃性熱可塑性樹脂組成物 | |
| DE2252210A1 (de) | Schwerentflammbare thermoplastische polyester | |
| DE2547498A1 (de) | Flammwidrige formmasse | |
| EP0794189A1 (de) | Salze von phosphonigen Säuren und deren Verwendung als Flammschutzmittel in Kunststoffen | |
| DE3211899A1 (de) | Verfahren zum kondensieren von poly(alkylenterephthalaten) | |
| DE2358293A1 (de) | Verbesserte stabilisierte polyestermassen und verbessertes verfahren zur stabilisierung von polyestern | |
| EP0794191A1 (de) | Salze von 1-Hydroxy-dihydrophospholoxiden und 1-Hydroxy-phospholanoxiden und ihre Verwendung als Flammschutzmittel | |
| DE1769725A1 (de) | Thermische Stabilisierung von Polyestern | |
| EP0025018B1 (de) | Flammwidrige Kunststofformmasse | |
| DE2833024C2 (en:Method) | ||
| DE2258663A1 (de) | Schwerentflammbare thermoplastische polyester | |
| EP0466002B1 (de) | Stabilisierte Polyaryletherketon-Formmassen | |
| EP0970093B1 (de) | Aluminiumsalze von alkylhydroxymethylphosphinsäuren | |
| DE2653120A1 (de) | Schnellkristallisierende polyestermassen | |
| DE1694207A1 (de) | Flammwidrige Formmassen auf Basis von gesaettigten Polyestern | |
| DE2238222A1 (de) | Schwerentflammbare thermoplastische polyester | |
| DE2253207A1 (de) | Flammhemmende polyesterharzzusammensetzungen | |
| DE3884500T2 (de) | Thermisch stabiles Flammschutzmittel vom Diphosphonattyp für Kunststoffe. | |
| DE2706123A1 (de) | Schnell kristallisierende polyaethylenterephthalate und verfahren zu ihrer herstellung | |
| US3883474A (en) | Flame resistant thermoplastic polyesters |