DE2252224A1 - Vorrichtung und methode zur herstellung von chlorhydrat aus dem elektrolyten einer batterie hoher energiedichte und chlor - Google Patents
Vorrichtung und methode zur herstellung von chlorhydrat aus dem elektrolyten einer batterie hoher energiedichte und chlorInfo
- Publication number
- DE2252224A1 DE2252224A1 DE2252224A DE2252224A DE2252224A1 DE 2252224 A1 DE2252224 A1 DE 2252224A1 DE 2252224 A DE2252224 A DE 2252224A DE 2252224 A DE2252224 A DE 2252224A DE 2252224 A1 DE2252224 A1 DE 2252224A1
- Authority
- DE
- Germany
- Prior art keywords
- chlorine
- zone
- pressure
- cooling
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000460 chlorine Substances 0.000 title claims description 150
- 229910052801 chlorine Inorganic materials 0.000 title claims description 150
- 239000003792 electrolyte Substances 0.000 title claims description 52
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 146
- 238000001816 cooling Methods 0.000 claims description 63
- 239000002826 coolant Substances 0.000 claims description 41
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 25
- 235000005074 zinc chloride Nutrition 0.000 claims description 18
- 239000011592 zinc chloride Substances 0.000 claims description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 17
- ACXCKRZOISAYHH-UHFFFAOYSA-N molecular chlorine hydrate Chemical compound O.ClCl ACXCKRZOISAYHH-UHFFFAOYSA-N 0.000 claims description 13
- 239000012266 salt solution Substances 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 241000270295 Serpentes Species 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003507 refrigerant Substances 0.000 claims description 8
- 230000007423 decrease Effects 0.000 claims description 6
- 229910001510 metal chloride Inorganic materials 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 230000033228 biological regulation Effects 0.000 claims description 2
- 230000008602 contraction Effects 0.000 claims description 2
- 230000005226 mechanical processes and functions Effects 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 238000001704 evaporation Methods 0.000 claims 2
- 230000008020 evaporation Effects 0.000 claims 2
- 238000005086 pumping Methods 0.000 claims 2
- MFSIEROJJKUHBQ-UHFFFAOYSA-N O.[Cl] Chemical compound O.[Cl] MFSIEROJJKUHBQ-UHFFFAOYSA-N 0.000 claims 1
- SCSNHYQHLRSOIN-UHFFFAOYSA-K [Cl-].[Zn+2].[Cl+].[Cl-].[Cl-] Chemical compound [Cl-].[Zn+2].[Cl+].[Cl-].[Cl-] SCSNHYQHLRSOIN-UHFFFAOYSA-K 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 239000012466 permeate Substances 0.000 claims 1
- 238000005057 refrigeration Methods 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 4
- 239000000110 cooling liquid Substances 0.000 description 3
- 230000004941 influx Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- BLKPHSLCUSJDIO-UHFFFAOYSA-I [Cl+].[Cl-].[Zn+2].[Zn+2].[Cl-].[Cl-].[Cl-].[Cl-] Chemical compound [Cl+].[Cl-].[Zn+2].[Zn+2].[Cl-].[Cl-].[Cl-].[Cl-] BLKPHSLCUSJDIO-UHFFFAOYSA-I 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003855 balanced salt solution Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/365—Zinc-halogen accumulators
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/015—Chlorine hydrates; Obtaining chlorine therefrom
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hybrid Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20004671A | 1971-11-18 | 1971-11-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2252224A1 true DE2252224A1 (de) | 1973-05-24 |
Family
ID=22740092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2252224A Pending DE2252224A1 (de) | 1971-11-18 | 1972-10-25 | Vorrichtung und methode zur herstellung von chlorhydrat aus dem elektrolyten einer batterie hoher energiedichte und chlor |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3783027A (enExample) |
| JP (1) | JPS4862689A (enExample) |
| AU (1) | AU4786372A (enExample) |
| BR (1) | BR7208124D0 (enExample) |
| CA (1) | CA977524A (enExample) |
| DE (1) | DE2252224A1 (enExample) |
| FR (1) | FR2169789B1 (enExample) |
| IT (1) | IT973579B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4020238A (en) * | 1973-07-02 | 1977-04-26 | Energy Development Associates | Control of generation of chlorine feed from chlorine hydrate for use in a metal chlorine electric energy storage device |
| US4306000A (en) * | 1980-04-29 | 1981-12-15 | Energy Development Associates, Inc. | Method of cooling zinc halogen batteries |
| US4386140A (en) * | 1982-04-16 | 1983-05-31 | Energy Development Associates, Inc. | Multiple stage multiple filter hydrate store |
| US4585709A (en) * | 1983-01-21 | 1986-04-29 | Energy Development Associates, Inc. | Method and apparatus for regulating the hydrate formation temperature in a metal-halogen battery |
| JPS59182203A (ja) * | 1983-03-26 | 1984-10-17 | Furukawa Electric Co Ltd:The | 塩素水和物生成槽 |
-
1971
- 1971-11-18 US US00200046A patent/US3783027A/en not_active Expired - Lifetime
-
1972
- 1972-10-13 CA CA154,175A patent/CA977524A/en not_active Expired
- 1972-10-18 AU AU47863/72A patent/AU4786372A/en not_active Expired
- 1972-10-25 DE DE2252224A patent/DE2252224A1/de active Pending
- 1972-11-14 JP JP47114196A patent/JPS4862689A/ja active Pending
- 1972-11-16 IT IT54058/72A patent/IT973579B/it active
- 1972-11-17 FR FR7240943A patent/FR2169789B1/fr not_active Expired
- 1972-11-17 BR BR008124/72A patent/BR7208124D0/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU4786372A (en) | 1974-04-26 |
| CA977524A (en) | 1975-11-11 |
| JPS4862689A (enExample) | 1973-09-01 |
| FR2169789B1 (enExample) | 1976-01-30 |
| FR2169789A1 (enExample) | 1973-09-14 |
| US3783027A (en) | 1974-01-01 |
| IT973579B (it) | 1974-06-10 |
| BR7208124D0 (pt) | 1973-08-23 |
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