DE2149370C3 - Verfahren zur Umwandlung rückstandshaltiger Erdölfraktionen - Google Patents
Verfahren zur Umwandlung rückstandshaltiger ErdölfraktionenInfo
- Publication number
- DE2149370C3 DE2149370C3 DE2149370A DE2149370A DE2149370C3 DE 2149370 C3 DE2149370 C3 DE 2149370C3 DE 2149370 A DE2149370 A DE 2149370A DE 2149370 A DE2149370 A DE 2149370A DE 2149370 C3 DE2149370 C3 DE 2149370C3
- Authority
- DE
- Germany
- Prior art keywords
- zone
- products
- catalytic
- catalyst
- catalysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 47
- 238000006243 chemical reaction Methods 0.000 title claims description 34
- 239000003208 petroleum Substances 0.000 title claims 11
- 239000003054 catalyst Substances 0.000 claims description 52
- 229930195733 hydrocarbon Natural products 0.000 claims description 50
- 150000002430 hydrocarbons Chemical class 0.000 claims description 50
- 230000003197 catalytic effect Effects 0.000 claims description 44
- 238000009835 boiling Methods 0.000 claims description 36
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 33
- 238000006555 catalytic reaction Methods 0.000 claims description 33
- 239000004215 Carbon black (E152) Substances 0.000 claims description 30
- 238000005336 cracking Methods 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 22
- 239000003921 oil Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 14
- 238000004523 catalytic cracking Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000000571 coke Substances 0.000 claims description 4
- 239000010779 crude oil Substances 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 4
- 239000003350 kerosene Substances 0.000 claims description 3
- 239000010426 asphalt Substances 0.000 claims 2
- 238000004939 coking Methods 0.000 claims 1
- 230000009849 deactivation Effects 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000001465 metallisation Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 60
- 239000007858 starting material Substances 0.000 description 24
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
- 239000010457 zeolite Substances 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000008186 active pharmaceutical agent Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10144470A | 1970-12-24 | 1970-12-24 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2149370A1 DE2149370A1 (de) | 1972-07-13 |
| DE2149370B2 DE2149370B2 (de) | 1977-09-22 |
| DE2149370C3 true DE2149370C3 (de) | 1978-05-24 |
Family
ID=22284664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2149370A Expired DE2149370C3 (de) | 1970-12-24 | 1971-10-02 | Verfahren zur Umwandlung rückstandshaltiger Erdölfraktionen |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3671420A (enExample) |
| BE (1) | BE776823A (enExample) |
| BR (1) | BR7108434D0 (enExample) |
| CA (1) | CA960982A (enExample) |
| DE (1) | DE2149370C3 (enExample) |
| ES (1) | ES397401A1 (enExample) |
| FR (1) | FR2118919B1 (enExample) |
| GB (1) | GB1346336A (enExample) |
| IT (1) | IT944220B (enExample) |
| NL (1) | NL7117718A (enExample) |
| SE (1) | SE372035B (enExample) |
| ZA (1) | ZA717670B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3869378A (en) * | 1971-11-16 | 1975-03-04 | Sun Oil Co Pennsylvania | Combination cracking process |
| US4040979A (en) * | 1976-02-23 | 1977-08-09 | Uop Inc. | Hydrocarbon conversion catalytic composite |
| GB8726838D0 (en) * | 1987-11-17 | 1987-12-23 | Shell Int Research | Preparation of light hydrocarbon distillates |
| US4990242A (en) * | 1989-06-14 | 1991-02-05 | Exxon Research And Engineering Company | Enhanced sulfur removal from fuels |
| US5961815A (en) * | 1995-08-28 | 1999-10-05 | Catalytic Distillation Technologies | Hydroconversion process |
| US6495029B1 (en) | 1997-08-22 | 2002-12-17 | Exxon Research And Engineering Company | Countercurrent desulfurization process for refractory organosulfur heterocycles |
| CA2243267C (en) | 1997-09-26 | 2003-12-30 | Exxon Research And Engineering Company | Countercurrent reactor with interstage stripping of nh3 and h2s in gas/liquid contacting zones |
| US6569314B1 (en) | 1998-12-07 | 2003-05-27 | Exxonmobil Research And Engineering Company | Countercurrent hydroprocessing with trickle bed processing of vapor product stream |
| US6497810B1 (en) | 1998-12-07 | 2002-12-24 | Larry L. Laccino | Countercurrent hydroprocessing with feedstream quench to control temperature |
| US6623621B1 (en) | 1998-12-07 | 2003-09-23 | Exxonmobil Research And Engineering Company | Control of flooding in a countercurrent flow reactor by use of temperature of liquid product stream |
| US6579443B1 (en) | 1998-12-07 | 2003-06-17 | Exxonmobil Research And Engineering Company | Countercurrent hydroprocessing with treatment of feedstream to remove particulates and foulant precursors |
| US6835301B1 (en) | 1998-12-08 | 2004-12-28 | Exxon Research And Engineering Company | Production of low sulfur/low aromatics distillates |
| US6617871B2 (en) * | 2001-07-09 | 2003-09-09 | Rambus Inc. | Methods and apparatus for bi-directional signaling |
| GB0312966D0 (en) * | 2003-06-05 | 2003-07-09 | Bp Chem Int Ltd | Process for the production of olefins |
| JP2007502699A (ja) * | 2003-08-18 | 2007-02-15 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 分配装置 |
| US20100314290A1 (en) * | 2009-06-10 | 2010-12-16 | Co2 Solutions Llc | Fluid catalytic cracking process including flue gas conversion process |
| FR3090684B1 (fr) * | 2018-12-19 | 2021-08-27 | Ifp Energies Now | Conversion d’un brut pétrolier en lit fluidisé, avec zones de différents temps de contact |
| EP3990578A1 (en) | 2019-08-05 | 2022-05-04 | SABIC Global Technologies, B.V. | Dense phase riser to maximize light olefins yields for naphtha catalytic cracking |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3098029A (en) * | 1959-07-22 | 1963-07-16 | Socony Mobil Oil Co Inc | Combination catalytic crackinghydroprocessing operation |
| US3186935A (en) * | 1962-01-30 | 1965-06-01 | Union Oil Co | Hydrogenation process and apparatus |
| US3211641A (en) * | 1962-04-11 | 1965-10-12 | Socony Mobil Oil Co Inc | Gas-liquid reactions and apparatus therefor, for the hydrogenation and hydrocrackingof hydrocarbons |
| US3448037A (en) * | 1968-06-18 | 1969-06-03 | Dorrance P Bunn Jr | Cracking with crystalline zeolite catalyst |
| US3607723A (en) * | 1969-03-28 | 1971-09-21 | Texaco Inc | Split flow hydrocracking process |
-
1970
- 1970-12-24 US US101444A patent/US3671420A/en not_active Expired - Lifetime
-
1971
- 1971-07-08 CA CA117,778A patent/CA960982A/en not_active Expired
- 1971-10-02 DE DE2149370A patent/DE2149370C3/de not_active Expired
- 1971-11-15 ZA ZA717670A patent/ZA717670B/xx unknown
- 1971-11-16 GB GB5307171A patent/GB1346336A/en not_active Expired
- 1971-11-26 ES ES397401A patent/ES397401A1/es not_active Expired
- 1971-12-15 FR FR7145004A patent/FR2118919B1/fr not_active Expired
- 1971-12-16 BE BE776823A patent/BE776823A/xx unknown
- 1971-12-20 SE SE7116358A patent/SE372035B/xx unknown
- 1971-12-20 BR BR8434/71A patent/BR7108434D0/pt unknown
- 1971-12-22 IT IT32736/71A patent/IT944220B/it active
- 1971-12-23 NL NL7117718A patent/NL7117718A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1346336A (en) | 1974-02-06 |
| FR2118919A1 (enExample) | 1972-08-04 |
| FR2118919B1 (enExample) | 1975-08-29 |
| SE372035B (sv) | 1974-12-09 |
| BR7108434D0 (pt) | 1973-05-03 |
| IT944220B (it) | 1973-04-20 |
| NL7117718A (enExample) | 1972-06-27 |
| ES397401A1 (es) | 1974-06-01 |
| US3671420A (en) | 1972-06-20 |
| CA960982A (en) | 1975-01-14 |
| DE2149370A1 (de) | 1972-07-13 |
| DE2149370B2 (de) | 1977-09-22 |
| AU3634671A (en) | 1973-06-07 |
| BE776823A (fr) | 1972-06-16 |
| ZA717670B (en) | 1973-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EHJ | Ceased/non-payment of the annual fee |