DE2103678A1 - - Google Patents
Info
- Publication number
- DE2103678A1 DE2103678A1 DE19712103678 DE2103678A DE2103678A1 DE 2103678 A1 DE2103678 A1 DE 2103678A1 DE 19712103678 DE19712103678 DE 19712103678 DE 2103678 A DE2103678 A DE 2103678A DE 2103678 A1 DE2103678 A1 DE 2103678A1
- Authority
- DE
- Germany
- Prior art keywords
- benzene
- chlorine
- polymers
- copolymers
- tris
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 34
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000000460 chlorine Substances 0.000 claims description 19
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 18
- 229910052801 chlorine Inorganic materials 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003017 thermal stabilizer Substances 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 description 23
- 238000002845 discoloration Methods 0.000 description 9
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 7
- -1 aliphatic alcohols Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000005033 polyvinylidene chloride Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 235000012424 soybean oil Nutrition 0.000 description 5
- 239000003549 soybean oil Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- 239000004801 Chlorinated PVC Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- YAUPZUPLDOYFST-UHFFFAOYSA-N dodecanoic acid;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound CCC(CO)(CO)CO.CCCCCCCCCCCC(O)=O YAUPZUPLDOYFST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- KCWGHIAGIBAKFB-UHFFFAOYSA-N ethane-1,2-diamine;octadecanoic acid Chemical compound NCCN.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O KCWGHIAGIBAKFB-UHFFFAOYSA-N 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N hydroxymethyl benzene Natural products OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- MKOIQZIVZSVNPT-UHFFFAOYSA-N 1-(2,3-diacetylphenyl)ethanone Chemical class CC(=O)C1=CC=CC(C(C)=O)=C1C(C)=O MKOIQZIVZSVNPT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920003346 Levapren® Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229920001986 Vinylidene chloride-vinyl chloride copolymer Polymers 0.000 description 1
- XPOHJXHLJGTWRK-UHFFFAOYSA-N [2,3,4,5,6-pentakis(hydroxymethyl)phenyl]methanol Chemical compound OCC1=C(CO)C(CO)=C(CO)C(CO)=C1CO XPOHJXHLJGTWRK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 description 1
- 229940059864 chlorine containing product ectoparasiticides Drugs 0.000 description 1
- 238000006006 cyclotrimerization reaction Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940058172 ethylbenzene Drugs 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920006214 polyvinylidene halide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712103678 DE2103678A1 (https=) | 1971-01-27 | 1971-01-27 | |
| US00219499A US3763096A (en) | 1971-01-27 | 1972-01-20 | Chlorine containing thermostabilized polymers |
| IT47834/72A IT948264B (it) | 1971-01-27 | 1972-01-20 | Polimeri e copolimeri clorurati termostabilizzati e masse modellate ottenute da essi |
| FR7202616A FR2124877A5 (https=) | 1971-01-27 | 1972-01-26 | |
| NL7201108A NL7201108A (https=) | 1971-01-27 | 1972-01-27 | |
| BE778570A BE778570A (fr) | 1971-01-27 | 1972-01-27 | Polymeres et copolymeres chlores thermostabilises et masses de moulage en resultant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712103678 DE2103678A1 (https=) | 1971-01-27 | 1971-01-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2103678A1 true DE2103678A1 (https=) | 1972-08-17 |
Family
ID=5796988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712103678 Pending DE2103678A1 (https=) | 1971-01-27 | 1971-01-27 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3763096A (https=) |
| BE (1) | BE778570A (https=) |
| DE (1) | DE2103678A1 (https=) |
| FR (1) | FR2124877A5 (https=) |
| IT (1) | IT948264B (https=) |
| NL (1) | NL7201108A (https=) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5659069A (en) * | 1996-03-20 | 1997-08-19 | Nexstar Pharmaceuticals, Inc. | Method for the cyclotrimerization of alkynes in aqueous solutions |
-
1971
- 1971-01-27 DE DE19712103678 patent/DE2103678A1/de active Pending
-
1972
- 1972-01-20 IT IT47834/72A patent/IT948264B/it active
- 1972-01-20 US US00219499A patent/US3763096A/en not_active Expired - Lifetime
- 1972-01-26 FR FR7202616A patent/FR2124877A5/fr not_active Expired
- 1972-01-27 BE BE778570A patent/BE778570A/xx unknown
- 1972-01-27 NL NL7201108A patent/NL7201108A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IT948264B (it) | 1973-05-30 |
| BE778570A (fr) | 1972-05-16 |
| NL7201108A (https=) | 1972-07-31 |
| FR2124877A5 (https=) | 1972-09-22 |
| US3763096A (en) | 1973-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2917496C2 (de) | Vulkanisierbare fluorierte Kautschukmasse | |
| DE1569021B2 (de) | Flammschutzmittel für synthetische organische Polymere | |
| DE2733695A1 (de) | Stabilisierte feuerhemmende styrolpolymermischungen | |
| DE69214718T2 (de) | 4,4'-Biphenylendiphosphonit Verbindungen und ihre Verwendung | |
| DE1569374B2 (de) | Vinylchloridpolymerisat stabilisator kombination und mit dieser stabilisierte vinylchloridpolymerisat masse | |
| DE1469941B2 (de) | Verwendung eines Gemisches von Organozinnstabilisatoren und Schwefelverbindungen zur Stabilisierung von halogenhaltigen Polymeri satkuns ts toffmas sen | |
| DD207917A5 (de) | Verfahren zum stabilisieren von polymerisaten auf der basis von vinylchlorid | |
| DE2728862A1 (de) | Stabilisierte formmassen auf der basis von vinylchlorid-polymerisaten | |
| DE2560036C2 (de) | Monomethylzinn-tris-thioglykolsäure-n-tetradecylester | |
| US3342767A (en) | Vinyl chloride resins containing cyclic phosphites | |
| NL8003266A (nl) | Vinylhalogenidestabilisatorsamenstellingen met lage toxiciteit. | |
| EP0253985B1 (de) | Stabilisierte Formmassen auf der Basis von Polyvinylchlorid oder Vinylchlorid-Copolymerisaten und Stabilisatorsystem | |
| DE2103678A1 (https=) | ||
| DE850228C (de) | Verfahren zur Herstellung von waerme- und lichtbestaendigen halogenhaltigen Harzen | |
| DE1282939B (de) | Schwerentflammbare, ein Styrolpolymerisat enthaltende Formmassen | |
| DE2522510C2 (de) | Zusammensetzung zur Herstellung von zelligen Vinylchloridpolymeren | |
| DE2446116C2 (de) | Stabilisatorkombinationen fuer halogenhaltige polymere | |
| EP0377428A1 (de) | Verarbeitungszusatz für halogenhaltige Polymere | |
| DE2005290A1 (de) | Neue Organo-Zinnverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren für Vinylhalogenidpolymerisate | |
| DE1544960B2 (de) | Stabilisierte halogenhaltige vinylpolymensate | |
| DE2652408C3 (de) | Wärmestabilisierung von Formmassen auf der Basis von Vinylchloridhomo- oder-copolymerisaten | |
| DE1806494C2 (de) | Stabilisatormischung für Halogen enthaltende Polymere | |
| DE1668701B2 (de) | Waermestabile halogenhaltige polymerisatmassen | |
| DE2300114B2 (de) | Selbstverlöschende Styrolpolymerisate | |
| DE1273811B (de) | Stabilisatoren fuer chlorhaltige Polymerisate |