DE2100784A1 - Verfahren zur gleichzeitigen Herstel lung von Wasserstoffperoxyd und ahphati sehen oder alicychschen Peroxyden - Google Patents
Verfahren zur gleichzeitigen Herstel lung von Wasserstoffperoxyd und ahphati sehen oder alicychschen PeroxydenInfo
- Publication number
- DE2100784A1 DE2100784A1 DE19712100784 DE2100784A DE2100784A1 DE 2100784 A1 DE2100784 A1 DE 2100784A1 DE 19712100784 DE19712100784 DE 19712100784 DE 2100784 A DE2100784 A DE 2100784A DE 2100784 A1 DE2100784 A1 DE 2100784A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen peroxide
- acid
- hydroperoxide
- peroxides
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 95
- 238000000034 method Methods 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 150000002978 peroxides Chemical class 0.000 title description 9
- 239000002253 acid Substances 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 235000011007 phosphoric acid Nutrition 0.000 claims description 8
- -1 alicyclic peroxides Chemical class 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical group [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 229940079864 sodium stannate Drugs 0.000 claims description 5
- 229940071182 stannate Drugs 0.000 claims description 5
- 150000002432 hydroperoxides Chemical class 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 239000011260 aqueous acid Substances 0.000 claims description 2
- RSGPROFUAZQXLV-UHFFFAOYSA-N hydrogen peroxide;2-hydroperoxy-2-methylpropane Chemical compound OO.CC(C)(C)OO RSGPROFUAZQXLV-UHFFFAOYSA-N 0.000 claims 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000012429 reaction media Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- HTJGRZDJSPNCJU-UHFFFAOYSA-N 1-hydroperoxy-1-methylcyclopentane Chemical compound OOC1(C)CCCC1 HTJGRZDJSPNCJU-UHFFFAOYSA-N 0.000 description 2
- SPQMVUPFYWDFCB-UHFFFAOYSA-N 2-hydroperoxybutane Chemical compound CCC(C)OO SPQMVUPFYWDFCB-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 125000005402 stannate group Chemical group 0.000 description 2
- 150000003606 tin compounds Chemical class 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- UUUYXCLERBDLEO-UHFFFAOYSA-N 1-hydroperoxy-1-methylcyclohexane Chemical compound OOC1(C)CCCCC1 UUUYXCLERBDLEO-UHFFFAOYSA-N 0.000 description 1
- QAPLQMROVGLYLM-UHFFFAOYSA-N 2-butan-2-ylperoxybutane Chemical compound CCC(C)OOC(C)CC QAPLQMROVGLYLM-UHFFFAOYSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001334 alicyclic compounds Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US268170A | 1970-01-13 | 1970-01-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2100784A1 true DE2100784A1 (de) | 1971-07-22 |
Family
ID=21701953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712100784 Pending DE2100784A1 (de) | 1970-01-13 | 1971-01-08 | Verfahren zur gleichzeitigen Herstel lung von Wasserstoffperoxyd und ahphati sehen oder alicychschen Peroxyden |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3653832A (en, 2012) |
| JP (1) | JPS4830838B1 (en, 2012) |
| BE (1) | BE761401A (en, 2012) |
| CA (1) | CA951874A (en, 2012) |
| CH (1) | CH563943A5 (en, 2012) |
| DE (1) | DE2100784A1 (en, 2012) |
| FR (1) | FR2076067B1 (en, 2012) |
| GB (1) | GB1315621A (en, 2012) |
| NL (1) | NL7019001A (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3899576A (en) * | 1973-08-20 | 1975-08-12 | Atlantic Richfield Co | Cyclic process for the production of hydrogen peroxide |
| US4131646A (en) * | 1977-09-16 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Preparation of hydrogen peroxide from dihydroanthracene hydroperoxides |
| DE4210425C2 (de) * | 1992-03-30 | 1994-04-21 | Degussa | Stabilisierte Percarbonsäurelösungen und Verfahren zu deren Herstellung |
| JP4743975B2 (ja) * | 2001-01-18 | 2011-08-10 | 丸善石油化学株式会社 | ラクトンの製造方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2497814A (en) * | 1947-04-17 | 1950-02-14 | Du Pont | Stabilization of peroxide solutions |
| US2522016A (en) * | 1948-12-13 | 1950-09-12 | California Research Corp | Di-organo peroxide |
-
1970
- 1970-01-13 US US2681A patent/US3653832A/en not_active Expired - Lifetime
- 1970-12-28 JP JP45120557A patent/JPS4830838B1/ja active Pending
- 1970-12-30 NL NL7019001A patent/NL7019001A/xx unknown
-
1971
- 1971-01-04 GB GB28371A patent/GB1315621A/en not_active Expired
- 1971-01-08 DE DE19712100784 patent/DE2100784A1/de active Pending
- 1971-01-08 CH CH27171A patent/CH563943A5/xx not_active IP Right Cessation
- 1971-01-11 FR FR7100591A patent/FR2076067B1/fr not_active Expired
- 1971-01-11 BE BE761401A patent/BE761401A/xx unknown
- 1971-01-12 CA CA102,499A patent/CA951874A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4830838B1 (en, 2012) | 1973-09-25 |
| NL7019001A (en, 2012) | 1971-07-15 |
| FR2076067B1 (en, 2012) | 1974-09-27 |
| FR2076067A1 (en, 2012) | 1971-10-15 |
| BE761401A (fr) | 1971-07-12 |
| GB1315621A (en) | 1973-05-02 |
| CA951874A (en) | 1974-07-30 |
| CH563943A5 (en, 2012) | 1975-07-15 |
| US3653832A (en) | 1972-04-04 |
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