DE2038765A1 - Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier Gase - Google Patents
Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier GaseInfo
- Publication number
- DE2038765A1 DE2038765A1 DE19702038765 DE2038765A DE2038765A1 DE 2038765 A1 DE2038765 A1 DE 2038765A1 DE 19702038765 DE19702038765 DE 19702038765 DE 2038765 A DE2038765 A DE 2038765A DE 2038765 A1 DE2038765 A1 DE 2038765A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon dioxide
- resin
- layer
- air
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 134
- 239000001569 carbon dioxide Substances 0.000 title claims description 67
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 67
- 239000007789 gas Substances 0.000 title claims description 47
- 238000000034 method Methods 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 12
- 230000008569 process Effects 0.000 title description 12
- 238000000926 separation method Methods 0.000 title description 9
- 239000011347 resin Substances 0.000 claims description 49
- 229920005989 resin Polymers 0.000 claims description 49
- 150000001412 amines Chemical class 0.000 claims description 8
- 239000003456 ion exchange resin Substances 0.000 claims description 6
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 claims description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- -1 nitrogen amine Chemical group 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 3
- 239000002775 capsule Substances 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 230000029058 respiratory gaseous exchange Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 description 16
- 230000009102 absorption Effects 0.000 description 15
- 238000010521 absorption reaction Methods 0.000 description 15
- 230000008929 regeneration Effects 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000009833 condensation Methods 0.000 description 11
- 230000005494 condensation Effects 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000009103 reabsorption Effects 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 206010042674 Swelling Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000006012 detection of carbon dioxide Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/07—Processes using organic exchangers in the weakly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/206—Ion exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0454—Controlling adsorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84932069A | 1969-08-12 | 1969-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2038765A1 true DE2038765A1 (de) | 1971-02-25 |
Family
ID=25305553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702038765 Pending DE2038765A1 (de) | 1969-08-12 | 1970-08-04 | Verfahren zur Trennung von Kohlendioxyd aus einer Mischung saeurefreier Gase |
Country Status (3)
| Country | Link |
|---|---|
| CA (1) | CA934939A (https=) |
| DE (1) | DE2038765A1 (https=) |
| GB (1) | GB1296889A (https=) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1307053B1 (it) * | 1999-09-23 | 2001-10-23 | Edison Termoelettrica Spa | Unita' di assorbimento dell'anidride carbonica e metodo dirigenerazione di tale unita'. |
| US6755892B2 (en) | 2000-08-17 | 2004-06-29 | Hamilton Sundstrand | Carbon dioxide scrubber for fuel and gas emissions |
| WO2006023743A2 (en) | 2004-08-20 | 2006-03-02 | The Trustees Of Columbia University In The City Of New York | Laminar scrubber apparatus for capturing carbon dioxide from air and methods of use |
| EP2409753B1 (en) * | 2005-07-28 | 2017-07-19 | Carbon Sink Inc. | Removal of carbon dioxide from air |
| US9266051B2 (en) | 2005-07-28 | 2016-02-23 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| RU2008139902A (ru) | 2006-03-08 | 2010-04-20 | ГЛОБАЛ РИСЕРЧ ТЕКНОЛОДЖИЗ, ЭлЭлСи (US) | Воздухозаборное устройство с функционализированной ионообменной мембраной для улавливания co2 из внешней среды |
| NZ575870A (en) | 2006-10-02 | 2012-02-24 | Global Res Technologies Llc | Method and apparatus for extracting carbon dioxide from ambient air |
| US8715393B2 (en) | 2007-04-17 | 2014-05-06 | Kilimanjaro Energy, Inc. | Capture of carbon dioxide (CO2) from air |
| CA2703617A1 (en) | 2007-11-05 | 2009-05-14 | Global Research Technologies, Llc | Removal of carbon dioxide from air |
| US8262774B2 (en) | 2007-11-20 | 2012-09-11 | Kilimanjaro Energy, Inc. | Air collector with functionalized ion exchange membrane for capturing ambient CO2 |
| CA3047633C (en) | 2008-02-19 | 2023-08-01 | Carbon Sink Inc. | Extraction and sequestration of carbon dioxide |
| WO2009149292A1 (en) | 2008-06-04 | 2009-12-10 | Global Research Technologies, Llc | Laminar flow air collector with solid sorbent materials for capturing ambient co2 |
| US9028590B2 (en) | 2009-10-19 | 2015-05-12 | Lanxess Deutschland Gmbh | Process and apparatus for carbon dioxide and carbonyl sulfide capture via ion exchange resins |
| EP2490789B1 (en) | 2009-10-19 | 2014-08-06 | Lanxess Sybron Chemicals Inc. | Process for carbon dioxide capture via ion exchange resins |
| EP2563495B1 (en) * | 2010-04-30 | 2019-09-25 | Peter Eisenberger | Method for carbon dioxide capture |
| WO2013104364A1 (en) | 2011-12-22 | 2013-07-18 | Re-N Technology Aps | A method for upgrading a gas |
| ES2717928T3 (es) * | 2012-08-31 | 2019-06-26 | Lanxess Sybron Chemicals Inc | Proceso para la captura de sulfuro de carbonilo a través de resinas de intercambio iónico |
| JP5936517B2 (ja) * | 2012-10-24 | 2016-06-22 | 株式会社日立製作所 | Ｃｏ２回収システム |
| WO2014073004A2 (en) * | 2012-11-08 | 2014-05-15 | Airef Engineers Pvt. Ltd. | Carbondioxide removal system |
| EP3166708B1 (en) * | 2014-07-10 | 2021-11-10 | Climeworks AG | Steam assisted vacuum desorption process for carbon dioxide capture |
| WO2019161114A1 (en) | 2018-02-16 | 2019-08-22 | Carbon Sink, Inc. | Fluidized bed extractors for capture of co2 from ambient air |
| ES2952749T3 (es) | 2018-06-14 | 2023-11-03 | Climeworks Ag | Método y dispositivo para la adsorción/desorción de dióxido de carbono de corrientes de gas con unidad de recuperación de calor |
| US20230173427A1 (en) | 2020-05-27 | 2023-06-08 | Climeworks Ag | Atmospheric steam desorption for direct air capture |
| US20230201759A1 (en) | 2020-05-27 | 2023-06-29 | Climeworks Ag | Methods and devices for steam driven carbon dioxide capture |
| US12582935B2 (en) | 2020-05-29 | 2026-03-24 | Climeworks Ag | Method for capture of carbon dioxide from ambient air and corresponding adsorber structures with a plurality of parallel surfaces |
| WO2024002881A1 (en) | 2022-06-28 | 2024-01-04 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| JP2025521914A (ja) | 2022-07-01 | 2025-07-10 | ダブリュ．エル．ゴア アンド アソシエイツ，インコーポレイティド | 吸着ガス分離プロセス用の粒子吸着床のための外部支持体を備えた構造 |
| WO2024039641A1 (en) | 2022-08-15 | 2024-02-22 | W. L. Gore & Associates, Inc. | Structures and methods for enhancing capture of carbon dioxide from ambient air |
| WO2024132899A1 (en) | 2022-12-21 | 2024-06-27 | Climeworks Ag | Uses of amino sorbents for capturing of co2 from gas streams |
| WO2025008318A1 (en) | 2023-07-05 | 2025-01-09 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| WO2025114104A2 (en) | 2023-11-27 | 2025-06-05 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
| WO2025228763A1 (en) | 2024-04-30 | 2025-11-06 | Climeworks Ag | Sorbent materials for co2 capture, uses thereof and methods for making same |
-
1970
- 1970-07-17 CA CA088522A patent/CA934939A/en not_active Expired
- 1970-07-22 GB GB1296889D patent/GB1296889A/en not_active Expired
- 1970-08-04 DE DE19702038765 patent/DE2038765A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA934939A (en) | 1973-10-09 |
| GB1296889A (https=) | 1972-11-22 |
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