DE2030741A1 - Mischpolyamid - Google Patents
MischpolyamidInfo
- Publication number
- DE2030741A1 DE2030741A1 DE19702030741 DE2030741A DE2030741A1 DE 2030741 A1 DE2030741 A1 DE 2030741A1 DE 19702030741 DE19702030741 DE 19702030741 DE 2030741 A DE2030741 A DE 2030741A DE 2030741 A1 DE2030741 A1 DE 2030741A1
- Authority
- DE
- Germany
- Prior art keywords
- mol
- terephthalamide
- mixed polyamide
- mixed
- consists essentially
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004952 Polyamide Substances 0.000 title claims description 75
- 229920002647 polyamide Polymers 0.000 title claims description 75
- 238000002844 melting Methods 0.000 claims description 25
- 230000008018 melting Effects 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 24
- ZWUNKULTLYLLTH-UHFFFAOYSA-N cyclohexane-1,4-dicarboxamide Chemical group NC(=O)C1CCC(C(N)=O)CC1 ZWUNKULTLYLLTH-UHFFFAOYSA-N 0.000 claims description 17
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical group NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 claims description 6
- OCBDCKOLSAYNMN-UHFFFAOYSA-N 4-(azacyclotridecane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCCCCCCCC1 OCBDCKOLSAYNMN-UHFFFAOYSA-N 0.000 claims description 5
- PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 claims description 5
- 150000001408 amides Chemical group 0.000 claims description 5
- NPKDHUPJIUWYFG-UHFFFAOYSA-N 4-(azecane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCCCCC1 NPKDHUPJIUWYFG-UHFFFAOYSA-N 0.000 claims description 4
- MTDGNKKKLZQYMC-UHFFFAOYSA-N 4-(azepane-1-carbonyl)cyclohexane-1-carboxamide Chemical compound C1CC(C(=O)N)CCC1C(=O)N1CCCCCC1 MTDGNKKKLZQYMC-UHFFFAOYSA-N 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 47
- 238000006116 polymerization reaction Methods 0.000 description 33
- 238000000034 method Methods 0.000 description 29
- 239000000203 mixture Substances 0.000 description 28
- 229920000642 polymer Polymers 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 20
- 238000003756 stirring Methods 0.000 description 12
- 238000009987 spinning Methods 0.000 description 10
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
- 239000004953 Aliphatic polyamide Substances 0.000 description 7
- 229920003231 aliphatic polyamide Polymers 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- -1 polyhexamethylene Polymers 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000005711 Benzoic acid Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 235000008001 rakum palm Nutrition 0.000 description 3
- 244000217124 rakum palm Species 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 241000396377 Tranes Species 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 2
- 229920006240 drawn fiber Polymers 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- KLNPWTHGTVSSEU-UHFFFAOYSA-N undecane-1,11-diamine Chemical compound NCCCCCCCCCCCN KLNPWTHGTVSSEU-UHFFFAOYSA-N 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- AFXJEJPYQGJFGK-UHFFFAOYSA-N 2-methylidenecyclohexane-1,4-dicarboxamide Chemical compound NC(=O)C1CCC(C(N)=O)C(=C)C1 AFXJEJPYQGJFGK-UHFFFAOYSA-N 0.000 description 1
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 101100206738 Mus musculus Tiam2 gene Proteins 0.000 description 1
- 241001077673 Mylon Species 0.000 description 1
- 241000237509 Patinopecten sp. Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000718541 Tetragastris balsamifera Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 229940032465 fenethylline Drugs 0.000 description 1
- NMCHYWGKBADVMK-UHFFFAOYSA-N fenetylline Chemical group C1=NC=2N(C)C(=O)N(C)C(=O)C=2N1CCNC(C)CC1=CC=CC=C1 NMCHYWGKBADVMK-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 235000020637 scallop Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 210000002435 tendon Anatomy 0.000 description 1
- 150000003503 terephthalic acid derivatives Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4936069 | 1969-06-24 | ||
| JP5408569 | 1969-07-10 | ||
| JP5900969 | 1969-07-28 | ||
| JP7778969 | 1969-10-01 | ||
| JP9160069 | 1969-11-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2030741A1 true DE2030741A1 (de) | 1971-01-07 |
Family
ID=27522791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702030741 Pending DE2030741A1 (de) | 1969-06-24 | 1970-06-23 | Mischpolyamid |
Country Status (4)
| Country | Link |
|---|---|
| AU (1) | AU1667270A (OSRAM) |
| DE (1) | DE2030741A1 (OSRAM) |
| FR (1) | FR2052875A5 (OSRAM) |
| NL (1) | NL7009082A (OSRAM) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2729190A1 (de) * | 1976-06-28 | 1977-12-29 | Rhone Poulenc Ind | Neue copolyamide auf basis von hexamethylenadipamid |
| EP0725101B1 (de) * | 1995-02-01 | 1998-04-01 | Ems-Inventa Ag | Transparente, farblose amorphe Polyamide und Formteile |
| DE102004040151A1 (de) * | 2004-08-19 | 2006-03-09 | Hosokawa Alpine Ag | Folienblaskopf für die Herstellung von Schlauchfolien |
-
1970
- 1970-06-19 NL NL7009082A patent/NL7009082A/xx unknown
- 1970-06-23 AU AU16672/70A patent/AU1667270A/en not_active Expired
- 1970-06-23 DE DE19702030741 patent/DE2030741A1/de active Pending
- 1970-06-23 FR FR7023188A patent/FR2052875A5/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2729190A1 (de) * | 1976-06-28 | 1977-12-29 | Rhone Poulenc Ind | Neue copolyamide auf basis von hexamethylenadipamid |
| EP0725101B1 (de) * | 1995-02-01 | 1998-04-01 | Ems-Inventa Ag | Transparente, farblose amorphe Polyamide und Formteile |
| DE102004040151A1 (de) * | 2004-08-19 | 2006-03-09 | Hosokawa Alpine Ag | Folienblaskopf für die Herstellung von Schlauchfolien |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7009082A (OSRAM) | 1970-12-29 |
| FR2052875A5 (en) | 1971-04-09 |
| AU1667270A (en) | 1972-01-06 |
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