DE1954284A1 - Verfahren zur AEnderung der Oberflaechenbenetzungs- und -haftungseigenschaften von poylmeren Formkoerpern - Google Patents
Verfahren zur AEnderung der Oberflaechenbenetzungs- und -haftungseigenschaften von poylmeren FormkoerpernInfo
- Publication number
- DE1954284A1 DE1954284A1 DE19691954284 DE1954284A DE1954284A1 DE 1954284 A1 DE1954284 A1 DE 1954284A1 DE 19691954284 DE19691954284 DE 19691954284 DE 1954284 A DE1954284 A DE 1954284A DE 1954284 A1 DE1954284 A1 DE 1954284A1
- Authority
- DE
- Germany
- Prior art keywords
- gas
- treated
- film
- reactive gas
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 69
- 238000000465 moulding Methods 0.000 title claims description 20
- 230000008569 process Effects 0.000 title claims description 19
- 238000009736 wetting Methods 0.000 title claims description 7
- 229920000642 polymer Polymers 0.000 title description 30
- 239000007789 gas Substances 0.000 claims description 99
- 239000012190 activator Substances 0.000 claims description 23
- 150000003254 radicals Chemical class 0.000 claims description 23
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 19
- LZDSILRDTDCIQT-UHFFFAOYSA-N dinitrogen trioxide Chemical compound [O-][N+](=O)N=O LZDSILRDTDCIQT-UHFFFAOYSA-N 0.000 claims description 10
- 150000002894 organic compounds Chemical class 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 7
- 230000005672 electromagnetic field Effects 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 7
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000001307 helium Substances 0.000 claims description 6
- 229910052734 helium Inorganic materials 0.000 claims description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 6
- 239000004157 Nitrosyl chloride Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229910052743 krypton Inorganic materials 0.000 claims description 3
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052754 neon Inorganic materials 0.000 claims description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019392 nitrosyl chloride Nutrition 0.000 claims description 3
- 239000001272 nitrous oxide Substances 0.000 claims description 3
- 229910052704 radon Inorganic materials 0.000 claims description 3
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052724 xenon Inorganic materials 0.000 claims description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 50
- 239000000839 emulsion Substances 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 22
- 230000005855 radiation Effects 0.000 description 16
- -1 B. water Chemical class 0.000 description 13
- 229920000298 Cellophane Polymers 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 11
- 239000008273 gelatin Substances 0.000 description 11
- 229920000159 gelatin Polymers 0.000 description 11
- 235000019322 gelatine Nutrition 0.000 description 11
- 235000011852 gelatine desserts Nutrition 0.000 description 11
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 10
- 230000004913 activation Effects 0.000 description 9
- 230000008859 change Effects 0.000 description 9
- 230000036961 partial effect Effects 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 229920006254 polymer film Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 230000005670 electromagnetic radiation Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 239000012634 fragment Substances 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229920001600 hydrophobic polymer Polymers 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920006267 polyester film Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229960003753 nitric oxide Drugs 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000035508 accumulation Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 210000004905 finger nail Anatomy 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910001872 inorganic gas Inorganic materials 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 150000002835 noble gases Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920006289 polycarbonate film Polymers 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- 241000282465 Canis Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 210000005224 forefinger Anatomy 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010505 homolytic fission reaction Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- RVEZZJVBDQCTEF-UHFFFAOYSA-N sulfenic acid Chemical compound SO RVEZZJVBDQCTEF-UHFFFAOYSA-N 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77274568A | 1968-11-01 | 1968-11-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1954284A1 true DE1954284A1 (de) | 1970-08-27 |
Family
ID=25096090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19691954284 Pending DE1954284A1 (de) | 1968-11-01 | 1969-10-28 | Verfahren zur AEnderung der Oberflaechenbenetzungs- und -haftungseigenschaften von poylmeren Formkoerpern |
Country Status (11)
| Country | Link |
|---|---|
| BE (1) | BE736993A (https=) |
| BR (1) | BR6913669D0 (https=) |
| CA (1) | CA1023297A (https=) |
| CH (1) | CH517140A (https=) |
| CS (1) | CS154647B2 (https=) |
| DE (1) | DE1954284A1 (https=) |
| ES (1) | ES373069A1 (https=) |
| FR (1) | FR2022357A1 (https=) |
| GB (1) | GB1294116A (https=) |
| NL (1) | NL6916564A (https=) |
| SU (1) | SU403148A3 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0073427A1 (de) * | 1981-09-01 | 1983-03-09 | Agfa-Gevaert AG | Verfahren und Vorrichtung zur Vorbehandlung von polymeren Trägermaterialien |
| DE102005030691A1 (de) * | 2005-06-29 | 2007-01-11 | Ahlbrandt System Gmbh | Verfahren zur Erhöhung der Oberflächenspannung der Oberfläche von vorzugsweise flächigen Kunststoff-Gebilden mittels einer Koronaentladung |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8909685D0 (en) * | 1989-04-27 | 1989-06-14 | British Petroleum Co Plc | Method for reducing fouling |
| US10470511B2 (en) | 2016-08-19 | 2019-11-12 | Levi Strauss & Co. | Using laser to create finishing pattern on apparel |
| EP3704608A4 (en) | 2017-10-31 | 2021-08-18 | Levi Strauss & Co. | USE OF NEURAL NETWORKS IN CLOTHING DESIGN |
| US10712922B2 (en) | 2017-10-31 | 2020-07-14 | Levi Strauss & Co. | Laser finishing design tool with damage assets |
| WO2019169053A1 (en) | 2018-02-27 | 2019-09-06 | Levi Strauss & Co. | Laser finishing design tool |
| CN112272596B (zh) | 2018-02-27 | 2023-06-23 | 利惠商业有限公司 | 激光整理服装的按需制造 |
| US10793998B2 (en) | 2018-08-07 | 2020-10-06 | Levi Strauss & Co. | Outdoor retail space structure |
| CN113302354B (zh) | 2018-11-30 | 2023-11-14 | 利惠商业有限公司 | 阴影中性3-d服装渲染 |
| EP4004270A4 (en) | 2019-07-23 | 2023-07-05 | Levi Strauss & Co. | 3D RENDER PREVIEW OF LASER-PRODUCED CLOTHING |
-
1969
- 1969-08-01 BE BE736993D patent/BE736993A/xx unknown
- 1969-10-09 CA CA064,562A patent/CA1023297A/en not_active Expired
- 1969-10-27 BR BR21366969A patent/BR6913669D0/pt unknown
- 1969-10-28 DE DE19691954284 patent/DE1954284A1/de active Pending
- 1969-10-29 FR FR6937173A patent/FR2022357A1/fr not_active Withdrawn
- 1969-10-30 GB GB5314869A patent/GB1294116A/en not_active Expired
- 1969-10-31 ES ES373069A patent/ES373069A1/es not_active Expired
- 1969-10-31 CS CS721169A patent/CS154647B2/cs unknown
- 1969-10-31 SU SU1375006A patent/SU403148A3/ru active
- 1969-10-31 CH CH33671A patent/CH517140A/fr not_active IP Right Cessation
- 1969-11-03 NL NL6916564A patent/NL6916564A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0073427A1 (de) * | 1981-09-01 | 1983-03-09 | Agfa-Gevaert AG | Verfahren und Vorrichtung zur Vorbehandlung von polymeren Trägermaterialien |
| DE102005030691A1 (de) * | 2005-06-29 | 2007-01-11 | Ahlbrandt System Gmbh | Verfahren zur Erhöhung der Oberflächenspannung der Oberfläche von vorzugsweise flächigen Kunststoff-Gebilden mittels einer Koronaentladung |
Also Published As
| Publication number | Publication date |
|---|---|
| SU403148A3 (https=) | 1973-10-19 |
| CA1023297A (en) | 1977-12-27 |
| NL6916564A (https=) | 1970-05-06 |
| CS154647B2 (https=) | 1974-04-30 |
| ES373069A1 (es) | 1971-11-16 |
| BR6913669D0 (pt) | 1973-04-19 |
| BE736993A (https=) | 1970-01-16 |
| CH517140A (fr) | 1971-12-31 |
| GB1294116A (en) | 1972-10-25 |
| FR2022357A1 (https=) | 1970-07-31 |
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