DE1945752B1 - Verfahren zur Extraktion von Wasserstoffperoxid aus Arbeitsloesungen des Alkylanthrachinonverfahrens - Google Patents
Verfahren zur Extraktion von Wasserstoffperoxid aus Arbeitsloesungen des AlkylanthrachinonverfahrensInfo
- Publication number
- DE1945752B1 DE1945752B1 DE19691945752 DE1945752A DE1945752B1 DE 1945752 B1 DE1945752 B1 DE 1945752B1 DE 19691945752 DE19691945752 DE 19691945752 DE 1945752 A DE1945752 A DE 1945752A DE 1945752 B1 DE1945752 B1 DE 1945752B1
- Authority
- DE
- Germany
- Prior art keywords
- extraction
- column
- hydrogen peroxide
- columns
- working solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000605 extraction Methods 0.000 title claims description 46
- 239000012224 working solution Substances 0.000 title claims description 33
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 21
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title claims description 11
- -1 alkyl anthraquinone Chemical class 0.000 title claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 150000003008 phosphonic acid esters Chemical class 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000007921 spray Substances 0.000 description 14
- 150000004056 anthraquinones Chemical class 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 239000012074 organic phase Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000010349 pulsation Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extraction Or Liquid Replacement (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE756013D BE756013A (fr) | 1969-09-10 | Procede pour l'extraction de peroxyde d'hydrogene des solutionsde travail du procede a l'anthraquinone | |
| DE19691945752 DE1945752B1 (de) | 1969-09-10 | 1969-09-10 | Verfahren zur Extraktion von Wasserstoffperoxid aus Arbeitsloesungen des Alkylanthrachinonverfahrens |
| ES382650A ES382650A1 (es) | 1969-09-10 | 1970-08-11 | Procedimiento para la extracion de peroxido de hidregeno desde soluciones de trabajo del procedimiento de la alcohi- lantraquinona. |
| NL7012339A NL7012339A (enExample) | 1969-09-10 | 1970-08-20 | |
| ZA705992A ZA705992B (en) | 1969-09-10 | 1970-09-01 | Method for the extraction of hydrogen peroxide from working solutions of the alkylanthraquinone process |
| CS601970A CS157110B2 (enExample) | 1969-09-10 | 1970-09-02 | |
| US00069153A US3742061A (en) | 1969-09-10 | 1970-09-02 | Process for the extraction of hydrogen peroxide from working solutions of the alkyl anthraquinone process |
| GB4219670A GB1319124A (en) | 1969-09-10 | 1970-09-03 | Extraction of hydrogen peroxide |
| AU19648/70A AU1964870A (en) | 1969-09-10 | 1970-09-08 | A process of extracting hydrogen peroxide fromthe working solutions ofthe alkylanthraquinone process |
| AT823170A AT314472B (de) | 1969-09-10 | 1970-09-10 | Verfahren zur Extraktion von Wasserstoffperoxyd aus Arbeitslösungen des Alkylanthrachinonverfahrens |
| SE12337/70A SE356496B (enExample) | 1969-09-10 | 1970-09-10 | |
| CA092,793A CA956785A (en) | 1969-09-10 | 1970-09-10 | Process for extracting hydrogen peroxide from process solutions of the alkyl anthraquinone process |
| FR7032946A FR2061269A5 (enExample) | 1969-09-10 | 1970-09-10 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691945752 DE1945752B1 (de) | 1969-09-10 | 1969-09-10 | Verfahren zur Extraktion von Wasserstoffperoxid aus Arbeitsloesungen des Alkylanthrachinonverfahrens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1945752B1 true DE1945752B1 (de) | 1971-02-11 |
Family
ID=5745063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19691945752 Pending DE1945752B1 (de) | 1969-09-10 | 1969-09-10 | Verfahren zur Extraktion von Wasserstoffperoxid aus Arbeitsloesungen des Alkylanthrachinonverfahrens |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3742061A (enExample) |
| AT (1) | AT314472B (enExample) |
| AU (1) | AU1964870A (enExample) |
| BE (1) | BE756013A (enExample) |
| CA (1) | CA956785A (enExample) |
| CS (1) | CS157110B2 (enExample) |
| DE (1) | DE1945752B1 (enExample) |
| ES (1) | ES382650A1 (enExample) |
| FR (1) | FR2061269A5 (enExample) |
| GB (1) | GB1319124A (enExample) |
| NL (1) | NL7012339A (enExample) |
| SE (1) | SE356496B (enExample) |
| ZA (1) | ZA705992B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2473488A1 (fr) * | 1980-01-14 | 1981-07-17 | Oxysynthese | Procede cyclique de production de peroxyde d'hydrogene |
| DE60140939D1 (de) * | 2000-06-19 | 2010-02-11 | Akzo Nobel Nv | Nd darin verwendete zusammensetzung |
| CZ299805B6 (cs) * | 2000-06-19 | 2008-12-03 | Akzo Nobel N. V. | Zpusob výroby peroxidu vodíku a kompozice použitelná pro provádení tohoto zpusobu |
| CA2679772A1 (en) * | 2007-03-15 | 2008-09-18 | Fmc Corporation | Recovery of aqueous hydrogen peroxide in auto-oxidation h2o2 production |
| CN107176593B (zh) * | 2016-03-11 | 2019-09-24 | 厦门大学 | 一种蒽醌法生产h2o2的氧化与萃取耦合生产新工艺及新型塔设备 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2430796A (en) * | 1945-11-13 | 1947-11-11 | Sol B Wiczer | Recovering solidified liquids |
| US2886416A (en) * | 1954-04-28 | 1959-05-12 | Columbia Southern Chem Corp | Preparation of hydrogen peroxide |
| DE1261838B (de) * | 1963-09-03 | 1968-02-29 | Degussa | Verfahren zur Herstellung von Wasserstoffperoxyd |
| US3499737A (en) * | 1968-02-20 | 1970-03-10 | Geigy Chem Corp | Method and apparatus for sparging chlorine into a reactor for producing cyanogen chloride |
-
0
- BE BE756013D patent/BE756013A/xx unknown
-
1969
- 1969-09-10 DE DE19691945752 patent/DE1945752B1/de active Pending
-
1970
- 1970-08-11 ES ES382650A patent/ES382650A1/es not_active Expired
- 1970-08-20 NL NL7012339A patent/NL7012339A/xx unknown
- 1970-09-01 ZA ZA705992A patent/ZA705992B/xx unknown
- 1970-09-02 CS CS601970A patent/CS157110B2/cs unknown
- 1970-09-02 US US00069153A patent/US3742061A/en not_active Expired - Lifetime
- 1970-09-03 GB GB4219670A patent/GB1319124A/en not_active Expired
- 1970-09-08 AU AU19648/70A patent/AU1964870A/en not_active Expired
- 1970-09-10 SE SE12337/70A patent/SE356496B/xx unknown
- 1970-09-10 CA CA092,793A patent/CA956785A/en not_active Expired
- 1970-09-10 FR FR7032946A patent/FR2061269A5/fr not_active Expired
- 1970-09-10 AT AT823170A patent/AT314472B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA956785A (en) | 1974-10-29 |
| SE356496B (enExample) | 1973-05-28 |
| ZA705992B (en) | 1971-09-29 |
| NL7012339A (enExample) | 1971-03-12 |
| FR2061269A5 (enExample) | 1971-06-18 |
| AT314472B (de) | 1974-04-10 |
| GB1319124A (en) | 1973-06-06 |
| US3742061A (en) | 1973-06-26 |
| BE756013A (fr) | 1971-02-15 |
| ES382650A1 (es) | 1972-11-01 |
| AU1964870A (en) | 1972-03-09 |
| CS157110B2 (enExample) | 1974-08-23 |
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