DE1495933A1 - Verfahren zur Herstellung von Polymerisationskatalysatoren - Google Patents
Verfahren zur Herstellung von PolymerisationskatalysatorenInfo
- Publication number
- DE1495933A1 DE1495933A1 DE19631495933 DE1495933A DE1495933A1 DE 1495933 A1 DE1495933 A1 DE 1495933A1 DE 19631495933 DE19631495933 DE 19631495933 DE 1495933 A DE1495933 A DE 1495933A DE 1495933 A1 DE1495933 A1 DE 1495933A1
- Authority
- DE
- Germany
- Prior art keywords
- aluminum
- catalyst
- catalysts
- polymerization
- titanium tetrachloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 31
- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000002685 polymerization catalyst Substances 0.000 title description 3
- 239000003054 catalyst Substances 0.000 claims description 87
- 229910052782 aluminium Inorganic materials 0.000 claims description 55
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 44
- 238000006116 polymerization reaction Methods 0.000 claims description 44
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 28
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 27
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000010936 titanium Substances 0.000 claims description 18
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 150000001993 dienes Chemical class 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 18
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 6
- 239000003701 inert diluent Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- -1 Anisole ethers Chemical class 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical group C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22014562A | 1962-08-29 | 1962-08-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1495933A1 true DE1495933A1 (de) | 1970-03-05 |
Family
ID=22822252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19631495933 Pending DE1495933A1 (de) | 1962-08-29 | 1963-08-29 | Verfahren zur Herstellung von Polymerisationskatalysatoren |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE636493A (enExample) |
| DE (1) | DE1495933A1 (enExample) |
| GB (1) | GB1023853A (enExample) |
| NL (1) | NL297285A (enExample) |
-
0
- NL NL297285D patent/NL297285A/xx unknown
- BE BE636493D patent/BE636493A/xx unknown
-
1963
- 1963-07-24 GB GB2927863A patent/GB1023853A/en not_active Expired
- 1963-08-29 DE DE19631495933 patent/DE1495933A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL297285A (enExample) | |
| GB1023853A (en) | 1966-03-30 |
| BE636493A (enExample) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE973626C (de) | Verfahren zur Herstellung von hochmolekularen Polyaethylenen | |
| DE2421934C2 (de) | Verfahren zur Hydrierung von ungesättigten Verbindungen | |
| DE1223559B (de) | Verfahren zur Herstellung von cis-1, 4-Polyisopren | |
| DE2027905B2 (de) | Verfahren zur herstellung von polyalkenameren | |
| DE2830080A1 (de) | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien | |
| DE2626097A1 (de) | Katalysatorkomponenten fuer die olefinpolymerisation, ihre herstellung und verwendung | |
| DE2509577C2 (de) | Ringöffnungspolymerisation von Cyclopenten | |
| DE2936653C2 (de) | Verfahren zur Polymerisation von 1,3-Butadien bzw. zu dessen Copolymerisation mit Isopren und/oder Styrol | |
| DE2028935B2 (de) | Polyalkenamere und Verfahren zu deren Herstellung | |
| DE69207524T2 (de) | Verbessertes Verfahren zur selektiven Hydrierung von Polymeren von konjugierten Diolefinen | |
| DE2105161C3 (de) | Verfahren zur Herstellung von flussigen Polybutenameren | |
| DE1620927A1 (de) | Verfahren zur Herstellung von hohem cis-1,4-Polybutadien | |
| EP0358763A1 (de) | Verfahren zur herstellung von buten-1 | |
| DE2053484A1 (de) | Verfahren zur Herstellung von flussi gem Polybutadien | |
| DE2122956A1 (de) | Verfahren zur Herstellung von flüssigen Butadienpolymerisaten | |
| DE2619488A1 (de) | Verfahren zur polymerisation von butadien | |
| DE1945358B2 (de) | Niedermolekulare Polyalkenamere und Verfahren zu deren Herstellung | |
| DE2534742A1 (de) | Verfahren zur selektiven hydrierung von cyclopentadien | |
| DE2642270C2 (de) | Verfahren zur Herstellung von Äthylvanadat | |
| DE1226307B (de) | Verfahren zur Herstellung von 1,4-cis-Polydienen | |
| DE1097982B (de) | Verfahren zur Herstellung von fluessigen Oligomeren aus 1, 3-Dienen | |
| DE1495933A1 (de) | Verfahren zur Herstellung von Polymerisationskatalysatoren | |
| DE1302599B (de) | Verfahren zur Polymerisation von 2-alkylsubstituierten Diolefinen | |
| DE2154635A1 (de) | Katalysatorsystem für die Polymerisation von ungesättigten Verbindungen, Verfahren unter Anwendung des Katalysatorsystems und Produkte, welche nach dem Verfahren erhalten werden | |
| EP0041157A2 (de) | Verfahren zur Homo- und Mischpolymerisation von alpha-Olefinen |