DE1281399B - Verfahren zum Entfernen von Schwefelwasserstoff und organischen Schwefelverbindungen aus Gasen und Daempfen - Google Patents
Verfahren zum Entfernen von Schwefelwasserstoff und organischen Schwefelverbindungen aus Gasen und DaempfenInfo
- Publication number
- DE1281399B DE1281399B DE1959U0005927 DEU0005927A DE1281399B DE 1281399 B DE1281399 B DE 1281399B DE 1959U0005927 DE1959U0005927 DE 1959U0005927 DE U0005927 A DEU0005927 A DE U0005927A DE 1281399 B DE1281399 B DE 1281399B
- Authority
- DE
- Germany
- Prior art keywords
- reaction
- gas
- reaction mass
- regeneration
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007789 gas Substances 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 24
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 9
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 8
- 150000002898 organic sulfur compounds Chemical class 0.000 title claims description 5
- 239000003517 fume Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 44
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052717 sulfur Inorganic materials 0.000 claims description 18
- 239000011593 sulfur Substances 0.000 claims description 18
- 230000008929 regeneration Effects 0.000 claims description 12
- 238000011069 regeneration method Methods 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000571 coke Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 230000005484 gravity Effects 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
- B01D53/12—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents according to the "fluidised technique"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/523—Mixtures of hydrogen sulfide and sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
- B01J8/28—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
- C10K1/30—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses with moving purifying masses
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB253558A GB902138A (en) | 1958-01-24 | 1958-01-24 | Improvements relating to the removal of hydrogen sulphide from industrial gases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1281399B true DE1281399B (de) | 1968-10-24 |
Family
ID=9741278
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1959U0005927 Pending DE1281399B (de) | 1958-01-24 | 1959-01-22 | Verfahren zum Entfernen von Schwefelwasserstoff und organischen Schwefelverbindungen aus Gasen und Daempfen |
| DE19591444974 Pending DE1444974A1 (de) | 1958-01-24 | 1959-01-22 | Verfahren und Vorrichtung zur Gasentschwefelung |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19591444974 Pending DE1444974A1 (de) | 1958-01-24 | 1959-01-22 | Verfahren und Vorrichtung zur Gasentschwefelung |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE575040A (enrdf_load_stackoverflow) |
| CA (2) | CA599620A (enrdf_load_stackoverflow) |
| DE (2) | DE1281399B (enrdf_load_stackoverflow) |
| FR (1) | FR1222802A (enrdf_load_stackoverflow) |
| GB (2) | GB902138A (enrdf_load_stackoverflow) |
| IT (1) | IT602573A (enrdf_load_stackoverflow) |
| LU (1) | LU36790A1 (enrdf_load_stackoverflow) |
| NL (2) | NL235378A (enrdf_load_stackoverflow) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4180549A (en) * | 1976-08-27 | 1979-12-25 | United States Steel Corporation | Desulfurization of hot reducing gas |
| US4164544A (en) * | 1976-08-27 | 1979-08-14 | United States Steel Corporation | Desulfurization of hot reducing gas |
| US4273749A (en) * | 1977-06-03 | 1981-06-16 | Hitachi, Ltd. | Refining process of hot gas containing hydrogen sulfide and ammonia |
| US4230603A (en) * | 1979-04-02 | 1980-10-28 | United States Steel Corporation | Desulfurizing pellet of manganese oxide and aluminum oxide and process for producing said pellet |
| PL2078555T3 (pl) * | 2008-01-11 | 2014-01-31 | Hitachi Zosen Inova Ag | Sposób i instalacja do oczyszczania gazów spalinowych |
| CN113522011B (zh) * | 2020-04-14 | 2023-09-05 | 中国石油化工股份有限公司 | 脱硫化氢的方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE442514C (de) * | 1925-01-03 | 1927-04-02 | Emil Raffloer | Verfahren zur Entschwefelung von Gasen |
| DE453378C (de) * | 1927-12-05 | Emil Raffloer | Verfahren zur Entschwefelung von Gasen | |
| DE561899C (de) * | 1927-11-12 | 1932-10-19 | Metallgesellschaft Ag | Verfahren und Vorrichtung zur Ausfuehrung von Reaktionen zwischen verschiedenartigenGasen oder Daempfen und einem fein verteilten festen Stoff |
| GB719056A (en) * | 1950-10-24 | 1954-11-24 | United Steel Companies Ltd | Improvements relating to the removal of hydrogen sulphide from industrial gases |
-
0
- CA CA599621A patent/CA599621A/en not_active Expired
- NL NL235377D patent/NL235377A/xx unknown
- CA CA599620A patent/CA599620A/en not_active Expired
- BE BE575040D patent/BE575040A/xx unknown
- IT IT602573D patent/IT602573A/it unknown
- NL NL235378D patent/NL235378A/xx unknown
- LU LU36790D patent/LU36790A1/xx unknown
-
1958
- 1958-01-24 GB GB253558A patent/GB902138A/en not_active Expired
-
1959
- 1959-01-22 DE DE1959U0005927 patent/DE1281399B/de active Pending
- 1959-01-22 DE DE19591444974 patent/DE1444974A1/de active Pending
- 1959-01-23 GB GB1984561A patent/GB902140A/en not_active Expired
- 1959-01-24 FR FR784905A patent/FR1222802A/fr not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE453378C (de) * | 1927-12-05 | Emil Raffloer | Verfahren zur Entschwefelung von Gasen | |
| DE442514C (de) * | 1925-01-03 | 1927-04-02 | Emil Raffloer | Verfahren zur Entschwefelung von Gasen |
| DE561899C (de) * | 1927-11-12 | 1932-10-19 | Metallgesellschaft Ag | Verfahren und Vorrichtung zur Ausfuehrung von Reaktionen zwischen verschiedenartigenGasen oder Daempfen und einem fein verteilten festen Stoff |
| GB719056A (en) * | 1950-10-24 | 1954-11-24 | United Steel Companies Ltd | Improvements relating to the removal of hydrogen sulphide from industrial gases |
Also Published As
| Publication number | Publication date |
|---|---|
| CA599621A (en) | 1960-06-07 |
| NL235378A (enrdf_load_stackoverflow) | |
| GB902138A (en) | 1962-07-25 |
| NL235377A (enrdf_load_stackoverflow) | |
| BE575040A (enrdf_load_stackoverflow) | |
| DE1444974A1 (de) | 1969-01-30 |
| LU36790A1 (enrdf_load_stackoverflow) | |
| FR1222802A (fr) | 1960-06-13 |
| CA599620A (en) | 1960-06-07 |
| IT602573A (enrdf_load_stackoverflow) | |
| GB902140A (en) | 1962-07-25 |
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