DE1278145B - Analytischer Nachweis des Vanadiums in Erdoel und Verfahren zur Steuerung von Erdoelraffinationsprozessen in Abhaengigkeit von AEnderungen des Vanadiumgehaltes eines Erdoelstromes - Google Patents
Analytischer Nachweis des Vanadiums in Erdoel und Verfahren zur Steuerung von Erdoelraffinationsprozessen in Abhaengigkeit von AEnderungen des Vanadiumgehaltes eines ErdoelstromesInfo
- Publication number
- DE1278145B DE1278145B DEG32489A DEG0032489A DE1278145B DE 1278145 B DE1278145 B DE 1278145B DE G32489 A DEG32489 A DE G32489A DE G0032489 A DEG0032489 A DE G0032489A DE 1278145 B DE1278145 B DE 1278145B
- Authority
- DE
- Germany
- Prior art keywords
- vanadium
- oil
- petroleum
- intensity
- examined
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052720 vanadium Inorganic materials 0.000 title claims description 93
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims description 92
- 238000000034 method Methods 0.000 title claims description 46
- 239000003208 petroleum Substances 0.000 title claims description 21
- 230000008569 process Effects 0.000 title claims description 21
- 238000005504 petroleum refining Methods 0.000 title claims description 9
- 238000001514 detection method Methods 0.000 title claims description 4
- 230000005298 paramagnetic effect Effects 0.000 claims description 38
- 238000004458 analytical method Methods 0.000 claims description 31
- 238000004611 spectroscopical analysis Methods 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000013074 reference sample Substances 0.000 claims description 7
- 238000007670 refining Methods 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 238000003776 cleavage reaction Methods 0.000 claims description 3
- 230000007017 scission Effects 0.000 claims description 3
- 239000003209 petroleum derivative Substances 0.000 claims description 2
- 230000002411 adverse Effects 0.000 claims 1
- 238000002094 microwave spectroscopy Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 description 109
- 239000000523 sample Substances 0.000 description 27
- 239000007789 gas Substances 0.000 description 18
- 230000005291 magnetic effect Effects 0.000 description 18
- 239000010779 crude oil Substances 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000011088 calibration curve Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000009795 derivation Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 210000000617 arm Anatomy 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- -1 porphyrin compounds Chemical class 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000003197 Byrsonima crassifolia Nutrition 0.000 description 1
- 240000001546 Byrsonima crassifolia Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000004435 EPR spectroscopy Methods 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- OIRDTQYFTABQOQ-UHTZMRCNSA-N Vidarabine Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](CO)[C@@H](O)[C@@H]1O OIRDTQYFTABQOQ-UHTZMRCNSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000010724 circulating oil Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000002265 electronic spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000005287 vanadyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/10—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with stationary catalyst bed
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Specific substances contained in the oils or fuels
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R33/00—Arrangements or instruments for measuring magnetic variables
- G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
- G01R33/60—Arrangements or instruments for measuring magnetic variables involving magnetic resonance using electron paramagnetic resonance
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Food Science & Technology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36381A US3087888A (en) | 1960-06-15 | 1960-06-15 | Determination of vanadium content of hydrocarbon oils by electron paramagnetic resonance spectrometry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1278145B true DE1278145B (de) | 1968-09-19 |
Family
ID=21888299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEG32489A Pending DE1278145B (de) | 1960-06-15 | 1961-06-14 | Analytischer Nachweis des Vanadiums in Erdoel und Verfahren zur Steuerung von Erdoelraffinationsprozessen in Abhaengigkeit von AEnderungen des Vanadiumgehaltes eines Erdoelstromes |
Country Status (6)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3348136A (en) * | 1962-05-31 | 1967-10-17 | Varian Associates | Gyromagnetic resonance apparatus utilizing two-sample signal comparison |
| US3498112A (en) * | 1968-04-30 | 1970-03-03 | Us Navy | Microwave system for determining water content in fuel oil |
| US3719453A (en) * | 1970-11-25 | 1973-03-06 | Phillips Petroleum Co | Detection of reducing conditions in a formation as in oil prospecting |
| US4822475A (en) * | 1988-03-08 | 1989-04-18 | Betz Laboratories, Inc. | Method for determining the fouling tendency of crude petroleum oils |
| US5169785A (en) * | 1990-10-26 | 1992-12-08 | Mobil Oil Corporation | Method for detecting fuel dilution of marine lubricating oils |
| US5233303A (en) * | 1991-05-23 | 1993-08-03 | Barney Bales | Portable dedicated electron spin resonance spectrometer |
| US9476847B2 (en) * | 2006-10-03 | 2016-10-25 | Invensys Systems, Inc. | Spectroscopic crude oil analysis |
| US7768260B2 (en) * | 2007-02-23 | 2010-08-03 | Baker Hughes Incorporated | Methods for identification and quantification of multicomponent-fluid and estimating fluid gas/ oil ratio from NMR logs |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE546564A (US07223432-20070529-C00017.png) * | 1955-04-02 | |||
| US2909482A (en) * | 1957-11-14 | 1959-10-20 | Exxon Research Engineering Co | Determination of asphaltic components of petroleum |
| US2999381A (en) * | 1958-04-23 | 1961-09-12 | Industrial Nucleonics Corp | Nuclear magnetic resonance measuring system |
| US2925374A (en) * | 1958-05-19 | 1960-02-16 | Exxon Research Engineering Co | Hydrocarbon treating process |
| US2926129A (en) * | 1958-06-13 | 1960-02-23 | Exxon Research Engineering Co | Deashing of residual fractions |
| US2966454A (en) * | 1959-04-03 | 1960-12-27 | Esso Rescarch And Engineering | Removal of nickel and vanadium from residual stocks |
| US2955252A (en) * | 1959-04-16 | 1960-10-04 | Exxon Research Engineering Co | Combination analyzer-sampler |
-
0
- NL NL265991D patent/NL265991A/xx unknown
- BE BE604997D patent/BE604997A/xx unknown
- NL NL126160D patent/NL126160C/xx active
- US US26312D patent/USRE26312E/en not_active Expired
-
1960
- 1960-06-15 US US36381A patent/US3087888A/en not_active Expired - Lifetime
-
1961
- 1961-06-14 DK DK243661AA patent/DK114992B/da unknown
- 1961-06-14 GB GB21415/61A patent/GB949412A/en not_active Expired
- 1961-06-14 DE DEG32489A patent/DE1278145B/de active Pending
Non-Patent Citations (1)
| Title |
|---|
| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| NL265991A (US07223432-20070529-C00017.png) | |
| USRE26312E (en) | 1967-11-28 |
| US3087888A (en) | 1963-04-30 |
| GB949412A (en) | 1964-02-12 |
| BE604997A (US07223432-20070529-C00017.png) | |
| NL126160C (US07223432-20070529-C00017.png) | |
| DK114992B (da) | 1969-08-25 |
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