DE1275235B - Verfahren zur Herstellung von Mitteldestillaten durch hydrierende Spaltung von Kohlenwasserstoffoelen - Google Patents
Verfahren zur Herstellung von Mitteldestillaten durch hydrierende Spaltung von KohlenwasserstoffoelenInfo
- Publication number
- DE1275235B DE1275235B DES103132A DES0103132A DE1275235B DE 1275235 B DE1275235 B DE 1275235B DE S103132 A DES103132 A DE S103132A DE S0103132 A DES0103132 A DE S0103132A DE 1275235 B DE1275235 B DE 1275235B
- Authority
- DE
- Germany
- Prior art keywords
- weight
- catalyst
- percent
- tungsten
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003921 oil Substances 0.000 title claims description 49
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 32
- 229930195733 hydrocarbon Natural products 0.000 title claims description 31
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 20
- 238000003776 cleavage reaction Methods 0.000 title claims description 18
- 230000007017 scission Effects 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003054 catalyst Substances 0.000 claims description 106
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 72
- 238000009835 boiling Methods 0.000 claims description 42
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 27
- 229910052731 fluorine Inorganic materials 0.000 claims description 27
- 239000011737 fluorine Substances 0.000 claims description 27
- 229910052759 nickel Inorganic materials 0.000 claims description 27
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 26
- 229910052721 tungsten Inorganic materials 0.000 claims description 26
- 239000010937 tungsten Substances 0.000 claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 15
- 239000007858 starting material Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000012876 carrier material Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 description 43
- 238000002474 experimental method Methods 0.000 description 24
- 230000000694 effects Effects 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 17
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 15
- 239000012263 liquid product Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 8
- 238000011282 treatment Methods 0.000 description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000012261 resinous substance Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005486 sulfidation Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical group [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 150000003657 tungsten Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/08—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL656504682A NL144656B (nl) | 1965-04-13 | 1965-04-13 | Werkwijze voor het hydrokraken van koolwaterstofolien. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1275235B true DE1275235B (de) | 1968-08-14 |
Family
ID=19792918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES103132A Pending DE1275235B (de) | 1965-04-13 | 1966-04-12 | Verfahren zur Herstellung von Mitteldestillaten durch hydrierende Spaltung von Kohlenwasserstoffoelen |
Country Status (10)
| Country | Link |
|---|---|
| BE (1) | BE679382A (OSRAM) |
| CH (1) | CH469803A (OSRAM) |
| DE (1) | DE1275235B (OSRAM) |
| DK (1) | DK121392B (OSRAM) |
| ES (1) | ES325385A1 (OSRAM) |
| FR (1) | FR1475462A (OSRAM) |
| GB (1) | GB1092400A (OSRAM) |
| NL (1) | NL144656B (OSRAM) |
| NO (1) | NO116331B (OSRAM) |
| SE (1) | SE301847B (OSRAM) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1191958A (en) * | 1968-10-08 | 1970-05-13 | Shell Int Research | Three-Stage Hydrocracking Process |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE637762A (OSRAM) * | 1963-09-23 | |||
| DE13369C (de) * | E. LANGEN in Cöln a. Rh | Ununterbrochen wirkende Flüssigkeit-Scheide-Centrifuge mit Schwimmer | ||
| GB928762A (en) * | 1960-01-28 | 1963-06-12 | Gulf Research Development Co | Catalyst composition |
| FR1355210A (fr) * | 1962-04-25 | 1964-03-13 | Gulf Research Development Co | Procédé d'hydrocraquage |
| BE639291A (OSRAM) * | 1962-10-31 | 1964-04-29 | ||
| FR1388593A (fr) * | 1963-04-25 | 1965-02-05 | Gulf Research Development Co | Procédé d'hydrocraquage |
-
1965
- 1965-04-13 NL NL656504682A patent/NL144656B/xx unknown
-
1966
- 1966-04-12 CH CH523766A patent/CH469803A/de unknown
- 1966-04-12 FR FR57298A patent/FR1475462A/fr not_active Expired
- 1966-04-12 SE SE4960/66A patent/SE301847B/xx unknown
- 1966-04-12 BE BE679382D patent/BE679382A/xx unknown
- 1966-04-12 DK DK186266AA patent/DK121392B/da unknown
- 1966-04-12 NO NO162532A patent/NO116331B/no unknown
- 1966-04-12 GB GB15994/66A patent/GB1092400A/en not_active Expired
- 1966-04-12 DE DES103132A patent/DE1275235B/de active Pending
- 1966-04-12 ES ES0325385A patent/ES325385A1/es not_active Expired
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE13369C (de) * | E. LANGEN in Cöln a. Rh | Ununterbrochen wirkende Flüssigkeit-Scheide-Centrifuge mit Schwimmer | ||
| GB928762A (en) * | 1960-01-28 | 1963-06-12 | Gulf Research Development Co | Catalyst composition |
| FR1355210A (fr) * | 1962-04-25 | 1964-03-13 | Gulf Research Development Co | Procédé d'hydrocraquage |
| BE639291A (OSRAM) * | 1962-10-31 | 1964-04-29 | ||
| FR1388593A (fr) * | 1963-04-25 | 1965-02-05 | Gulf Research Development Co | Procédé d'hydrocraquage |
| BE637762A (OSRAM) * | 1963-09-23 |
Also Published As
| Publication number | Publication date |
|---|---|
| NL144656B (nl) | 1975-01-15 |
| GB1092400A (en) | 1967-11-22 |
| ES325385A1 (es) | 1967-05-01 |
| NL6504682A (OSRAM) | 1966-10-14 |
| DK121392B (da) | 1971-10-11 |
| BE679382A (OSRAM) | 1966-10-12 |
| NO116331B (OSRAM) | 1969-03-10 |
| CH469803A (de) | 1969-03-15 |
| SE301847B (OSRAM) | 1968-06-24 |
| FR1475462A (fr) | 1967-03-31 |
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