DE1240652B - Verfahren zur Herstellung von mit Kieselsaeure verstaerkten Kautschukvulkanisaten - Google Patents
Verfahren zur Herstellung von mit Kieselsaeure verstaerkten KautschukvulkanisatenInfo
- Publication number
- DE1240652B DE1240652B DE1960D0034944 DED0034944A DE1240652B DE 1240652 B DE1240652 B DE 1240652B DE 1960D0034944 DE1960D0034944 DE 1960D0034944 DE D0034944 A DED0034944 A DE D0034944A DE 1240652 B DE1240652 B DE 1240652B
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- silica
- weight
- mixture
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 38
- 229920001971 elastomer Polymers 0.000 title claims description 22
- 239000005060 rubber Substances 0.000 title claims description 22
- 239000000377 silicon dioxide Substances 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims description 28
- 229920000126 latex Polymers 0.000 claims description 15
- 239000004816 latex Substances 0.000 claims description 10
- 238000001556 precipitation Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004438 BET method Methods 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 230000001112 coagulating effect Effects 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000000945 filler Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 6
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000005018 casein Substances 0.000 description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 3
- 235000021240 caseins Nutrition 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 2
- OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
- JFISFZKKYWLPPP-UHFFFAOYSA-N 4-sulfanyl-3h-1,3-benzothiazole-2-thione Chemical compound C1=CC=C2SC(S)=NC2=C1S JFISFZKKYWLPPP-UHFFFAOYSA-N 0.000 description 1
- 239000006145 Eagle's minimal essential medium Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Compounds (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE611512D BE611512A (en, 2012) | 1960-12-14 | ||
| NL272499D NL272499A (en, 2012) | 1960-12-14 | ||
| DE1960D0034944 DE1240652B (de) | 1960-12-14 | 1960-12-14 | Verfahren zur Herstellung von mit Kieselsaeure verstaerkten Kautschukvulkanisaten |
| GB4444961A GB1004149A (en) | 1960-12-14 | 1961-12-12 | Vulcanisable mixtures of natural or synthetic rubber or rubber-like elastomers and precipitated silica fillers for use therein |
| FR882026A FR1314596A (fr) | 1960-12-14 | 1961-12-14 | Mélanges vulcanisables de caoutchouc naturel ou synthétique, ou d'élastomères semblables au caoutchouc, et de charge en silice précipitée, ainsi que procédés pourleur préparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1960D0034944 DE1240652B (de) | 1960-12-14 | 1960-12-14 | Verfahren zur Herstellung von mit Kieselsaeure verstaerkten Kautschukvulkanisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1240652B true DE1240652B (de) | 1967-05-18 |
Family
ID=7042425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1960D0034944 Pending DE1240652B (de) | 1960-12-14 | 1960-12-14 | Verfahren zur Herstellung von mit Kieselsaeure verstaerkten Kautschukvulkanisaten |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE611512A (en, 2012) |
| DE (1) | DE1240652B (en, 2012) |
| GB (1) | GB1004149A (en, 2012) |
| NL (1) | NL272499A (en, 2012) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4722954A (en) * | 1985-02-14 | 1988-02-02 | Gerald Hallworth | Formation of solid polymeric material comprising a latex and a filler mixture of silica and xanthan gum |
| US4978402A (en) * | 1987-11-06 | 1990-12-18 | The Dow Chemical Company | Formation of flexible laminates by bonding a backing to a pre-coated substrate |
| US5022948A (en) * | 1988-06-16 | 1991-06-11 | The Dow Chemical Company | Method of bonding layers using discrete areas of adhesive |
| US6409822B1 (en) * | 1996-03-15 | 2002-06-25 | Rhodia Chimie | Aqueous suspension including a mixture of at least one aqueous suspension of precipitated silica and of at least one latex |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2497464A (en) * | 1947-04-19 | 1950-02-14 | Us Rubber Co | Incorporation of clay filler into synthetic rubber |
| FR1064230A (fr) * | 1951-10-09 | 1954-05-12 | Columbia Southern Chem Corp | Perfectionnements aux procédés pour la préparation de silice pagmentaire finementdivisée |
| US2964490A (en) * | 1957-03-12 | 1960-12-13 | Us Rubber Co | Butadiene copolymer rubber-silica masterbatch and process of preparation |
-
0
- NL NL272499D patent/NL272499A/xx unknown
- BE BE611512D patent/BE611512A/xx unknown
-
1960
- 1960-12-14 DE DE1960D0034944 patent/DE1240652B/de active Pending
-
1961
- 1961-12-12 GB GB4444961A patent/GB1004149A/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2497464A (en) * | 1947-04-19 | 1950-02-14 | Us Rubber Co | Incorporation of clay filler into synthetic rubber |
| FR1064230A (fr) * | 1951-10-09 | 1954-05-12 | Columbia Southern Chem Corp | Perfectionnements aux procédés pour la préparation de silice pagmentaire finementdivisée |
| US2964490A (en) * | 1957-03-12 | 1960-12-13 | Us Rubber Co | Butadiene copolymer rubber-silica masterbatch and process of preparation |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4722954A (en) * | 1985-02-14 | 1988-02-02 | Gerald Hallworth | Formation of solid polymeric material comprising a latex and a filler mixture of silica and xanthan gum |
| US4781781A (en) * | 1985-02-14 | 1988-11-01 | Gerald Hallworth | Formation of solid polymeric material |
| US4978402A (en) * | 1987-11-06 | 1990-12-18 | The Dow Chemical Company | Formation of flexible laminates by bonding a backing to a pre-coated substrate |
| US5022948A (en) * | 1988-06-16 | 1991-06-11 | The Dow Chemical Company | Method of bonding layers using discrete areas of adhesive |
| US6409822B1 (en) * | 1996-03-15 | 2002-06-25 | Rhodia Chimie | Aqueous suspension including a mixture of at least one aqueous suspension of precipitated silica and of at least one latex |
| US6602935B2 (en) | 1996-03-15 | 2003-08-05 | Rhodia Chimie | Aqueous silica suspensions and their applications in compositions based on inorganic binder |
Also Published As
| Publication number | Publication date |
|---|---|
| NL272499A (en, 2012) | |
| BE611512A (en, 2012) | |
| GB1004149A (en) | 1965-09-08 |
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