DE112006001733T5 - Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln - Google Patents
Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln Download PDFInfo
- Publication number
- DE112006001733T5 DE112006001733T5 DE112006001733T DE112006001733T DE112006001733T5 DE 112006001733 T5 DE112006001733 T5 DE 112006001733T5 DE 112006001733 T DE112006001733 T DE 112006001733T DE 112006001733 T DE112006001733 T DE 112006001733T DE 112006001733 T5 DE112006001733 T5 DE 112006001733T5
- Authority
- DE
- Germany
- Prior art keywords
- aluminoxanate
- carbon atoms
- composition according
- soluble
- twenty carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 226
- 150000003839 salts Chemical class 0.000 title claims abstract description 91
- 239000002904 solvent Substances 0.000 title claims description 39
- 125000001931 aliphatic group Chemical group 0.000 title claims description 18
- 125000003118 aryl group Chemical group 0.000 title description 12
- -1 alkylaluminum compound Chemical class 0.000 claims abstract description 128
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 60
- 239000003446 ligand Substances 0.000 claims abstract description 42
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 35
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 35
- 150000004820 halides Chemical class 0.000 claims abstract description 31
- 125000002577 pseudohalo group Chemical group 0.000 claims abstract description 25
- 239000003960 organic solvent Substances 0.000 claims abstract description 22
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 17
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 107
- 239000003054 catalyst Substances 0.000 claims description 98
- 239000007788 liquid Substances 0.000 claims description 59
- 150000003624 transition metals Chemical group 0.000 claims description 47
- 229910052723 transition metal Inorganic materials 0.000 claims description 45
- 238000006116 polymerization reaction Methods 0.000 claims description 35
- 239000003849 aromatic solvent Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 23
- 239000012876 carrier material Substances 0.000 claims description 22
- 238000002360 preparation method Methods 0.000 claims description 21
- 239000000178 monomer Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 125000004429 atom Chemical group 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 230000000737 periodic effect Effects 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 10
- 150000002602 lanthanoids Chemical class 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052768 actinide Inorganic materials 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 150000001255 actinides Chemical class 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229910052570 clay Inorganic materials 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920006295 polythiol Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052622 kaolinite Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 150000004673 fluoride salts Chemical group 0.000 claims 1
- 229910052900 illite Inorganic materials 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 135
- 239000007787 solid Substances 0.000 description 56
- NZQQFMVULBBDSP-FPLPWBNLSA-N bis(4-methylpentan-2-yl) (z)-but-2-enedioate Chemical compound CC(C)CC(C)OC(=O)\C=C/C(=O)OC(C)CC(C)C NZQQFMVULBBDSP-FPLPWBNLSA-N 0.000 description 47
- 238000001228 spectrum Methods 0.000 description 44
- 239000010936 titanium Substances 0.000 description 44
- 239000000243 solution Substances 0.000 description 40
- 150000001875 compounds Chemical class 0.000 description 29
- 229910052751 metal Inorganic materials 0.000 description 23
- 239000002184 metal Substances 0.000 description 23
- 238000005481 NMR spectroscopy Methods 0.000 description 21
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- 150000003623 transition metal compounds Chemical class 0.000 description 20
- 239000012190 activator Substances 0.000 description 18
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 17
- 229930195733 hydrocarbon Natural products 0.000 description 17
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 15
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 15
- 239000012071 phase Substances 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 12
- 241000894007 species Species 0.000 description 12
- 229910052719 titanium Inorganic materials 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- ZMZGFLUUZLELNE-UHFFFAOYSA-N 2,3,5-triiodobenzoic acid Chemical compound OC(=O)C1=CC(I)=CC(I)=C1I ZMZGFLUUZLELNE-UHFFFAOYSA-N 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- 229910007926 ZrCl Inorganic materials 0.000 description 9
- 125000005234 alkyl aluminium group Chemical group 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 8
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 8
- 150000002902 organometallic compounds Chemical class 0.000 description 8
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 7
- 241001191009 Gymnomyza Species 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 7
- ORVACBDINATSAR-UHFFFAOYSA-N dimethylaluminum Chemical compound C[Al]C ORVACBDINATSAR-UHFFFAOYSA-N 0.000 description 7
- 238000001879 gelation Methods 0.000 description 7
- 238000007745 plasma electrolytic oxidation reaction Methods 0.000 description 7
- 230000000379 polymerizing effect Effects 0.000 description 7
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000002051 biphasic effect Effects 0.000 description 6
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- YMWUJEATGCHHMB-MICDWDOJSA-N dichloro(deuterio)methane Chemical compound [2H]C(Cl)Cl YMWUJEATGCHHMB-MICDWDOJSA-N 0.000 description 5
- 229910052735 hafnium Inorganic materials 0.000 description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 5
- 125000004430 oxygen atom Chemical group O* 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000005191 phase separation Methods 0.000 description 5
- 230000037048 polymerization activity Effects 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- GJEONJVNTMLKMR-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].[Hf+3] Chemical compound [Cl-].[Cl-].[Cl-].[Hf+3] GJEONJVNTMLKMR-UHFFFAOYSA-K 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 4
- 125000004104 aryloxy group Chemical group 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 4
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 4
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 4
- XEZNGIUYQVAUSS-UHFFFAOYSA-N 18-crown-6 Chemical compound C1COCCOCCOCCOCCOCCO1 XEZNGIUYQVAUSS-UHFFFAOYSA-N 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000002102 aryl alkyloxo group Chemical group 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 125000000000 cycloalkoxy group Chemical group 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 3
- 150000004677 hydrates Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000012488 sample solution Substances 0.000 description 3
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- MBWMIEZHOLGJBM-UHFFFAOYSA-N 3-(4-methylphenyl)-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid Chemical compound CC1=CC=C(C(CC(O)=O)NC(=O)OC(C)(C)C)C=C1 MBWMIEZHOLGJBM-UHFFFAOYSA-N 0.000 description 2
- WSWMGHRLUYADNA-UHFFFAOYSA-N 7-nitro-1,2,3,4-tetrahydroquinoline Chemical compound C1CCNC2=CC([N+](=O)[O-])=CC=C21 WSWMGHRLUYADNA-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- QDZGLKRYQGDOFS-UHFFFAOYSA-N C1=CCCCCC([Ni]C=2CCCCC=CC=2)=C1 Chemical compound C1=CCCCCC([Ni]C=2CCCCC=CC=2)=C1 QDZGLKRYQGDOFS-UHFFFAOYSA-N 0.000 description 2
- 229910004664 Cerium(III) chloride Inorganic materials 0.000 description 2
- 229910021559 Chromium(II) bromide Inorganic materials 0.000 description 2
- 229910021562 Chromium(II) fluoride Inorganic materials 0.000 description 2
- 229910021560 Chromium(III) bromide Inorganic materials 0.000 description 2
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 2
- 229910021564 Chromium(III) fluoride Inorganic materials 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- 101100285402 Danio rerio eng1a gene Proteins 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 2
- 229910021549 Vanadium(II) chloride Inorganic materials 0.000 description 2
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 2
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- QUGHSZRQAPBODA-UHFFFAOYSA-K [Br-].[Br-].[Br-].[Hf+3] Chemical compound [Br-].[Br-].[Br-].[Hf+3] QUGHSZRQAPBODA-UHFFFAOYSA-K 0.000 description 2
- RPBTVVXHHNXNDO-UHFFFAOYSA-L [Cl-].[Cl-].CC1(C=CC=C1)[Hf+2] Chemical compound [Cl-].[Cl-].CC1(C=CC=C1)[Hf+2] RPBTVVXHHNXNDO-UHFFFAOYSA-L 0.000 description 2
- VAFXHNPAMHBKMS-UHFFFAOYSA-K [I-].[I-].[I-].[Hf+3] Chemical compound [I-].[I-].[I-].[Hf+3] VAFXHNPAMHBKMS-UHFFFAOYSA-K 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 150000001540 azides Chemical class 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 description 2
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 description 2
- ZEDZJUDTPVFRNB-UHFFFAOYSA-K cerium(3+);triiodide Chemical class I[Ce](I)I ZEDZJUDTPVFRNB-UHFFFAOYSA-K 0.000 description 2
- MOOUSOJAOQPDEH-UHFFFAOYSA-K cerium(iii) bromide Chemical class [Br-].[Br-].[Br-].[Ce+3] MOOUSOJAOQPDEH-UHFFFAOYSA-K 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 2
- 239000011636 chromium(III) chloride Substances 0.000 description 2
- 235000007831 chromium(III) chloride Nutrition 0.000 description 2
- XZQOHYZUWTWZBL-UHFFFAOYSA-L chromium(ii) bromide Chemical compound [Cr+2].[Br-].[Br-] XZQOHYZUWTWZBL-UHFFFAOYSA-L 0.000 description 2
- XBWRJSSJWDOUSJ-UHFFFAOYSA-L chromium(ii) chloride Chemical compound Cl[Cr]Cl XBWRJSSJWDOUSJ-UHFFFAOYSA-L 0.000 description 2
- RNFYGEKNFJULJY-UHFFFAOYSA-L chromium(ii) fluoride Chemical compound [F-].[F-].[Cr+2] RNFYGEKNFJULJY-UHFFFAOYSA-L 0.000 description 2
- UZDWIWGMKWZEPE-UHFFFAOYSA-K chromium(iii) bromide Chemical compound [Cr+3].[Br-].[Br-].[Br-] UZDWIWGMKWZEPE-UHFFFAOYSA-K 0.000 description 2
- 150000003983 crown ethers Chemical class 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 2
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- GWWKZPLMVIATIO-UHFFFAOYSA-L dibromozirconium Chemical compound Br[Zr]Br GWWKZPLMVIATIO-UHFFFAOYSA-L 0.000 description 2
- XXLOICMXOBKOLH-UHFFFAOYSA-L diiodotitanium Chemical compound I[Ti]I XXLOICMXOBKOLH-UHFFFAOYSA-L 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical class O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 2
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 2
- FEEFWFYISQGDKK-UHFFFAOYSA-J hafnium(4+);tetrabromide Chemical compound Br[Hf](Br)(Br)Br FEEFWFYISQGDKK-UHFFFAOYSA-J 0.000 description 2
- QHEDSQMUHIMDOL-UHFFFAOYSA-J hafnium(4+);tetrafluoride Chemical compound F[Hf](F)(F)F QHEDSQMUHIMDOL-UHFFFAOYSA-J 0.000 description 2
- YCJQNNVSZNFWAH-UHFFFAOYSA-J hafnium(4+);tetraiodide Chemical compound I[Hf](I)(I)I YCJQNNVSZNFWAH-UHFFFAOYSA-J 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000005826 halohydrocarbons Chemical class 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 150000002540 isothiocyanates Chemical class 0.000 description 2
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 description 2
- OYMJNIHGVDEDFX-UHFFFAOYSA-J molybdenum tetrachloride Chemical compound Cl[Mo](Cl)(Cl)Cl OYMJNIHGVDEDFX-UHFFFAOYSA-J 0.000 description 2
- ZSSVQAGPXAAOPV-UHFFFAOYSA-K molybdenum trichloride Chemical compound Cl[Mo](Cl)Cl ZSSVQAGPXAAOPV-UHFFFAOYSA-K 0.000 description 2
- BQBYSLAFGRVJME-UHFFFAOYSA-L molybdenum(2+);dichloride Chemical compound Cl[Mo]Cl BQBYSLAFGRVJME-UHFFFAOYSA-L 0.000 description 2
- GMMJTCLAKDKBCZ-UHFFFAOYSA-L molybdenum(ii) bromide Chemical compound Br[Mo]Br GMMJTCLAKDKBCZ-UHFFFAOYSA-L 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- DSYRJFDOOSKABR-UHFFFAOYSA-I niobium(v) bromide Chemical compound [Br-].[Br-].[Br-].[Br-].[Br-].[Nb+5] DSYRJFDOOSKABR-UHFFFAOYSA-I 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 2
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 2
- NFVUDQKTAWONMJ-UHFFFAOYSA-I pentafluorovanadium Chemical compound [F-].[F-].[F-].[F-].[F-].[V+5] NFVUDQKTAWONMJ-UHFFFAOYSA-I 0.000 description 2
- 125000004437 phosphorous atom Chemical group 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical group [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 2
- ZCBSOTLLNBJIEK-UHFFFAOYSA-N silane titanium Chemical compound [SiH4].[Ti] ZCBSOTLLNBJIEK-UHFFFAOYSA-N 0.000 description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 2
- WWJBJTBTXOHQAZ-UHFFFAOYSA-J tetrabromomolybdenum Chemical compound Br[Mo](Br)(Br)Br WWJBJTBTXOHQAZ-UHFFFAOYSA-J 0.000 description 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
- OMDXFCRSKHYDTM-UHFFFAOYSA-J thorium(4+);tetrabromide Chemical compound Br[Th](Br)(Br)Br OMDXFCRSKHYDTM-UHFFFAOYSA-J 0.000 description 2
- WEQHQGJDZLDFID-UHFFFAOYSA-J thorium(iv) chloride Chemical compound Cl[Th](Cl)(Cl)Cl WEQHQGJDZLDFID-UHFFFAOYSA-J 0.000 description 2
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 2
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 2
- AUZMWGNTACEWDV-UHFFFAOYSA-L titanium(2+);dibromide Chemical compound Br[Ti]Br AUZMWGNTACEWDV-UHFFFAOYSA-L 0.000 description 2
- MTAYDNKNMILFOK-UHFFFAOYSA-K titanium(3+);tribromide Chemical compound Br[Ti](Br)Br MTAYDNKNMILFOK-UHFFFAOYSA-K 0.000 description 2
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 2
- NLPMQGKZYAYAFE-UHFFFAOYSA-K titanium(iii) fluoride Chemical compound F[Ti](F)F NLPMQGKZYAYAFE-UHFFFAOYSA-K 0.000 description 2
- TYEZTGPOVBHTQW-UHFFFAOYSA-K tribromouranium Chemical compound Br[U](Br)Br TYEZTGPOVBHTQW-UHFFFAOYSA-K 0.000 description 2
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 description 2
- HPICRATUQFHULE-UHFFFAOYSA-J uranium(4+);tetrachloride Chemical compound Cl[U](Cl)(Cl)Cl HPICRATUQFHULE-UHFFFAOYSA-J 0.000 description 2
- SAWLVFKYPSYVBL-UHFFFAOYSA-K uranium(iii) chloride Chemical compound Cl[U](Cl)Cl SAWLVFKYPSYVBL-UHFFFAOYSA-K 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 2
- JTWLHYPUICYOLE-UHFFFAOYSA-J vanadium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[V+4] JTWLHYPUICYOLE-UHFFFAOYSA-J 0.000 description 2
- ITAKKORXEUJTBC-UHFFFAOYSA-L vanadium(ii) chloride Chemical compound Cl[V]Cl ITAKKORXEUJTBC-UHFFFAOYSA-L 0.000 description 2
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 2
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 2
- YRDBVAQLYFVSFE-UHFFFAOYSA-K zirconium(3+);tribromide Chemical compound [Br-].[Br-].[Br-].[Zr+3] YRDBVAQLYFVSFE-UHFFFAOYSA-K 0.000 description 2
- PFXYQVJESZAMSV-UHFFFAOYSA-K zirconium(iii) chloride Chemical compound Cl[Zr](Cl)Cl PFXYQVJESZAMSV-UHFFFAOYSA-K 0.000 description 2
- LSWWNKUULMMMIL-UHFFFAOYSA-J zirconium(iv) bromide Chemical compound Br[Zr](Br)(Br)Br LSWWNKUULMMMIL-UHFFFAOYSA-J 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- FSJSYDFBTIVUFD-SUKNRPLKSA-N (z)-4-hydroxypent-3-en-2-one;oxovanadium Chemical compound [V]=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FSJSYDFBTIVUFD-SUKNRPLKSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- VFRGATWKSPNXLT-UHFFFAOYSA-N 1,2-dimethoxybutane Chemical compound CCC(OC)COC VFRGATWKSPNXLT-UHFFFAOYSA-N 0.000 description 1
- LEEANUDEDHYDTG-UHFFFAOYSA-N 1,2-dimethoxypropane Chemical compound COCC(C)OC LEEANUDEDHYDTG-UHFFFAOYSA-N 0.000 description 1
- UUAMLBIYJDPGFU-UHFFFAOYSA-N 1,3-dimethoxypropane Chemical compound COCCCOC UUAMLBIYJDPGFU-UHFFFAOYSA-N 0.000 description 1
- GJFNRSDCSTVPCJ-UHFFFAOYSA-N 1,8-bis(dimethylamino)naphthalene Chemical compound C1=CC(N(C)C)=C2C(N(C)C)=CC=CC2=C1 GJFNRSDCSTVPCJ-UHFFFAOYSA-N 0.000 description 1
- MISTZQJSHHTDCF-UHFFFAOYSA-N 1-(1-propoxyethoxy)propane Chemical compound CCCOC(C)OCCC MISTZQJSHHTDCF-UHFFFAOYSA-N 0.000 description 1
- CAQYAZNFWDDMIT-UHFFFAOYSA-N 1-ethoxy-2-methoxyethane Chemical compound CCOCCOC CAQYAZNFWDDMIT-UHFFFAOYSA-N 0.000 description 1
- XQQZRZQVBFHBHL-UHFFFAOYSA-N 12-crown-4 Chemical compound C1COCCOCCOCCO1 XQQZRZQVBFHBHL-UHFFFAOYSA-N 0.000 description 1
- VFTFKUDGYRBSAL-UHFFFAOYSA-N 15-crown-5 Chemical compound C1COCCOCCOCCOCCO1 VFTFKUDGYRBSAL-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- LPHIYKWSEYTCLW-UHFFFAOYSA-N 1h-azaborole Chemical compound N1B=CC=C1 LPHIYKWSEYTCLW-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- KNENSDLFTGIERH-UHFFFAOYSA-N 2,2,4,4-tetramethyl-3-phenylpentan-3-ol Chemical compound CC(C)(C)C(O)(C(C)(C)C)C1=CC=CC=C1 KNENSDLFTGIERH-UHFFFAOYSA-N 0.000 description 1
- RLPGNHILYGVQDE-UHFFFAOYSA-N 2,3-dimethoxybutane Chemical compound COC(C)C(C)OC RLPGNHILYGVQDE-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- GDKAXSGMPFSRJY-UHFFFAOYSA-J 2-ethylhexanoate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O GDKAXSGMPFSRJY-UHFFFAOYSA-J 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- RSPAIISXQHXRKX-UHFFFAOYSA-L 5-butylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound Cl[Zr+2]Cl.CCCCC1=CC=C[CH-]1.CCCCC1=CC=C[CH-]1 RSPAIISXQHXRKX-UHFFFAOYSA-L 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- VCFVRHAQERGNFA-UHFFFAOYSA-L C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C2=CC=CC=C2C=C1 VCFVRHAQERGNFA-UHFFFAOYSA-L 0.000 description 1
- JPSHILHGDRCOQO-UHFFFAOYSA-L C1=CC=C2C([Hf](Cl)Cl)C=CC2=C1 Chemical compound C1=CC=C2C([Hf](Cl)Cl)C=CC2=C1 JPSHILHGDRCOQO-UHFFFAOYSA-L 0.000 description 1
- IBEXEHCAULHQDL-UHFFFAOYSA-N C1=CC=CC=C1[Ti](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C1=CC=CC=C1[Ti](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 IBEXEHCAULHQDL-UHFFFAOYSA-N 0.000 description 1
- AFWGUYICVXHLDE-UHFFFAOYSA-N CC1=C(C(=C(C1(C)[Th]C1(C(=C(C(=C1C)C)C)C)C)C)C)C Chemical compound CC1=C(C(=C(C1(C)[Th]C1(C(=C(C(=C1C)C)C)C)C)C)C)C AFWGUYICVXHLDE-UHFFFAOYSA-N 0.000 description 1
- MLOQZZUGWOLMCU-UHFFFAOYSA-N CC[Zr](CC)(CC)CC Chemical compound CC[Zr](CC)(CC)CC MLOQZZUGWOLMCU-UHFFFAOYSA-N 0.000 description 1
- UHBKEKFHZYFRRU-UHFFFAOYSA-N C[Ti](C)(C)C Chemical compound C[Ti](C)(C)C UHBKEKFHZYFRRU-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910004755 Cerium(III) bromide Inorganic materials 0.000 description 1
- 229910008069 Cerium(III) iodide Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910021554 Chromium(II) chloride Inorganic materials 0.000 description 1
- XKBGOOJIPZMVML-UHFFFAOYSA-L Cl[Th](Cl)C1C=CC2=CC=CC=C12 Chemical compound Cl[Th](Cl)C1C=CC2=CC=CC=C12 XKBGOOJIPZMVML-UHFFFAOYSA-L 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 229910021550 Vanadium Chloride Inorganic materials 0.000 description 1
- KPNWVNJRGHNZFB-UHFFFAOYSA-L [Cl-].[Cl-].C(C=C)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1(C(=C(C(=C1C)C)C)C)C Chemical compound [Cl-].[Cl-].C(C=C)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1(C(=C(C(=C1C)C)C)C)C KPNWVNJRGHNZFB-UHFFFAOYSA-L 0.000 description 1
- UXDFDBYFHNIOSS-UHFFFAOYSA-L [Cl-].[Cl-].C(C=C)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(C=C)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1C=CC=C1 UXDFDBYFHNIOSS-UHFFFAOYSA-L 0.000 description 1
- KCSFZUUQDZRPJU-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[U+2] Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[U+2] KCSFZUUQDZRPJU-UHFFFAOYSA-L 0.000 description 1
- RBQGALRSGWYFMO-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=CC=CC=2C3=CC=CC=C3CC1=2 Chemical compound [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=CC=CC=2C3=CC=CC=C3CC1=2 RBQGALRSGWYFMO-UHFFFAOYSA-L 0.000 description 1
- BBCHWNBCYPBQPC-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CCC1)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1C=CC=C1 Chemical compound [Cl-].[Cl-].C1(C=CCC1)C1C2=CC=CC=C2C=2C=CC=C(C1=2)[Zr+2]C1C=CC=C1 BBCHWNBCYPBQPC-UHFFFAOYSA-L 0.000 description 1
- XFIIDQNAANWLFW-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Zr+2]C1C(C(C)=CC=C2C)=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC(C(=CC=C2C)C)=C2C1[Zr+2]C1C(C(C)=CC=C2C)=C2C=C1 XFIIDQNAANWLFW-UHFFFAOYSA-L 0.000 description 1
- LGLBXTFCJQDONE-UHFFFAOYSA-L [Cl-].[Cl-].C=CCC1c2ccccc2-c2cccc([Zr++]c3cccc4-c5ccccc5C(CC=C)c34)c12 Chemical compound [Cl-].[Cl-].C=CCC1c2ccccc2-c2cccc([Zr++]c3cccc4-c5ccccc5C(CC=C)c34)c12 LGLBXTFCJQDONE-UHFFFAOYSA-L 0.000 description 1
- NOHOSTVOEQLCMI-UHFFFAOYSA-L [Cl-].[Cl-].CC1=C(C(=C(C1(C)[U+2]C1(C(=C(C(=C1C)C)C)C)C)C)C)C Chemical compound [Cl-].[Cl-].CC1=C(C(=C(C1(C)[U+2]C1(C(=C(C(=C1C)C)C)C)C)C)C)C NOHOSTVOEQLCMI-UHFFFAOYSA-L 0.000 description 1
- DBVYELOZKSVGDW-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(CCCC2)=C2C1[Zr+2]C1C(CCCC2)=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC(CCCC2)=C2C1[Zr+2]C1C(CCCC2)=C2C=C1C DBVYELOZKSVGDW-UHFFFAOYSA-L 0.000 description 1
- LEOYKWIXWJXYQJ-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C LEOYKWIXWJXYQJ-UHFFFAOYSA-L 0.000 description 1
- VCOKPLHNHKEXIO-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=C(C)C2=C1C=CC2[Zr+2] Chemical compound [Cl-].[Cl-].CC1=CC=C(C)C2=C1C=CC2[Zr+2] VCOKPLHNHKEXIO-UHFFFAOYSA-L 0.000 description 1
- XRMLSJOTMSZVND-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1C Chemical compound [Cl-].[Cl-].CC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1C XRMLSJOTMSZVND-UHFFFAOYSA-L 0.000 description 1
- UMRCJFSXEZHMIS-UHFFFAOYSA-L [Cl-].[Cl-].CC1C=C(C)C(C)=C1[Zr++] Chemical compound [Cl-].[Cl-].CC1C=C(C)C(C)=C1[Zr++] UMRCJFSXEZHMIS-UHFFFAOYSA-L 0.000 description 1
- MPOPEWWQMXWSJQ-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Zr+2] MPOPEWWQMXWSJQ-UHFFFAOYSA-L 0.000 description 1
- OCQLRVFGIINPTO-UHFFFAOYSA-L [Cl-].[Cl-].CCCCC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1CCCC Chemical compound [Cl-].[Cl-].CCCCC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1CCCC OCQLRVFGIINPTO-UHFFFAOYSA-L 0.000 description 1
- HAIQPWLCDGMZST-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](C)=[Zr++](C1C=Cc2ccc(cc12)-c1ccccc1)C1C=Cc2ccc(cc12)-c1ccccc1 Chemical compound [Cl-].[Cl-].C[Si](C)=[Zr++](C1C=Cc2ccc(cc12)-c1ccccc1)C1C=Cc2ccc(cc12)-c1ccccc1 HAIQPWLCDGMZST-UHFFFAOYSA-L 0.000 description 1
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 1
- DZYMMRGSCPJCSA-UHFFFAOYSA-L [Cl-].[Cl-].[Zr++]c1cccc2-c3ccccc3C(C3CCC=C3)c12 Chemical compound [Cl-].[Cl-].[Zr++]c1cccc2-c3ccccc3C(C3CCC=C3)c12 DZYMMRGSCPJCSA-UHFFFAOYSA-L 0.000 description 1
- RZMMIPFUKMHZFD-UHFFFAOYSA-N [Cr+3].CCCCCC(=O)OCC(Cl)Cl Chemical compound [Cr+3].CCCCCC(=O)OCC(Cl)Cl RZMMIPFUKMHZFD-UHFFFAOYSA-N 0.000 description 1
- CLGYSTIXOGUVGG-UHFFFAOYSA-N [Ni].NP(=N)=N Chemical compound [Ni].NP(=N)=N CLGYSTIXOGUVGG-UHFFFAOYSA-N 0.000 description 1
- ADANNTOYRVPQLJ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C ADANNTOYRVPQLJ-UHFFFAOYSA-N 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- RBYGDVHOECIAFC-UHFFFAOYSA-L acetonitrile;palladium(2+);dichloride Chemical compound [Cl-].[Cl-].[Pd+2].CC#N.CC#N RBYGDVHOECIAFC-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000004423 acyloxy group Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- AMVQGJHFDJVOOB-UHFFFAOYSA-H aluminium sulfate octadecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O AMVQGJHFDJVOOB-UHFFFAOYSA-H 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000002635 aromatic organic solvent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- XQYBHCMKXLINQE-UHFFFAOYSA-N buta-1,3-diene;prop-1-ene Chemical compound CC=C.C=CC=C XQYBHCMKXLINQE-UHFFFAOYSA-N 0.000 description 1
- MTKOCRSQUPLVTD-UHFFFAOYSA-N butan-1-olate;titanium(2+) Chemical compound CCCCO[Ti]OCCCC MTKOCRSQUPLVTD-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- TVCHACRVJZXHLX-UHFFFAOYSA-K carbanide;titanium(4+);trichloride Chemical compound [CH3-].Cl[Ti+](Cl)Cl TVCHACRVJZXHLX-UHFFFAOYSA-K 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- MFBPBRIDLMRZJL-UHFFFAOYSA-L chromium(2+);2-ethylhexanoate Chemical compound [Cr+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O MFBPBRIDLMRZJL-UHFFFAOYSA-L 0.000 description 1
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 1
- WBKDDMYJLXVBNI-UHFFFAOYSA-K chromium(3+);2-ethylhexanoate Chemical compound [Cr+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O WBKDDMYJLXVBNI-UHFFFAOYSA-K 0.000 description 1
- XEHUIDSUOAGHBW-UHFFFAOYSA-N chromium;pentane-2,4-dione Chemical compound [Cr].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O XEHUIDSUOAGHBW-UHFFFAOYSA-N 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229920005565 cyclic polymer Polymers 0.000 description 1
- 125000006841 cyclic skeleton Chemical group 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 1
- YMNCCEXICREQQV-UHFFFAOYSA-L cyclopenta-1,3-diene;titanium(4+);dichloride Chemical compound [Cl-].[Cl-].[Ti+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 YMNCCEXICREQQV-UHFFFAOYSA-L 0.000 description 1
- WDGICGVEWQIMTQ-UHFFFAOYSA-L cyclopentane;difluorotitanium Chemical compound F[Ti]F.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 WDGICGVEWQIMTQ-UHFFFAOYSA-L 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- MUNARLQNCCGPQU-UHFFFAOYSA-L dichloropalladium;2-pyridin-2-ylpyridine Chemical compound Cl[Pd]Cl.N1=CC=CC=C1C1=CC=CC=N1 MUNARLQNCCGPQU-UHFFFAOYSA-L 0.000 description 1
- IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- LWBWGOJHWAARSS-UHFFFAOYSA-N diethylalumanyloxy(diethyl)alumane Chemical compound CC[Al](CC)O[Al](CC)CC LWBWGOJHWAARSS-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical class C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- FBZANXDWQAVSTQ-UHFFFAOYSA-N dodecamethylpentasiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C FBZANXDWQAVSTQ-UHFFFAOYSA-N 0.000 description 1
- 229940087203 dodecamethylpentasiloxane Drugs 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002222 fluorine compounds Chemical group 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- AQXQIUZAGYLHQA-UHFFFAOYSA-N hexane silane Chemical compound [SiH4].CCCCCC AQXQIUZAGYLHQA-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- IBMIFJZXMKTKTG-UHFFFAOYSA-L methylidenetitanium(2+);dichloride Chemical compound Cl[Ti](Cl)=C IBMIFJZXMKTKTG-UHFFFAOYSA-L 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- BMGNSKKZFQMGDH-FDGPNNRMSA-L nickel(2+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ni+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O BMGNSKKZFQMGDH-FDGPNNRMSA-L 0.000 description 1
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 1
- UMIPWJGWASORKV-UHFFFAOYSA-N oct-1-yne Chemical compound CCCCCCC#C UMIPWJGWASORKV-UHFFFAOYSA-N 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- WVNUZODXEDDHRM-UHFFFAOYSA-L oxalate;thallium(1+) Chemical compound [Tl+].[Tl+].[O-]C(=O)C([O-])=O WVNUZODXEDDHRM-UHFFFAOYSA-L 0.000 description 1
- BBJSDUUHGVDNKL-UHFFFAOYSA-J oxalate;titanium(4+) Chemical compound [Ti+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BBJSDUUHGVDNKL-UHFFFAOYSA-J 0.000 description 1
- LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- JLKIGFTWXXRPMT-UHFFFAOYSA-N sulphamethoxazole Chemical compound O1C(C)=CC(NS(=O)(=O)C=2C=CC(N)=CC=2)=N1 JLKIGFTWXXRPMT-UHFFFAOYSA-N 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- YRGLXIVYESZPLQ-UHFFFAOYSA-I tantalum pentafluoride Chemical compound F[Ta](F)(F)(F)F YRGLXIVYESZPLQ-UHFFFAOYSA-I 0.000 description 1
- GCPVYIPZZUPXPB-UHFFFAOYSA-I tantalum(v) bromide Chemical compound Br[Ta](Br)(Br)(Br)Br GCPVYIPZZUPXPB-UHFFFAOYSA-I 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- BIEFSHWAGDHEIT-UHFFFAOYSA-J tetrabromovanadium Chemical compound [V+4].[Br-].[Br-].[Br-].[Br-] BIEFSHWAGDHEIT-UHFFFAOYSA-J 0.000 description 1
- 229940008424 tetradecamethylhexasiloxane Drugs 0.000 description 1
- JYHZWKLCYKMFOD-UHFFFAOYSA-J tetraiodovanadium Chemical compound [V+4].[I-].[I-].[I-].[I-] JYHZWKLCYKMFOD-UHFFFAOYSA-J 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YPFBRNLUIFQCQL-UHFFFAOYSA-K tribromomolybdenum Chemical compound Br[Mo](Br)Br YPFBRNLUIFQCQL-UHFFFAOYSA-K 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical class [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- HUYLAMJIPCOVOM-UHFFFAOYSA-K triiodotitanium Chemical compound [Ti+3].[I-].[I-].[I-] HUYLAMJIPCOVOM-UHFFFAOYSA-K 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- IMNIORQANNGBDO-UHFFFAOYSA-J uranium(4+);tetrabromide Chemical compound Br[U](Br)(Br)Br IMNIORQANNGBDO-UHFFFAOYSA-J 0.000 description 1
- SFIHWLKHBCDNCE-UHFFFAOYSA-N uranyl formate Chemical compound OC=O.OC=O.O=[U]=O SFIHWLKHBCDNCE-UHFFFAOYSA-N 0.000 description 1
- 125000005289 uranyl group Chemical group 0.000 description 1
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
- WSJLOGNSKRVGAD-UHFFFAOYSA-L vanadium(ii) bromide Chemical compound [V+2].[Br-].[Br-] WSJLOGNSKRVGAD-UHFFFAOYSA-L 0.000 description 1
- ZOYIPGHJSALYPY-UHFFFAOYSA-K vanadium(iii) bromide Chemical compound [V+3].[Br-].[Br-].[Br-] ZOYIPGHJSALYPY-UHFFFAOYSA-K 0.000 description 1
- 125000005287 vanadyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69638705P | 2005-07-01 | 2005-07-01 | |
| US60/696,387 | 2005-07-01 | ||
| PCT/US2006/024905 WO2007005400A2 (fr) | 2005-07-01 | 2006-06-27 | Compositions de sel d'aluminoxanate possedant une stabilite amelioree dans des solvants aromatiques et aliphatiques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE112006001733T5 true DE112006001733T5 (de) | 2008-07-31 |
Family
ID=35429575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE112006001733T Withdrawn DE112006001733T5 (de) | 2005-07-01 | 2006-06-27 | Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE112006001733T5 (fr) |
| WO (1) | WO2007005400A2 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI555574B (zh) | 2011-03-09 | 2016-11-01 | 亞比馬利股份有限公司 | 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途 |
Citations (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US304523A (en) | 1884-09-02 | Anti friction journal box | ||
| US908463A (en) | 1908-02-25 | 1909-01-05 | Frederick Joseph High | Insulator. |
| US2864843A (en) | 1953-05-06 | 1958-12-16 | Ethyl Corp | Cyclopentadienyl moiety-containing metal monohalides |
| US2983740A (en) | 1953-06-15 | 1961-05-09 | Du Pont | Compounds of a group iv-a metal directly bonded to two cyclopentadienyl nuclei and to at least one inorganic anion and their preparation |
| US4665046A (en) | 1985-10-21 | 1987-05-12 | The Dow Chemical Company | Organoactinide polymer catalysts |
| US4691036A (en) | 1985-02-27 | 1987-09-01 | Bayer Aktiengesellschaft | Organic nickel compounds, the production thereof and the use thereof as polymerization catalysts |
| US4716205A (en) | 1985-10-15 | 1987-12-29 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed polymerization of ethylene |
| US4724273A (en) | 1985-02-13 | 1988-02-09 | Studiengesellschaft Kohle Mbh | Process for preparing alpha-olefin polymers and oligomers |
| US4874880A (en) | 1987-03-10 | 1989-10-17 | Chisso Corporation | Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US4906754A (en) | 1985-10-15 | 1990-03-06 | E. I. Du Pont De Nemours And Company | Nickel catalysts for copolymerization of ethylene |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US4931417A (en) | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
| EP0381495A2 (fr) | 1989-02-03 | 1990-08-08 | Tosoh Corporation | Procédé de préparation du polyéthylène |
| US4952713A (en) | 1988-06-02 | 1990-08-28 | Battelle Memorial Institute | Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation |
| US5003095A (en) | 1990-03-08 | 1991-03-26 | Ethyl Corporation | Process for preparing methylaluminoxanes |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5030606A (en) | 1985-10-15 | 1991-07-09 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed copolymerization of ethylene |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5041583A (en) | 1990-06-28 | 1991-08-20 | Ethyl Corporation | Preparation of aluminoxanes |
| US5066631A (en) | 1990-10-16 | 1991-11-19 | Ethyl Corporation | Hydrocarbon solutions of alkylaluminoxane compounds |
| US5081231A (en) | 1987-08-27 | 1992-01-14 | The Dow Chemical Company | Uranium (III) catalyst for the selective dimerization of propylene to 4-methyl-1-pentene |
| US5084802A (en) | 1989-05-16 | 1992-01-28 | At&T Bell Laboratories | Method for manufacture of EMI reducing circuit card apparatus |
| US5099050A (en) | 1991-04-15 | 1992-03-24 | Ethyl Corporation | Preparation of aluminoxanes |
| US5145819A (en) | 1990-11-12 | 1992-09-08 | Hoechst Aktiengesellschaft | 2-substituted disindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5157008A (en) | 1991-08-01 | 1992-10-20 | Ethyl Corporation | Hydrocarbon solutions of alkylaluminoxane compounds |
| US5162278A (en) | 1988-07-15 | 1992-11-10 | Fina Technology, Inc. | Non-bridged syndiospecific metallocene catalysts and polymerization process |
| US5175326A (en) | 1985-10-15 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Nickel containing organo-metallic compound as catalyst |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5245019A (en) | 1992-01-27 | 1993-09-14 | Phillips Petroleum Company | Olefin polymerization catalyst and process |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| US5268495A (en) | 1990-12-11 | 1993-12-07 | Hoechst Aktiengesellschaft | Metallocenes having bicyclic cyclopentadiene derivatives as ligands, processes for their preparation and their use as catalysts |
| US5276208A (en) | 1990-11-12 | 1994-01-04 | Hoechst Aktiengesellschaft | Metallocenes containing ligands of 2-substituted idenyl derivatives, process for their preparation, and their use as catalysts |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US5329031A (en) | 1991-11-28 | 1994-07-12 | Showa Denko K.K. | Metallocene and process for producing polyolefin using the same |
| US5329033A (en) | 1991-08-26 | 1994-07-12 | Hoechst Aktiengesellschaft | Process for the preparation of an olefin polymer |
| US5330948A (en) | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| US5347025A (en) | 1992-09-09 | 1994-09-13 | Tosoh Corporation | Catalyst for polymerization of vinyl compound |
| US5347026A (en) | 1993-06-11 | 1994-09-13 | Phillips Petroleum Company | Fluorene compounds and methods for making |
| US5347752A (en) | 1992-06-19 | 1994-09-20 | Black Kevin E | Flower care, storage and display device |
| US5371260A (en) | 1994-01-10 | 1994-12-06 | Albemarle Corporation | Amino-aluminoxane compositions |
| US5516739A (en) | 1990-04-20 | 1996-05-14 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| WO1996023010A2 (fr) | 1995-01-24 | 1996-08-01 | E.I. Du Pont De Nemours And Company | POLYMERES D'OLEFINES ET DE α-OLEFINES ET PROCEDES DE POLYMERISATION |
| US5554775A (en) | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
| US5561216A (en) | 1994-07-01 | 1996-10-01 | University Of North Carolina At Chapel Hill | Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| US5565395A (en) | 1995-05-26 | 1996-10-15 | Albemarle Corporation | Aluminoxanate compositions |
| WO1997002298A1 (fr) | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | Procede de polymerisation d'olefines |
| WO1997017380A2 (fr) | 1995-11-06 | 1997-05-15 | Minnesota Mining And Manufacturing Company | Compositions polymerisables comprenant des monomeres d'hydrocarbures d'alphaolefines, et procedes d'utilisation |
| US5637660A (en) | 1995-04-17 | 1997-06-10 | Lyondell Petrochemical Company | Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety |
| US5670682A (en) | 1995-10-19 | 1997-09-23 | Albemarle Corporation | Liquid clathrate aluminoxane compositions |
| JPH09272709A (ja) | 1996-04-05 | 1997-10-21 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒の保存方法 |
| US5756611A (en) | 1997-02-21 | 1998-05-26 | Lyondell Petrochemical Company | α-olefin polymerization catalysts |
| WO1998032776A1 (fr) | 1997-01-28 | 1998-07-30 | Borealis A/S | Nouvelle composition homogene de catalyseur de polymerisation des olefines |
| WO1998040374A2 (fr) | 1997-03-10 | 1998-09-17 | Eastman Chemical Company | Catalyseurs de polymerisation d'olefines contenant des metaux de transition des groupes 8-10, ligands bidentes, procedes utilisant de tels catalyseurs et polymeres obtenus a partir de ces procedes |
| US5866663A (en) | 1995-01-24 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Processes of polymerizing olefins |
| US5922631A (en) | 1995-10-19 | 1999-07-13 | Albemarle Corporation | Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds |
| US6020493A (en) | 1999-05-06 | 2000-02-01 | Equistar Chemicals, Lp | Single-site catalyst preparation |
| US6114483A (en) | 1997-08-27 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| WO2003082466A1 (fr) | 2002-03-28 | 2003-10-09 | Albemarle Corporation | Hydrocarbylhaloalumino xanes |
| WO2003082879A1 (fr) | 2002-03-28 | 2003-10-09 | Albemarle Corporation | Compositions d'aluminoxanates ioniques et utilisation de ces compositions dans une catalyse |
-
2006
- 2006-06-27 WO PCT/US2006/024905 patent/WO2007005400A2/fr active Application Filing
- 2006-06-27 DE DE112006001733T patent/DE112006001733T5/de not_active Withdrawn
Patent Citations (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US304523A (en) | 1884-09-02 | Anti friction journal box | ||
| US908463A (en) | 1908-02-25 | 1909-01-05 | Frederick Joseph High | Insulator. |
| US2864843A (en) | 1953-05-06 | 1958-12-16 | Ethyl Corp | Cyclopentadienyl moiety-containing metal monohalides |
| US2983740A (en) | 1953-06-15 | 1961-05-09 | Du Pont | Compounds of a group iv-a metal directly bonded to two cyclopentadienyl nuclei and to at least one inorganic anion and their preparation |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4724273A (en) | 1985-02-13 | 1988-02-09 | Studiengesellschaft Kohle Mbh | Process for preparing alpha-olefin polymers and oligomers |
| US4691036A (en) | 1985-02-27 | 1987-09-01 | Bayer Aktiengesellschaft | Organic nickel compounds, the production thereof and the use thereof as polymerization catalysts |
| US5175326A (en) | 1985-10-15 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Nickel containing organo-metallic compound as catalyst |
| US4716205A (en) | 1985-10-15 | 1987-12-29 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed polymerization of ethylene |
| US5030606A (en) | 1985-10-15 | 1991-07-09 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed copolymerization of ethylene |
| US4906754A (en) | 1985-10-15 | 1990-03-06 | E. I. Du Pont De Nemours And Company | Nickel catalysts for copolymerization of ethylene |
| US4665046A (en) | 1985-10-21 | 1987-05-12 | The Dow Chemical Company | Organoactinide polymer catalysts |
| US4874880A (en) | 1987-03-10 | 1989-10-17 | Chisso Corporation | Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides |
| US5081231A (en) | 1987-08-27 | 1992-01-14 | The Dow Chemical Company | Uranium (III) catalyst for the selective dimerization of propylene to 4-methyl-1-pentene |
| US4931417A (en) | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US4952713A (en) | 1988-06-02 | 1990-08-28 | Battelle Memorial Institute | Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5162278A (en) | 1988-07-15 | 1992-11-10 | Fina Technology, Inc. | Non-bridged syndiospecific metallocene catalysts and polymerization process |
| EP0381495A2 (fr) | 1989-02-03 | 1990-08-08 | Tosoh Corporation | Procédé de préparation du polyéthylène |
| US5084802A (en) | 1989-05-16 | 1992-01-28 | At&T Bell Laboratories | Method for manufacture of EMI reducing circuit card apparatus |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5003095A (en) | 1990-03-08 | 1991-03-26 | Ethyl Corporation | Process for preparing methylaluminoxanes |
| US5516739A (en) | 1990-04-20 | 1996-05-14 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| US5041583A (en) | 1990-06-28 | 1991-08-20 | Ethyl Corporation | Preparation of aluminoxanes |
| US5066631A (en) | 1990-10-16 | 1991-11-19 | Ethyl Corporation | Hydrocarbon solutions of alkylaluminoxane compounds |
| US5145819A (en) | 1990-11-12 | 1992-09-08 | Hoechst Aktiengesellschaft | 2-substituted disindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins |
| US5276208A (en) | 1990-11-12 | 1994-01-04 | Hoechst Aktiengesellschaft | Metallocenes containing ligands of 2-substituted idenyl derivatives, process for their preparation, and their use as catalysts |
| US5268495A (en) | 1990-12-11 | 1993-12-07 | Hoechst Aktiengesellschaft | Metallocenes having bicyclic cyclopentadiene derivatives as ligands, processes for their preparation and their use as catalysts |
| US5099050A (en) | 1991-04-15 | 1992-03-24 | Ethyl Corporation | Preparation of aluminoxanes |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5157008A (en) | 1991-08-01 | 1992-10-20 | Ethyl Corporation | Hydrocarbon solutions of alkylaluminoxane compounds |
| US5329033A (en) | 1991-08-26 | 1994-07-12 | Hoechst Aktiengesellschaft | Process for the preparation of an olefin polymer |
| US5329031A (en) | 1991-11-28 | 1994-07-12 | Showa Denko K.K. | Metallocene and process for producing polyolefin using the same |
| US5245019A (en) | 1992-01-27 | 1993-09-14 | Phillips Petroleum Company | Olefin polymerization catalyst and process |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5330948A (en) | 1992-03-31 | 1994-07-19 | Northwestern University | Homogeneous catalysts for stereoregular olefin polymerization |
| US5347752A (en) | 1992-06-19 | 1994-09-20 | Black Kevin E | Flower care, storage and display device |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| US5347025A (en) | 1992-09-09 | 1994-09-13 | Tosoh Corporation | Catalyst for polymerization of vinyl compound |
| US5347026A (en) | 1993-06-11 | 1994-09-13 | Phillips Petroleum Company | Fluorene compounds and methods for making |
| US5371260A (en) | 1994-01-10 | 1994-12-06 | Albemarle Corporation | Amino-aluminoxane compositions |
| US5561216A (en) | 1994-07-01 | 1996-10-01 | University Of North Carolina At Chapel Hill | Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| US5554775A (en) | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| US5866663A (en) | 1995-01-24 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Processes of polymerizing olefins |
| US5880323A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Processes for making α-olefins |
| WO1996023010A2 (fr) | 1995-01-24 | 1996-08-01 | E.I. Du Pont De Nemours And Company | POLYMERES D'OLEFINES ET DE α-OLEFINES ET PROCEDES DE POLYMERISATION |
| US5637660A (en) | 1995-04-17 | 1997-06-10 | Lyondell Petrochemical Company | Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety |
| US5565395A (en) | 1995-05-26 | 1996-10-15 | Albemarle Corporation | Aluminoxanate compositions |
| WO1997002298A1 (fr) | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | Procede de polymerisation d'olefines |
| US5714556A (en) | 1995-06-30 | 1998-02-03 | E. I. Dupont De Nemours And Company | Olefin polymerization process |
| US5670682A (en) | 1995-10-19 | 1997-09-23 | Albemarle Corporation | Liquid clathrate aluminoxane compositions |
| US5922631A (en) | 1995-10-19 | 1999-07-13 | Albemarle Corporation | Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds |
| WO1997017380A2 (fr) | 1995-11-06 | 1997-05-15 | Minnesota Mining And Manufacturing Company | Compositions polymerisables comprenant des monomeres d'hydrocarbures d'alphaolefines, et procedes d'utilisation |
| JPH09272709A (ja) | 1996-04-05 | 1997-10-21 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒の保存方法 |
| WO1998032776A1 (fr) | 1997-01-28 | 1998-07-30 | Borealis A/S | Nouvelle composition homogene de catalyseur de polymerisation des olefines |
| US5756611A (en) | 1997-02-21 | 1998-05-26 | Lyondell Petrochemical Company | α-olefin polymerization catalysts |
| WO1998040374A2 (fr) | 1997-03-10 | 1998-09-17 | Eastman Chemical Company | Catalyseurs de polymerisation d'olefines contenant des metaux de transition des groupes 8-10, ligands bidentes, procedes utilisant de tels catalyseurs et polymeres obtenus a partir de ces procedes |
| US6114483A (en) | 1997-08-27 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| US6020493A (en) | 1999-05-06 | 2000-02-01 | Equistar Chemicals, Lp | Single-site catalyst preparation |
| WO2003082466A1 (fr) | 2002-03-28 | 2003-10-09 | Albemarle Corporation | Hydrocarbylhaloalumino xanes |
| WO2003082879A1 (fr) | 2002-03-28 | 2003-10-09 | Albemarle Corporation | Compositions d'aluminoxanates ioniques et utilisation de ces compositions dans une catalyse |
Non-Patent Citations (9)
| Title |
|---|
| Brookhart et al. in Macromolecules, 1995, 28, 5378 |
| Mashima in Shokubai 1999, Band 41, Seite 58 |
| Matsui et al. in Chemistry Letters 2000, Seiten 554-555 |
| Moeller et al., Chemistry, 2. Auflage, Academic Press, Copyright 1984 |
| Schmidt et al. in J. Am. Chem. Soc., 1985, 107, 1443 |
| Seite 27 der Ausgabe vom Chemical & Engineering Neves vom 4. Februar 1985 |
| Seite 27 der Ausgabe von Chemical & Engineering News vom 4. Februar 1985 |
| Starzewski et al. in Angew. Chem. Int. Ed. Eng1., 1987, 26, 63 |
| von Johnson et al. in J. Am. Chem. Soc, 1995, 117, 6414 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007005400A2 (fr) | 2007-01-11 |
| WO2007005400A3 (fr) | 2007-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69723244T2 (de) | Allyl-enthaltende metallkomplexe, und verfahren zur polymerisation von olefinen | |
| DE69334188T2 (de) | Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten | |
| DE60022678T2 (de) | Verfahren zur herstellung eines geträgerten katalysatorsystems und dessen verwendung in einem polymerisationsverfahren | |
| DE60021405T2 (de) | Katalysatorsysteme und deren verwendung in einem polymerisationsverfahren | |
| DE69320805T3 (de) | Verfahren zur herstellung von cyclopentadien-metallkomplex verbindungen und verfahren zur verwendung | |
| DE69033368T3 (de) | Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation | |
| JP3481285B2 (ja) | ポリオレフィンの製造用触媒組成物および製造方法 | |
| CA2546579C (fr) | Compositions d'haloaluminoxane, preparation et utilisation de celles-ci dans des catalyses | |
| EP0336128B1 (fr) | Procédé de préparation d'un polymère d'alpha-oléfine | |
| DE69920334T2 (de) | Übergangsmetallverbindungen und diese enthaltende Katalysatoren zur Polymerisierung von Olefinen | |
| EP0882076B1 (fr) | Systemes de catalyseurs a supports | |
| EP0646604B1 (fr) | Procédé de polymérisation d'oléfine | |
| EP1290039B1 (fr) | Systeme catalyseur pour la polymerisation d'olefines comprenant, comme materiau support, une hydrotalcite calcinee | |
| WO2003082879A1 (fr) | Compositions d'aluminoxanates ioniques et utilisation de ces compositions dans une catalyse | |
| JPH10502951A (ja) | エチレン重合体製造のためのプロ触媒、その製造方法及び用途 | |
| EP1042371A1 (fr) | Systeme de catalyseur supporte pour la polymerisation d'olefines | |
| DE69916431T2 (de) | Donor-modifizierte katalysatoren für die polymerisation von olefinen | |
| DE69630780T2 (de) | Verfahren für syndiotaktische Olefinausbreitung | |
| DE69821528T2 (de) | Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen | |
| DE60004160T2 (de) | Ein verfahren zur herstellung eines geträgerten katalysators und dessen verwendung in einem polymerisationsverfahren | |
| DE4446922A1 (de) | Metallocenverbindung und ihre Verwendung als Katalysatorkomponente | |
| EP0742225A1 (fr) | Composé organométallique | |
| DE69634589T2 (de) | Katalysatorsystem für die Co-Polymerisation von Alphaolefinen | |
| DE60025017T2 (de) | Geträgerter polymerisations-metallocene-katalysator | |
| EP1095069B1 (fr) | Procede permettant de preparer un systeme de catalyseur supporte |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |
Effective date: 20140101 |