DE10296642T5 - Zinkanodenmatrix für eine wiederaufladbare Alkalibatterie - Google Patents
Zinkanodenmatrix für eine wiederaufladbare Alkalibatterie Download PDFInfo
- Publication number
- DE10296642T5 DE10296642T5 DE10296642T DE10296642T DE10296642T5 DE 10296642 T5 DE10296642 T5 DE 10296642T5 DE 10296642 T DE10296642 T DE 10296642T DE 10296642 T DE10296642 T DE 10296642T DE 10296642 T5 DE10296642 T5 DE 10296642T5
- Authority
- DE
- Germany
- Prior art keywords
- anode
- paste according
- zinc
- cellulose
- anode paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011701 zinc Substances 0.000 title claims description 65
- 229910052725 zinc Inorganic materials 0.000 title claims description 64
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 63
- 239000011159 matrix material Substances 0.000 title claims description 25
- 229920002678 cellulose Polymers 0.000 claims abstract description 24
- 239000001913 cellulose Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 239000010405 anode material Substances 0.000 claims abstract description 3
- 239000006185 dispersion Substances 0.000 claims abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 20
- 239000011324 bead Substances 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000011787 zinc oxide Substances 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- -1 polysiloxanes Polymers 0.000 claims description 10
- 239000001856 Ethyl cellulose Substances 0.000 claims description 9
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 9
- 229920001249 ethyl cellulose Polymers 0.000 claims description 9
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 9
- 230000035699 permeability Effects 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 229920000306 polymethylpentene Polymers 0.000 claims description 2
- 239000011116 polymethylpentene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 5
- 150000004706 metal oxides Chemical class 0.000 claims 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229920003086 cellulose ether Polymers 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920001281 polyalkylene Polymers 0.000 claims 1
- 229920006380 polyphenylene oxide Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 235000010980 cellulose Nutrition 0.000 description 16
- 239000003349 gelling agent Substances 0.000 description 11
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 9
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 7
- 238000013459 approach Methods 0.000 description 6
- 210000001787 dendrite Anatomy 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 5
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- 239000004627 regenerated cellulose Substances 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229920001600 hydrophobic polymer Polymers 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- 239000008108 microcrystalline cellulose Substances 0.000 description 2
- 229940016286 microcrystalline cellulose Drugs 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical group [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/32—Silver accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/839,668 | 2001-04-19 | ||
| US09/839,668 US6582851B2 (en) | 2001-04-19 | 2001-04-19 | Anode matrix |
| PCT/US2002/012441 WO2002086992A1 (en) | 2001-04-19 | 2002-04-19 | Zinc anode matrix for rechargeable alkaline battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10296642T5 true DE10296642T5 (de) | 2004-04-22 |
Family
ID=25280359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10296642T Withdrawn DE10296642T5 (de) | 2001-04-19 | 2002-04-19 | Zinkanodenmatrix für eine wiederaufladbare Alkalibatterie |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6582851B2 (enExample) |
| EP (1) | EP1380060A1 (enExample) |
| JP (1) | JP2004527085A (enExample) |
| DE (1) | DE10296642T5 (enExample) |
| DK (1) | DK200301441A (enExample) |
| GB (1) | GB2388954B (enExample) |
| WO (1) | WO2002086992A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7416697B2 (en) | 2002-06-14 | 2008-08-26 | General Electric Company | Method for preparing a metallic article having an other additive constituent, without any melting |
| US7531021B2 (en) | 2004-11-12 | 2009-05-12 | General Electric Company | Article having a dispersion of ultrafine titanium boride particles in a titanium-base matrix |
| US20060210877A1 (en) * | 2005-03-15 | 2006-09-21 | Rechargable Battery Corporation | Flexible pasted anode, primary cell with pasted anode, and method for making same |
| CN101192661B (zh) * | 2006-11-21 | 2011-12-28 | 北京中航长力能源科技有限公司 | 一种注入式锌空气金属燃料电池流动态锌胶电极材料 |
| WO2012067977A2 (en) | 2010-11-15 | 2012-05-24 | Zpower, Llc | Polymer plasticizers for separators |
| US9831499B2 (en) | 2012-04-04 | 2017-11-28 | Phinergy Ltd. | Zinc electrode for use in rechargeable batteries |
| ES2561133B1 (es) | 2014-07-24 | 2016-12-01 | Alejandro Rodriguez Barros | Retrovisor exterior multifunción con dispositivo emisor laser incorporado |
| JP6371162B2 (ja) * | 2014-08-22 | 2018-08-08 | 株式会社日本触媒 | 電極及びそれを用いて構成される電池 |
| JP6721952B2 (ja) * | 2015-07-14 | 2020-07-15 | 国立大学法人九州大学 | 燃料電池及び電解質膜として用いられるナノセルロース膜 |
| CN107681129A (zh) * | 2017-08-23 | 2018-02-09 | 北京航空航天大学 | 一种锌基电池用三维锌/碳复合材料及其制备方法 |
| US10448137B1 (en) | 2018-06-21 | 2019-10-15 | Bose Corporation | Dual zone discharge of rechargeable batteries |
| JP7467213B2 (ja) | 2020-04-21 | 2024-04-15 | エナジーウィズ株式会社 | 亜鉛電池用の負極及び亜鉛電池 |
| CN112713273B (zh) * | 2020-12-18 | 2022-04-26 | 浙江金鹰瓦力新能源科技有限公司 | 一种电池锌负极材料的制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56143667A (en) * | 1980-04-07 | 1981-11-09 | Matsushita Electric Ind Co Ltd | Manufacture of alkaline battery |
| US4368244A (en) | 1980-06-11 | 1983-01-11 | General Electric Company | Zinc electrode for use in rechargeable electrochemical cells |
| US4778737A (en) | 1985-07-30 | 1988-10-18 | The B. F. Goodrich Company | Compositions of polymers in alkaline media |
| US5300371A (en) * | 1990-03-23 | 1994-04-05 | Battery Technologies Inc. | Manganese dioxide positive electrode for rechargeable cells, and cells containing the same |
| CA2046148C (en) | 1990-08-14 | 1997-01-07 | Dale R. Getz | Alkaline cells that are substantially free of mercury |
| US5206096A (en) | 1990-12-31 | 1993-04-27 | Electric Fuel Limited | Slurry for use in rechargeable metal-air batteries |
| US5348816A (en) | 1991-06-11 | 1994-09-20 | Fuji Electrochemical Co., Ltd. | Alkaline battery |
| HUT67932A (en) | 1991-12-19 | 1995-05-29 | Environmental Batteries System | Alkaline manganese dioxide cell of low mercury content or withot mercury |
| JP3111634B2 (ja) | 1992-05-25 | 2000-11-27 | 松下電器産業株式会社 | 亜鉛アルカリ電池の製造法 |
| US5348820A (en) | 1992-07-10 | 1994-09-20 | Nippon Oil Company, Limited | Zinc electrode for alkaline storage battery |
| US5382482A (en) | 1992-08-07 | 1995-01-17 | Nippon Oil Company, Limited | Zinc electrode for alkaline storage battery |
| DE19521727B4 (de) | 1994-06-27 | 2006-04-06 | Toshiba Battery Co., Ltd. | Alkalische Sekundärbatterie |
| JP3359164B2 (ja) * | 1994-10-19 | 2002-12-24 | キヤノン株式会社 | 二次電池 |
| US5686204A (en) | 1996-01-31 | 1997-11-11 | Rayovac Corporation | Gelling agent for alkaline electrochemical cells |
-
2001
- 2001-04-19 US US09/839,668 patent/US6582851B2/en not_active Expired - Fee Related
-
2002
- 2002-04-19 JP JP2002584407A patent/JP2004527085A/ja not_active Withdrawn
- 2002-04-19 WO PCT/US2002/012441 patent/WO2002086992A1/en not_active Ceased
- 2002-04-19 EP EP02723918A patent/EP1380060A1/en not_active Withdrawn
- 2002-04-19 DE DE10296642T patent/DE10296642T5/de not_active Withdrawn
- 2002-04-19 GB GB0316055A patent/GB2388954B/en not_active Expired - Fee Related
-
2003
- 2003-10-02 DK DK200301441A patent/DK200301441A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US6582851B2 (en) | 2003-06-24 |
| GB2388954B (en) | 2004-10-13 |
| WO2002086992A1 (en) | 2002-10-31 |
| JP2004527085A (ja) | 2004-09-02 |
| DK200301441A (da) | 2003-10-02 |
| GB0316055D0 (en) | 2003-08-13 |
| GB2388954A (en) | 2003-11-26 |
| EP1380060A1 (en) | 2004-01-14 |
| US20020177040A1 (en) | 2002-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8127 | New person/name/address of the applicant |
Owner name: ZPOWER BATTERY, INC.,, SANTA BARBARA, CALIF., US |
|
| 8127 | New person/name/address of the applicant |
Owner name: ZPOWER,INC., CARMARILLO, CALIF., US |
|
| 8139 | Disposal/non-payment of the annual fee |