DE102018215394A1 - Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen - Google Patents

Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen Download PDF

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Publication number
DE102018215394A1
DE102018215394A1 DE102018215394.9A DE102018215394A DE102018215394A1 DE 102018215394 A1 DE102018215394 A1 DE 102018215394A1 DE 102018215394 A DE102018215394 A DE 102018215394A DE 102018215394 A1 DE102018215394 A1 DE 102018215394A1
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Germany
Prior art keywords
procedure according
hydrogenolysis
oxygen
boron
sugar
Prior art date
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Withdrawn
Application number
DE102018215394.9A
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German (de)
English (en)
Inventor
Christoph Glotzbach
Steffen Schirrmeister
Regina Palkovits
Anna Katharina Beine
Peter J. C. Hausoul
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ThyssenKrupp AG
Rheinisch Westlische Technische Hochschuke RWTH
ThyssenKrupp Industrial Solutions AG
Original Assignee
ThyssenKrupp AG
Rheinisch Westlische Technische Hochschuke RWTH
ThyssenKrupp Industrial Solutions AG
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Application filed by ThyssenKrupp AG, Rheinisch Westlische Technische Hochschuke RWTH, ThyssenKrupp Industrial Solutions AG filed Critical ThyssenKrupp AG
Priority to DE102018215394.9A priority Critical patent/DE102018215394A1/de
Priority to PCT/EP2019/073498 priority patent/WO2020053035A1/fr
Publication of DE102018215394A1 publication Critical patent/DE102018215394A1/de
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE102018215394.9A 2018-09-11 2018-09-11 Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen Withdrawn DE102018215394A1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE102018215394.9A DE102018215394A1 (de) 2018-09-11 2018-09-11 Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen
PCT/EP2019/073498 WO2020053035A1 (fr) 2018-09-11 2019-09-04 Procédé de transformation chimique de sucres ou d'alcools de sucre en glycols

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Application Number Priority Date Filing Date Title
DE102018215394.9A DE102018215394A1 (de) 2018-09-11 2018-09-11 Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen

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DE (1) DE102018215394A1 (fr)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019113135A1 (de) * 2019-05-17 2020-11-19 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen
US11167268B2 (en) * 2019-09-25 2021-11-09 National Tsing Hua University Catalyst and method for manufacturing the same and method for hydrogenating aromatic epoxy compound
CN115073263A (zh) * 2022-06-28 2022-09-20 南京工业大学 一种催化剂连续催化制备小分子多元醇的方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115340452B (zh) * 2021-05-14 2023-12-08 四川大学 一种由赤藓糖醇、甘露醇或山梨醇催化转化制备羟基乙酸的方法

Citations (11)

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WO2003035593A1 (fr) * 2001-10-23 2003-05-01 Battelle Memorial Institute Hydrogenolyse de sucres et alcools a 5 atomes de carbone
WO2008071642A1 (fr) * 2006-12-15 2008-06-19 Basf Se Procédé pour produire du 1,2-éthylèneglycol et du 1,2-propylèneglycol par hydrogénolyse par catalyse hétérogène d'un polyol
DE102008028070A1 (de) * 2008-06-12 2009-12-17 Bayer Technology Services Gmbh Katalysator und Verfahren zur Hydrierung von organischen Verbindungen
US20100276644A1 (en) * 2007-12-20 2010-11-04 Bayer Technology Services Gmbh Method for producing nitrogen-doped carbon nanotubes
US20110154722A1 (en) * 2009-12-31 2011-06-30 Chheda Juben Nemchand Direct aqueous phase reforming of bio-based feedstocks
US8350108B2 (en) * 2008-08-27 2013-01-08 Virent, Inc. Synthesis of liquid fuels from biomass
EP2061860B1 (fr) * 2007-03-08 2013-12-18 Virent, Inc. Synthèse de combustibles et de produits chimiques liquides à partir d'hydrocarbures oxygénés
US8877958B2 (en) * 2010-10-28 2014-11-04 Cognis Ip Management Gmbh Method to prepare beta-functionalized aliphatic esters
WO2016119568A1 (fr) * 2015-01-27 2016-08-04 中国石油化工股份有限公司 Matériau nanocarbone contenant un hétéro-atome, son procédé de préparation et utilisation associée, et procédé de réaction de déshydrogénation d'hydrocarbures
WO2017011615A1 (fr) * 2015-07-15 2017-01-19 Archer Daniels Midland Company Catalyseurs multimétalliques contenant du cuivre améliorés et procédé d'utilisation de ceux-ci pour produire du 1,2-propane-diol d'origine biologique
DE102017204322A1 (de) * 2017-03-15 2018-09-20 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4640748B2 (ja) * 2001-07-12 2011-03-02 旭化成ケミカルズ株式会社 カルボン酸直接水素添加用触媒
CN101850249B (zh) * 2009-03-31 2011-12-28 华东理工大学 一种规整结构钌催化剂及其制备方法

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003035593A1 (fr) * 2001-10-23 2003-05-01 Battelle Memorial Institute Hydrogenolyse de sucres et alcools a 5 atomes de carbone
WO2008071642A1 (fr) * 2006-12-15 2008-06-19 Basf Se Procédé pour produire du 1,2-éthylèneglycol et du 1,2-propylèneglycol par hydrogénolyse par catalyse hétérogène d'un polyol
EP2061860B1 (fr) * 2007-03-08 2013-12-18 Virent, Inc. Synthèse de combustibles et de produits chimiques liquides à partir d'hydrocarbures oxygénés
US20100276644A1 (en) * 2007-12-20 2010-11-04 Bayer Technology Services Gmbh Method for producing nitrogen-doped carbon nanotubes
DE102008028070A1 (de) * 2008-06-12 2009-12-17 Bayer Technology Services Gmbh Katalysator und Verfahren zur Hydrierung von organischen Verbindungen
US8350108B2 (en) * 2008-08-27 2013-01-08 Virent, Inc. Synthesis of liquid fuels from biomass
US20110154722A1 (en) * 2009-12-31 2011-06-30 Chheda Juben Nemchand Direct aqueous phase reforming of bio-based feedstocks
US8877958B2 (en) * 2010-10-28 2014-11-04 Cognis Ip Management Gmbh Method to prepare beta-functionalized aliphatic esters
WO2016119568A1 (fr) * 2015-01-27 2016-08-04 中国石油化工股份有限公司 Matériau nanocarbone contenant un hétéro-atome, son procédé de préparation et utilisation associée, et procédé de réaction de déshydrogénation d'hydrocarbures
WO2017011615A1 (fr) * 2015-07-15 2017-01-19 Archer Daniels Midland Company Catalyseurs multimétalliques contenant du cuivre améliorés et procédé d'utilisation de ceux-ci pour produire du 1,2-propane-diol d'origine biologique
DE102017204322A1 (de) * 2017-03-15 2018-09-20 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur chemischen Umsetzung von Zuckern oder Zuckeralkoholen zu Glykolen

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019113135A1 (de) * 2019-05-17 2020-11-19 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen
WO2020234237A1 (fr) 2019-05-17 2020-11-26 Thyssenkrupp Ag Procédé de production de glycols à partir de sucres et d'alcool de sucre
US11167268B2 (en) * 2019-09-25 2021-11-09 National Tsing Hua University Catalyst and method for manufacturing the same and method for hydrogenating aromatic epoxy compound
CN115073263A (zh) * 2022-06-28 2022-09-20 南京工业大学 一种催化剂连续催化制备小分子多元醇的方法
CN115073263B (zh) * 2022-06-28 2024-01-02 南京工业大学 一种催化剂连续催化制备小分子多元醇的方法

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