DE102012220793A1 - Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen - Google Patents
Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen Download PDFInfo
- Publication number
- DE102012220793A1 DE102012220793A1 DE102012220793A DE102012220793A DE102012220793A1 DE 102012220793 A1 DE102012220793 A1 DE 102012220793A1 DE 102012220793 A DE102012220793 A DE 102012220793A DE 102012220793 A DE102012220793 A DE 102012220793A DE 102012220793 A1 DE102012220793 A1 DE 102012220793A1
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- Prior art keywords
- alkyl
- metal
- lithium
- reaction
- independently
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 16
- 239000002184 metal Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000003792 electrolyte Substances 0.000 title claims description 10
- 239000000654 additive Substances 0.000 title claims description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 title 1
- 150000003839 salts Chemical class 0.000 claims abstract description 19
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims abstract description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 229910001512 metal fluoride Inorganic materials 0.000 claims abstract description 12
- 229910015900 BF3 Inorganic materials 0.000 claims abstract description 9
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 8
- 150000002825 nitriles Chemical group 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- 239000003446 ligand Substances 0.000 claims abstract description 6
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 4
- 150000001768 cations Chemical class 0.000 claims abstract description 4
- 239000002738 chelating agent Substances 0.000 claims abstract description 4
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims description 31
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 14
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- -1 phosphorus halides Chemical class 0.000 claims description 7
- 239000002841 Lewis acid Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 150000007517 lewis acids Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 4
- 239000013522 chelant Substances 0.000 claims description 4
- 150000002596 lactones Chemical class 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 claims description 2
- 125000005910 alkyl carbonate group Chemical group 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 150000004651 carbonic acid esters Chemical class 0.000 claims description 2
- 150000004292 cyclic ethers Chemical class 0.000 claims description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- ZTOMUSMDRMJOTH-UHFFFAOYSA-N glutaronitrile Chemical compound N#CCCCC#N ZTOMUSMDRMJOTH-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical compound N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 claims 1
- OKVJWADVFPXWQD-UHFFFAOYSA-N difluoroborinic acid Chemical class OB(F)F OKVJWADVFPXWQD-UHFFFAOYSA-N 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 29
- 229910013188 LiBOB Inorganic materials 0.000 description 19
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 14
- 229910013063 LiBF 4 Inorganic materials 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- 238000005481 NMR spectroscopy Methods 0.000 description 8
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 238000001897 boron-11 nuclear magnetic resonance spectrum Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229910003902 SiCl 4 Inorganic materials 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 1
- JYFWUMLHFWQKFF-UHFFFAOYSA-O CC[OH+]C(C(F)(F)F)C(F)(F)F Chemical compound CC[OH+]C(C(F)(F)F)C(F)(F)F JYFWUMLHFWQKFF-UHFFFAOYSA-O 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- PAQDBBQZEOTLCK-UHFFFAOYSA-N O=C(C(O1)=O)O[B]1(F)F Chemical compound O=C(C(O1)=O)O[B]1(F)F PAQDBBQZEOTLCK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- DDCDOSJHFOGNRO-UHFFFAOYSA-N bis(trimethylsilyl) oxalate Chemical compound C[Si](C)(C)OC(=O)C(=O)O[Si](C)(C)C DDCDOSJHFOGNRO-UHFFFAOYSA-N 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- QTTDHHKBHTUYCK-UHFFFAOYSA-L dilithium;propanedioate Chemical compound [Li+].[Li+].[O-]C(=O)CC([O-])=O QTTDHHKBHTUYCK-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- CTIKAHQFRQTTAY-UHFFFAOYSA-N fluoro(trimethyl)silane Chemical compound C[Si](C)(C)F CTIKAHQFRQTTAY-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- HOTBIMZWHWHNKJ-UHFFFAOYSA-N lithium;1,1,1,3,3,3-hexafluoropropan-2-olate Chemical compound [Li+].FC(F)(F)C([O-])C(F)(F)F HOTBIMZWHWHNKJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000652 nickel hydride Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012220793A DE102012220793A1 (de) | 2011-11-14 | 2012-11-14 | Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011086306.0 | 2011-11-14 | ||
| DE102011086306 | 2011-11-14 | ||
| DE102012220793A DE102012220793A1 (de) | 2011-11-14 | 2012-11-14 | Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102012220793A1 true DE102012220793A1 (de) | 2013-05-16 |
Family
ID=47172642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102012220793A Withdrawn DE102012220793A1 (de) | 2011-11-14 | 2012-11-14 | Verfahren zur Herstellung von Metalldifluorochelatoboraten und Verwendung als Batterieelektrolyte oder Additive in galvanischen Zellen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9260456B2 (https=) |
| EP (1) | EP2780346B1 (https=) |
| JP (1) | JP6188706B2 (https=) |
| CN (1) | CN104185636B (https=) |
| CA (1) | CA2856123C (https=) |
| DE (1) | DE102012220793A1 (https=) |
| WO (1) | WO2013072359A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108475823B (zh) * | 2015-12-18 | 2022-07-12 | 巴斯夫欧洲公司 | 包含不对称硼酸盐的用于锂离子电池的非水电解质 |
| CN105541890B (zh) * | 2016-01-27 | 2017-08-29 | 太原理工大学 | 一种二氟草酸硼酸钠的合成方法 |
| CN107017434B (zh) * | 2016-01-28 | 2019-06-11 | 宁德新能源科技有限公司 | 非水电解液及锂离子二次电池 |
| KR102662137B1 (ko) | 2016-02-05 | 2024-04-29 | 고션 인코포레이티드 | 다이플루오로 킬레이토 보레이트 염의 제조 |
| CN107305963A (zh) * | 2016-04-25 | 2017-10-31 | 上海交通大学 | 用于锂硫电池的电解液及其制备方法 |
| CN105870504B (zh) * | 2016-05-04 | 2019-11-22 | 宁德新能源科技有限公司 | 一种电解液及锂离子电池 |
| US10287302B2 (en) * | 2017-06-12 | 2019-05-14 | Seeo, Inc. | Method for synthesis of lithium fluorinated borate salts |
| CN109134522A (zh) * | 2017-06-16 | 2019-01-04 | 中国科学院青岛生物能源与过程研究所 | 双羟基螯合氟代烷氧基硼酸盐及其制备方法和应用 |
| CN108101931B (zh) * | 2017-12-19 | 2019-10-29 | 河南师范大学 | 一种双草酸硼酸铵盐[nhr1r2r3][bc4o8]及其制备方法 |
| CN111138462B (zh) * | 2018-11-05 | 2022-10-21 | 江苏国泰超威新材料有限公司 | 一种2-氟丙二酸二氟硼酸锂的制备方法及其应用 |
| JP7155898B2 (ja) * | 2018-11-08 | 2022-10-19 | 株式会社豊田自動織機 | 電解液及び二次電池 |
| US11649358B2 (en) | 2019-09-11 | 2023-05-16 | Uchicago Argonne, Llc | Borate salts, polymers and composites |
| CN111592559A (zh) * | 2020-05-22 | 2020-08-28 | 兰州理工大学 | 一种一步法合成二氟草酸硼酸钠的方法 |
| CN111883827A (zh) * | 2020-07-16 | 2020-11-03 | 香河昆仑化学制品有限公司 | 一种锂离子电池非水电解液和锂离子电池 |
| CN113800525A (zh) * | 2021-11-03 | 2021-12-17 | 九江天赐高新材料有限公司 | 一种利用硼盐尾气联产氟硅酸盐和盐酸的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1195834A2 (en) | 2000-10-03 | 2002-04-10 | Central Glass Company, Limited | Electrolyte for electrochemical device |
| EP1308449A2 (en) | 2001-11-05 | 2003-05-07 | Central Glass Company, Limited | Process for synthesizing ionic metal complex |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10108592C1 (de) * | 2001-02-22 | 2002-08-14 | Chemetall Gmbh | Borchelatkomplexe, Verfahren zu deren Herstellung sowie deren Verwendung |
| DE102004011522A1 (de) * | 2004-03-08 | 2005-09-29 | Chemetall Gmbh | Leitsalze für Lithiumionenbatterien und deren Herstellung |
| DE102010008331A1 (de) * | 2009-02-18 | 2010-08-19 | Chemetall Gmbh | Galvanische Zelle mit einer Lithiummetall oder eine lithiummetallhaltigen Legierung als Anodenmaterial |
| CN101643481B (zh) * | 2009-08-28 | 2011-08-17 | 张家港市国泰华荣化工新材料有限公司 | 一种得到二氟草酸硼酸锂与双草酸硼酸锂的合成工艺 |
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2012
- 2012-11-14 CA CA2856123A patent/CA2856123C/en active Active
- 2012-11-14 CN CN201280055854.9A patent/CN104185636B/zh active Active
- 2012-11-14 DE DE102012220793A patent/DE102012220793A1/de not_active Withdrawn
- 2012-11-14 WO PCT/EP2012/072603 patent/WO2013072359A1/de not_active Ceased
- 2012-11-14 JP JP2014541642A patent/JP6188706B2/ja active Active
- 2012-11-14 EP EP12784274.8A patent/EP2780346B1/de active Active
- 2012-11-14 US US14/357,919 patent/US9260456B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1195834A2 (en) | 2000-10-03 | 2002-04-10 | Central Glass Company, Limited | Electrolyte for electrochemical device |
| EP1308449A2 (en) | 2001-11-05 | 2003-05-07 | Central Glass Company, Limited | Process for synthesizing ionic metal complex |
| US6849752B2 (en) | 2001-11-05 | 2005-02-01 | Central Glass Company, Ltd. | Process for synthesizing ionic metal complex |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104185636A (zh) | 2014-12-03 |
| US9260456B2 (en) | 2016-02-16 |
| CA2856123A1 (en) | 2013-05-23 |
| US20140288331A1 (en) | 2014-09-25 |
| EP2780346A1 (de) | 2014-09-24 |
| WO2013072359A1 (de) | 2013-05-23 |
| JP2014533293A (ja) | 2014-12-11 |
| CA2856123C (en) | 2020-07-21 |
| CN104185636B (zh) | 2016-08-17 |
| JP6188706B2 (ja) | 2017-08-30 |
| EP2780346B1 (de) | 2019-10-16 |
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