DE102009032802A1 - Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils - Google Patents
Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils Download PDFInfo
- Publication number
- DE102009032802A1 DE102009032802A1 DE102009032802A DE102009032802A DE102009032802A1 DE 102009032802 A1 DE102009032802 A1 DE 102009032802A1 DE 102009032802 A DE102009032802 A DE 102009032802A DE 102009032802 A DE102009032802 A DE 102009032802A DE 102009032802 A1 DE102009032802 A1 DE 102009032802A1
- Authority
- DE
- Germany
- Prior art keywords
- olefin
- feed stream
- stream
- desulfurization
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 136
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 238000000034 method Methods 0.000 title claims abstract description 49
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 41
- 230000023556 desulfurization Effects 0.000 title claims abstract description 41
- 239000003054 catalyst Substances 0.000 claims abstract description 102
- 239000007789 gas Substances 0.000 claims abstract description 60
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 29
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000001105 regulatory effect Effects 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 48
- 230000001276 controlling effect Effects 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 17
- 238000010790 dilution Methods 0.000 claims description 11
- 239000012895 dilution Substances 0.000 claims description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 238000005201 scrubbing Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 239000003463 adsorbent Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims 26
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 150000003464 sulfur compounds Chemical class 0.000 abstract description 6
- 239000008188 pellet Substances 0.000 abstract 1
- 239000012495 reaction gas Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1088—Olefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/802—Diluents
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009032802A DE102009032802A1 (de) | 2009-07-10 | 2009-07-10 | Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils |
| EP10739852.1A EP2451903B1 (de) | 2009-07-10 | 2010-07-07 | Verfahren zur entschwefelung olefinhaltiger einsatzstoffe durch regelung des olefinanteils |
| PCT/EP2010/004092 WO2011003585A2 (de) | 2009-07-10 | 2010-07-07 | Verfahren zur entschwefelung olefinhaltiger einsatzstoffe durch regelung des olefinanteils |
| DK10739852.1T DK2451903T3 (da) | 2009-07-10 | 2010-07-07 | Fremgangsmåde til afsvovling af olefinholdige råstoffer ved regulering af olefinandelen |
| CN201080031139.2A CN102471703B (zh) | 2009-07-10 | 2010-07-07 | 通过烯烃份额的调节为含烯烃原料脱硫的方法 |
| EA201290030A EA028944B1 (ru) | 2009-07-10 | 2010-07-07 | Способ удаления серы из содержащего олефины сырья путем регулирования содержания олефинов |
| US13/382,822 US20130030235A1 (en) | 2009-07-10 | 2010-07-07 | Method for desulfurizing olefin-containing charge material by controlling the olefin content |
| PL10739852T PL2451903T3 (pl) | 2009-07-10 | 2010-07-07 | Sposób odsiarczania surowców zawierających olefiny przez regulowanie udziału olefin |
| MX2012000429A MX2012000429A (es) | 2009-07-10 | 2010-07-07 | Procedimiento para la desulfuracion de materiales de carga que contienen olefinas mediante la regulacion de la porcion de olefinas. |
| IN1106DEN2012 IN2012DN01106A (https=) | 2009-07-10 | 2010-07-07 | |
| MYPI2012000075A MY172046A (en) | 2009-07-10 | 2010-07-07 | Method for desulfurizing olefin-containing charge material by controlling the olefin content |
| CA2767397A CA2767397A1 (en) | 2009-07-10 | 2010-07-07 | Process for the desulphurisation of olefin-containing feedstocks by controlling the olefin content |
| CO12021311A CO6612178A2 (es) | 2009-07-10 | 2012-02-07 | Procedimiento para la desulfuracion de materiales de carga que contienen olefinas mediante la regulacion de la porcion de olefinas |
| ZA2012/00993A ZA201200993B (en) | 2009-07-10 | 2012-02-10 | Process for the desulphurisation of olefin containing feedstocks by controlling the olefin content |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009032802A DE102009032802A1 (de) | 2009-07-10 | 2009-07-10 | Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102009032802A1 true DE102009032802A1 (de) | 2011-01-13 |
Family
ID=42938202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102009032802A Withdrawn DE102009032802A1 (de) | 2009-07-10 | 2009-07-10 | Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20130030235A1 (https=) |
| EP (1) | EP2451903B1 (https=) |
| CN (1) | CN102471703B (https=) |
| CA (1) | CA2767397A1 (https=) |
| CO (1) | CO6612178A2 (https=) |
| DE (1) | DE102009032802A1 (https=) |
| DK (1) | DK2451903T3 (https=) |
| EA (1) | EA028944B1 (https=) |
| IN (1) | IN2012DN01106A (https=) |
| MX (1) | MX2012000429A (https=) |
| MY (1) | MY172046A (https=) |
| PL (1) | PL2451903T3 (https=) |
| WO (1) | WO2011003585A2 (https=) |
| ZA (1) | ZA201200993B (https=) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10597593B2 (en) * | 2016-10-07 | 2020-03-24 | Haldor Topsoe A/S | Process for hydrotreatment of a fuel gas stream containing more than 4% olefins |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007059243A1 (de) | 2007-12-07 | 2009-06-10 | Uhde Gmbh | Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe |
| DE102008059243A1 (de) | 2008-11-21 | 2010-05-27 | Newfrey Llc, Newark | Fügebauteil und Verfahren zum Herstellen eines Fügebauteils |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB104771A (en) * | 1916-04-04 | 1917-03-22 | Augustus Bever | Improvements in Explosive Projectiles. |
| GB1044771A (https=) | 1963-04-02 | 1900-01-01 | ||
| US3506567A (en) | 1966-08-04 | 1970-04-14 | Standard Oil Co | Two-stage conversion of nitrogen contaminated feedstocks |
| US3983029A (en) | 1973-03-02 | 1976-09-28 | Chevron Research Company | Hydrotreating catalyst and process |
| US4017382A (en) * | 1975-11-17 | 1977-04-12 | Gulf Research & Development Company | Hydrodesulfurization process with upstaged reactor zones |
| NL191763C (nl) * | 1979-09-26 | 1996-07-02 | Shell Int Research | Werkwijze voor ontmetalliseren van een koolwaterstofolie. |
| CA2614020C (en) | 2005-07-04 | 2014-02-11 | Neste Oil Oyj | Process for the manufacture of diesel range hydrocarbons |
| ES2550259T5 (es) * | 2005-07-04 | 2023-06-08 | Neste Oyj | Proceso para la fabricación de hidrocarburos en el intervalo del diésel |
| AR066682A1 (es) * | 2007-05-25 | 2009-09-02 | Shell Int Research | Un proceso para remover azufre a partir de sendas corrientes de gas de combustible, menos reactivas y mas reactivas que contienen azufre organico y olefinas livianas |
| US9279087B2 (en) * | 2008-06-30 | 2016-03-08 | Uop Llc | Multi-staged hydroprocessing process and system |
| ES2385693T3 (es) * | 2009-03-04 | 2012-07-30 | IFP Energies Nouvelles | Procedimiento para la hidrogenación continua de materias primas que contienen triglicéridos |
-
2009
- 2009-07-10 DE DE102009032802A patent/DE102009032802A1/de not_active Withdrawn
-
2010
- 2010-07-07 IN IN1106DEN2012 patent/IN2012DN01106A/en unknown
- 2010-07-07 MY MYPI2012000075A patent/MY172046A/en unknown
- 2010-07-07 EP EP10739852.1A patent/EP2451903B1/de active Active
- 2010-07-07 CA CA2767397A patent/CA2767397A1/en not_active Abandoned
- 2010-07-07 MX MX2012000429A patent/MX2012000429A/es unknown
- 2010-07-07 EA EA201290030A patent/EA028944B1/ru not_active IP Right Cessation
- 2010-07-07 DK DK10739852.1T patent/DK2451903T3/da active
- 2010-07-07 PL PL10739852T patent/PL2451903T3/pl unknown
- 2010-07-07 WO PCT/EP2010/004092 patent/WO2011003585A2/de not_active Ceased
- 2010-07-07 US US13/382,822 patent/US20130030235A1/en not_active Abandoned
- 2010-07-07 CN CN201080031139.2A patent/CN102471703B/zh not_active Expired - Fee Related
-
2012
- 2012-02-07 CO CO12021311A patent/CO6612178A2/es active IP Right Grant
- 2012-02-10 ZA ZA2012/00993A patent/ZA201200993B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007059243A1 (de) | 2007-12-07 | 2009-06-10 | Uhde Gmbh | Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe |
| DE102008059243A1 (de) | 2008-11-21 | 2010-05-27 | Newfrey Llc, Newark | Fügebauteil und Verfahren zum Herstellen eines Fügebauteils |
Also Published As
| Publication number | Publication date |
|---|---|
| CO6612178A2 (es) | 2013-02-01 |
| MX2012000429A (es) | 2012-06-08 |
| ZA201200993B (en) | 2012-09-26 |
| PL2451903T3 (pl) | 2021-03-08 |
| EA201290030A1 (ru) | 2012-07-30 |
| EP2451903B1 (de) | 2020-09-02 |
| MY172046A (en) | 2019-11-12 |
| CA2767397A1 (en) | 2011-01-13 |
| CN102471703A (zh) | 2012-05-23 |
| WO2011003585A2 (de) | 2011-01-13 |
| WO2011003585A3 (de) | 2011-06-16 |
| DK2451903T3 (da) | 2020-11-23 |
| CN102471703B (zh) | 2015-12-16 |
| US20130030235A1 (en) | 2013-01-31 |
| IN2012DN01106A (https=) | 2015-04-10 |
| EP2451903A2 (de) | 2012-05-16 |
| EA028944B1 (ru) | 2018-01-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R081 | Change of applicant/patentee |
Owner name: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, DE Free format text: FORMER OWNER: UHDE GMBH, 44141 DORTMUND, DE Effective date: 20141027 |
|
| R012 | Request for examination validly filed | ||
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |