DE102004055425B4 - Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben - Google Patents

Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben Download PDF

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Publication number
DE102004055425B4
DE102004055425B4 DE102004055425A DE102004055425A DE102004055425B4 DE 102004055425 B4 DE102004055425 B4 DE 102004055425B4 DE 102004055425 A DE102004055425 A DE 102004055425A DE 102004055425 A DE102004055425 A DE 102004055425A DE 102004055425 B4 DE102004055425 B4 DE 102004055425B4
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DE
Germany
Prior art keywords
fuel
mixing chamber
zone
oxidizing agent
supplied
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE102004055425A
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German (de)
English (en)
Other versions
DE102004055425A1 (de
Inventor
Zdeněk Dr. Porš
Andreas Tschauder
Joachim Dr. Pasel
Ralf Dr. Peters
Detlef Prof. Dr. Stolten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Forschungszentrum Juelich GmbH
Original Assignee
Forschungszentrum Juelich GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Forschungszentrum Juelich GmbH filed Critical Forschungszentrum Juelich GmbH
Priority to DE102004055425A priority Critical patent/DE102004055425B4/de
Priority to EP05806947.7A priority patent/EP1812154B1/de
Priority to PCT/DE2005/002041 priority patent/WO2006053534A1/de
Priority to JP2007541666A priority patent/JP4898695B2/ja
Priority to CA2587326A priority patent/CA2587326C/en
Priority to US11/791,011 priority patent/US7461618B2/en
Publication of DE102004055425A1 publication Critical patent/DE102004055425A1/de
Application granted granted Critical
Publication of DE102004055425B4 publication Critical patent/DE102004055425B4/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B01J19/0026Avoiding carbon deposits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F2025/91Direction of flow or arrangement of feed and discharge openings
    • B01F2025/913Vortex flow, i.e. flow spiraling in a tangential direction and moving in an axial direction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/10Mixing gases with gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/70Spray-mixers, e.g. for mixing intersecting sheets of material
    • B01F25/72Spray-mixers, e.g. for mixing intersecting sheets of material with nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00259Preventing runaway of the chemical reaction
    • B01J2219/00265Preventing flame propagation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1247Higher hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276Mixing of different feed components
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE102004055425A 2004-11-17 2004-11-17 Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben Expired - Lifetime DE102004055425B4 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE102004055425A DE102004055425B4 (de) 2004-11-17 2004-11-17 Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben
EP05806947.7A EP1812154B1 (de) 2004-11-17 2005-11-12 Mischkammer für einen reformer sowie verfahren zum betreiben derselben
PCT/DE2005/002041 WO2006053534A1 (de) 2004-11-17 2005-11-12 Mischkammer für einen reformer sowie verfahren zum betreiben derselben
JP2007541666A JP4898695B2 (ja) 2004-11-17 2005-11-12 改質器の混合室及びそれを運転する方法
CA2587326A CA2587326C (en) 2004-11-17 2005-11-12 Mixing chamber for a reformer and method for operating same
US11/791,011 US7461618B2 (en) 2004-11-17 2005-11-12 Reformer mixing chamber and method for operating same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102004055425A DE102004055425B4 (de) 2004-11-17 2004-11-17 Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben

Publications (2)

Publication Number Publication Date
DE102004055425A1 DE102004055425A1 (de) 2006-05-24
DE102004055425B4 true DE102004055425B4 (de) 2007-06-14

Family

ID=35788324

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102004055425A Expired - Lifetime DE102004055425B4 (de) 2004-11-17 2004-11-17 Mischkammer für einen Reformer sowie Verfahren zum Betreiben derselben

Country Status (6)

Country Link
US (1) US7461618B2 (https=)
EP (1) EP1812154B1 (https=)
JP (1) JP4898695B2 (https=)
CA (1) CA2587326C (https=)
DE (1) DE102004055425B4 (https=)
WO (1) WO2006053534A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007040192A1 (de) * 2007-08-25 2009-02-26 J. Eberspächer GmbH & Co. KG Reformer und Brennstoffzellensystem
RU2538260C2 (ru) * 2009-04-23 2015-01-10 Эвоник Рем ГмбХ Дозирующее кольцо
CN112546889A (zh) * 2020-11-16 2021-03-26 哈尔滨工业大学 一种用于储释热系统热稳定输出的气体混合装置

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US7547002B2 (en) 2005-04-15 2009-06-16 Delavan Inc Integrated fuel injection and mixing systems for fuel reformers and methods of using the same
US7766251B2 (en) 2005-12-22 2010-08-03 Delavan Inc Fuel injection and mixing systems and methods of using the same
DE102006016912A1 (de) * 2006-04-11 2007-12-13 Forschungszentrum Jülich GmbH Verfahren zum Verdampfen eines flüssigen Kraftstoffs sowie eine Mischkammer zur Durchführung dieses Verfahrens
US8074895B2 (en) 2006-04-12 2011-12-13 Delavan Inc Fuel injection and mixing systems having piezoelectric elements and methods of using the same
DE102006024038A1 (de) * 2006-05-23 2007-11-29 Forschungszentrum Jülich GmbH Vorrichtung zur Herstellung eines Kraftstoff-Oxidationsmittel-Gemisches
DE102006032956B4 (de) * 2006-07-17 2010-07-01 Enerday Gmbh Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu gasförmigem Reformat
DE102006046718A1 (de) * 2006-10-02 2008-04-03 Enerday Gmbh Verdampfungsvorrichtung zum Aufbereiten von Brennstoff für einen Reformer und ein Brennstoffzellensystem
CN102143907A (zh) * 2008-07-02 2011-08-03 瑞典电池公司 将烃类燃料转化为富氢气体的重整反应器及方法
WO2010121722A1 (de) * 2009-04-22 2010-10-28 Vaillant Gmbh Vorrichtung zum mischen von gasströmen
FR2960449B1 (fr) * 2010-05-25 2012-08-03 Inst Francais Du Petrole Reacteur pour le reformage autotherme de gasoil
CA2809289A1 (en) * 2010-09-03 2012-03-08 Greg Naterer Thermochemical reactors and processes for hydrolysis of cupric chloride
AT513913B1 (de) 2013-02-04 2016-12-15 Avl List Gmbh Brennstoffzellensystem, welches mit Kohlenwasserstoffen betreibbar ist
AT513912B1 (de) 2013-02-04 2016-08-15 Avl List Gmbh Energieerzeugungseinheit mit einem Hochtemperatur-Brennstoffzellenstack und einer Verdampfungseinheit
US20170241380A1 (en) * 2016-02-22 2017-08-24 Donald Joseph Stoddard Liquid fuel based engine system using high velocity fuel vapor injectors
EP3441360B1 (en) 2017-08-10 2020-07-29 Sener Ingenieria Y Sistemas, S.A. System for alcohol reforming and hydrogen production, units of the system and method thereof
KR20210097189A (ko) * 2018-12-06 2021-08-06 라벤 에스알 엘엘씨 스팀/co2 개질에 의한 수소 및 ft 생성물의 제조
EP3693338B1 (en) 2019-02-07 2021-09-01 Sener Ingenieria Y Sistemas, S.A. High-pressure auto-thermal system for reforming alcohol and producing hydrogen, and method therefor
CN116272454B (zh) * 2023-03-14 2026-01-30 上海齐耀动力技术有限公司 一种气体混合器及固体氧化物燃料电池发电系统

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US5826422A (en) * 1995-01-09 1998-10-27 Hitachi, Ltd. Fuel reforming apparatus and electric power generating system having the same
WO1998058874A1 (de) * 1997-06-24 1998-12-30 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und vorrichtung zur autothermen reformierung von kohlenwasserstoffen
WO2000010911A1 (en) * 1998-08-19 2000-03-02 International Fuel Cells, Llc Method and apparatus for injecting a liquid hydrocarbon fuel into a fuel cell power plant reformer
DE10141843A1 (de) * 2000-08-30 2002-06-13 Denso Corp Wasserstoffversorgungsvorrichtung
US6472092B1 (en) * 1998-08-12 2002-10-29 Honda Giken Kogyo Kabushiki Kaisha Fuel-reforming apparatus comprising a plate-shaped reforming catalyst
WO2003066518A1 (en) * 2002-02-08 2003-08-14 Nissan Motor Co., Ltd. Fuel reforming system and fuel cell system having same
DE10196651T1 (de) * 2000-09-20 2003-09-04 Toshiba Kk Brennstoff-Reformierungsanlage für eine Polymerelektrolytmembran-Brennstoffzelle

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US6872379B2 (en) * 2001-08-15 2005-03-29 Sulzer Hexis Ag Method for the reformation of fuels, in particular heating oil
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Publication number Priority date Publication date Assignee Title
DE2439873A1 (de) * 1973-08-20 1975-03-13 Us Health Verfahren und vorrichtung zum erzeugen wasserstoffreichen gases
US5826422A (en) * 1995-01-09 1998-10-27 Hitachi, Ltd. Fuel reforming apparatus and electric power generating system having the same
WO1998058874A1 (de) * 1997-06-24 1998-12-30 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und vorrichtung zur autothermen reformierung von kohlenwasserstoffen
US6472092B1 (en) * 1998-08-12 2002-10-29 Honda Giken Kogyo Kabushiki Kaisha Fuel-reforming apparatus comprising a plate-shaped reforming catalyst
WO2000010911A1 (en) * 1998-08-19 2000-03-02 International Fuel Cells, Llc Method and apparatus for injecting a liquid hydrocarbon fuel into a fuel cell power plant reformer
DE10141843A1 (de) * 2000-08-30 2002-06-13 Denso Corp Wasserstoffversorgungsvorrichtung
DE10196651T1 (de) * 2000-09-20 2003-09-04 Toshiba Kk Brennstoff-Reformierungsanlage für eine Polymerelektrolytmembran-Brennstoffzelle
WO2003066518A1 (en) * 2002-02-08 2003-08-14 Nissan Motor Co., Ltd. Fuel reforming system and fuel cell system having same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007040192A1 (de) * 2007-08-25 2009-02-26 J. Eberspächer GmbH & Co. KG Reformer und Brennstoffzellensystem
RU2538260C2 (ru) * 2009-04-23 2015-01-10 Эвоник Рем ГмбХ Дозирующее кольцо
US9169194B2 (en) 2009-04-23 2015-10-27 Evonik Röhm Gmbh Metering ring
CN112546889A (zh) * 2020-11-16 2021-03-26 哈尔滨工业大学 一种用于储释热系统热稳定输出的气体混合装置

Also Published As

Publication number Publication date
EP1812154B1 (de) 2020-08-19
JP2008520529A (ja) 2008-06-19
CA2587326C (en) 2013-04-16
DE102004055425A1 (de) 2006-05-24
US7461618B2 (en) 2008-12-09
US20080011250A1 (en) 2008-01-17
CA2587326A1 (en) 2006-05-26
JP4898695B2 (ja) 2012-03-21
EP1812154A1 (de) 2007-08-01
WO2006053534A1 (de) 2006-05-26

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