DE10142747A1 - Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen - Google Patents

Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Info

Publication number
DE10142747A1
DE10142747A1 DE10142747A DE10142747A DE10142747A1 DE 10142747 A1 DE10142747 A1 DE 10142747A1 DE 10142747 A DE10142747 A DE 10142747A DE 10142747 A DE10142747 A DE 10142747A DE 10142747 A1 DE10142747 A1 DE 10142747A1
Authority
DE
Germany
Prior art keywords
metal cyanide
weight
catalyst
dmc
butanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE10142747A
Other languages
German (de)
English (en)
Inventor
Walter Schaefer
Joerg Hofmann
Pieter Ooms
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DE10142747A priority Critical patent/DE10142747A1/de
Priority to MXPA04001909A priority patent/MXPA04001909A/es
Priority to PCT/EP2002/009241 priority patent/WO2003020422A1/de
Priority to KR10-2004-7002928A priority patent/KR20040029087A/ko
Priority to CA002458529A priority patent/CA2458529A1/en
Priority to PL02367455A priority patent/PL367455A1/xx
Priority to BR0212074-7A priority patent/BR0212074A/pt
Priority to RU2004109814/04A priority patent/RU2004109814A/ru
Priority to HU0401624A priority patent/HUP0401624A2/hu
Priority to HK05103884.8A priority patent/HK1071093B/xx
Priority to CNB028166876A priority patent/CN1289194C/zh
Priority to JP2003524724A priority patent/JP2005509051A/ja
Priority to EP02754998A priority patent/EP1425098A1/de
Priority to US10/229,882 priority patent/US6818587B2/en
Priority to TW091119473A priority patent/TW592815B/zh
Publication of DE10142747A1 publication Critical patent/DE10142747A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/049—Pillared clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Polyethers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE10142747A 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen Withdrawn DE10142747A1 (de)

Priority Applications (15)

Application Number Priority Date Filing Date Title
DE10142747A DE10142747A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
MXPA04001909A MXPA04001909A (es) 2001-08-31 2002-08-19 Catalizadores de cianuro metalicos dobles, para la preparacion de polioles de poliester.
PCT/EP2002/009241 WO2003020422A1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
KR10-2004-7002928A KR20040029087A (ko) 2001-08-31 2002-08-19 폴리에테르 폴리올의 제조를 위한 이중 금속 시안화물 촉매
CA002458529A CA2458529A1 (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for the production of polyetherpolyols
PL02367455A PL367455A1 (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for the production of polyetherpolyols
BR0212074-7A BR0212074A (pt) 2001-08-31 2002-08-19 Catalisadores de cianeto de metal duplo para a preparação de poliéter-polióis
RU2004109814/04A RU2004109814A (ru) 2001-08-31 2002-08-19 Двойные металлцианидные катализаторы для получения полиэфирполиолов
HU0401624A HUP0401624A2 (hu) 2001-08-31 2002-08-19 Kettős fém-cianid (DMC) katalizátor poliéter-poliolok előállításához és eljárás előállítására
HK05103884.8A HK1071093B (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for the production of polyetherpolyols
CNB028166876A CN1289194C (zh) 2001-08-31 2002-08-19 用于制备聚醚多元醇的双金属氰化物催化剂
JP2003524724A JP2005509051A (ja) 2001-08-31 2002-08-19 ポリエーテルポリオールを製造するための複金属シアン化物触媒
EP02754998A EP1425098A1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
US10/229,882 US6818587B2 (en) 2001-08-31 2002-08-28 Double-metal cyanide catalysts for preparing polyether polyols
TW091119473A TW592815B (en) 2001-08-31 2002-08-28 Double-metal cyanide catalysts for preparing polyether polyols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10142747A DE10142747A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Publications (1)

Publication Number Publication Date
DE10142747A1 true DE10142747A1 (de) 2003-03-20

Family

ID=7697295

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10142747A Withdrawn DE10142747A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Country Status (14)

Country Link
US (1) US6818587B2 (enExample)
EP (1) EP1425098A1 (enExample)
JP (1) JP2005509051A (enExample)
KR (1) KR20040029087A (enExample)
CN (1) CN1289194C (enExample)
BR (1) BR0212074A (enExample)
CA (1) CA2458529A1 (enExample)
DE (1) DE10142747A1 (enExample)
HU (1) HUP0401624A2 (enExample)
MX (1) MXPA04001909A (enExample)
PL (1) PL367455A1 (enExample)
RU (1) RU2004109814A (enExample)
TW (1) TW592815B (enExample)
WO (1) WO2003020422A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060120012A (ko) * 2003-10-10 2006-11-24 쉘 인터내셔날 리써취 마트샤피지 비.브이. 폴리에테르 폴리올의 제조방법
WO2009093599A1 (ja) * 2008-01-25 2009-07-30 Kaneka Corporation ポリアルキレンオキシドの製造方法
KR101129344B1 (ko) 2009-08-18 2012-03-26 부산대학교 산학협력단 나노 크기 이중금속 혹은 다중금속 시안염 촉매 및 그 제조방법
CN103910865B (zh) * 2014-03-27 2017-02-01 上海应用技术学院 含有小分子聚醚多元醇的双金属氰化物催化剂及制备方法
WO2020062816A1 (zh) 2018-09-29 2020-04-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
WO2023038406A1 (ko) * 2021-09-08 2023-03-16 주식회사 엘지화학 이중 금속 시아나이드 촉매, 이의 제조방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트의 제조방법
WO2023054999A1 (ko) * 2021-09-29 2023-04-06 주식회사 엘지화학 폴리알킬렌 카보네이트 수지의 제조방법

Family Cites Families (17)

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Publication number Priority date Publication date Assignee Title
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
JP2653236B2 (ja) 1990-10-05 1997-09-17 旭硝子株式会社 ポリエーテル化合物の製造方法
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5712216A (en) 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5811829A (en) * 1995-08-10 1998-09-22 Arco Chemical Technology, L.P. Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability
US5545601A (en) 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
US5767323A (en) * 1995-12-22 1998-06-16 Arco Chemical Technology, L.P. Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation
US5627120A (en) 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5714428A (en) 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
US6013596A (en) * 1998-05-18 2000-01-11 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing cyclic, bidentate complexing agents
DE19842383A1 (de) 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19906985A1 (de) * 1999-02-19 2000-08-31 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Also Published As

Publication number Publication date
WO2003020422A1 (de) 2003-03-13
TW592815B (en) 2004-06-21
PL367455A1 (en) 2005-02-21
HK1071093A1 (en) 2005-07-08
CN1547505A (zh) 2004-11-17
CN1289194C (zh) 2006-12-13
EP1425098A1 (de) 2004-06-09
MXPA04001909A (es) 2005-03-07
US6818587B2 (en) 2004-11-16
KR20040029087A (ko) 2004-04-03
US20030050187A1 (en) 2003-03-13
RU2004109814A (ru) 2005-10-20
HUP0401624A2 (hu) 2004-11-29
CA2458529A1 (en) 2003-03-13
JP2005509051A (ja) 2005-04-07
BR0212074A (pt) 2004-09-28

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Owner name: BAYER MATERIALSCIENCE AG, 51373 LEVERKUSEN, DE

8139 Disposal/non-payment of the annual fee