RU2004109814A - Двойные металлцианидные катализаторы для получения полиэфирполиолов - Google Patents
Двойные металлцианидные катализаторы для получения полиэфирполиолов Download PDFInfo
- Publication number
- RU2004109814A RU2004109814A RU2004109814/04A RU2004109814A RU2004109814A RU 2004109814 A RU2004109814 A RU 2004109814A RU 2004109814/04 A RU2004109814/04 A RU 2004109814/04A RU 2004109814 A RU2004109814 A RU 2004109814A RU 2004109814 A RU2004109814 A RU 2004109814A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- double
- cyclic
- metal cyanide
- catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 9
- 229920005906 polyester polyol Polymers 0.000 title 1
- -1 cyanide compound Chemical class 0.000 claims 7
- 239000002184 metal Substances 0.000 claims 6
- 229910052751 metal Inorganic materials 0.000 claims 6
- 229920005862 polyol Polymers 0.000 claims 6
- 239000003446 ligand Substances 0.000 claims 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B01J35/615—
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Claims (7)
1. Двойной металлцианидый катализатор, содержащий
a) по меньшей мере, одно двойное металлцианидное соединение,
b) по меньшей мере, один органический комплексный лиганд, который не является циклическим полиолом, и
c) по меньшей мере, один циклический полиол.
2. Катализатор по п.1, который дополнительно содержит d) воду и/или е) водорастворимую соль металла.
3. Катализатор по п.1 или 2, в котором двойным металлцианидным соединением а) является гексацианокобальтат (111) цинка.
4. Катализатор по п.1 или 2, в котором органическим комплексным лигандом b) является трет-бутанол.
5. Катализатор по п.1 или 2, который содержит 1-80 вес.%, по меньшей мере, одного циклического полиола.
6. Способ получения катализатора, который включает следующие стадии:
i) взаимодействие в водном растворе
α) солей металлов с металлцианидными солями
β) органических комплексных лигандов, которые не являются циклическими полиолами, и
γ) циклических полиолов,
ii) выделение, промывка и сушка полученного на стадии i) катализатора.
7. Способ получения полиэфирполиолов полиприсоединением оксидов алкилена к исходным соединениям, содержащим активные атомы водорода, в присутствии одного или нескольких катализаторов по одному из пп.1-5.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10142747.6 | 2001-08-31 | ||
| DE10142747A DE10142747A1 (de) | 2001-08-31 | 2001-08-31 | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2004109814A true RU2004109814A (ru) | 2005-10-20 |
Family
ID=7697295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004109814/04A RU2004109814A (ru) | 2001-08-31 | 2002-08-19 | Двойные металлцианидные катализаторы для получения полиэфирполиолов |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6818587B2 (ru) |
| EP (1) | EP1425098A1 (ru) |
| JP (1) | JP2005509051A (ru) |
| KR (1) | KR20040029087A (ru) |
| CN (1) | CN1289194C (ru) |
| BR (1) | BR0212074A (ru) |
| CA (1) | CA2458529A1 (ru) |
| DE (1) | DE10142747A1 (ru) |
| HK (1) | HK1071093A1 (ru) |
| HU (1) | HUP0401624A2 (ru) |
| MX (1) | MXPA04001909A (ru) |
| PL (1) | PL367455A1 (ru) |
| RU (1) | RU2004109814A (ru) |
| TW (1) | TW592815B (ru) |
| WO (1) | WO2003020422A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050090572A1 (en) * | 2003-10-10 | 2005-04-28 | Beckers Johannes G.J. | Process for the preparation of a polyether polyol |
| US8481788B2 (en) * | 2008-01-25 | 2013-07-09 | Kaneka Corporation | Process for producing polyalkylene oxide |
| KR101129344B1 (ko) | 2009-08-18 | 2012-03-26 | 부산대학교 산학협력단 | 나노 크기 이중금속 혹은 다중금속 시안염 촉매 및 그 제조방법 |
| CN103910865B (zh) * | 2014-03-27 | 2017-02-01 | 上海应用技术学院 | 含有小分子聚醚多元醇的双金属氰化物催化剂及制备方法 |
| WO2020062816A1 (zh) | 2018-09-29 | 2020-04-02 | 杭州普力材料科技有限公司 | 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法 |
| CN117916020A (zh) * | 2021-09-08 | 2024-04-19 | 株式会社Lg化学 | 双金属氰化物催化剂、制备其的方法和使用其制备聚亚烷基碳酸酯的方法 |
| EP4273183A1 (en) * | 2021-09-29 | 2023-11-08 | Lg Chem, Ltd. | Method for manufacturing polyalkylene carbonate resin |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| JP2653236B2 (ja) | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5712216A (en) | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5670601A (en) * | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
| US5811829A (en) * | 1995-08-10 | 1998-09-22 | Arco Chemical Technology, L.P. | Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability |
| US5545601A (en) | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5767323A (en) * | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5714428A (en) | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
| US6013596A (en) * | 1998-05-18 | 2000-01-11 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing cyclic, bidentate complexing agents |
| DE19842383A1 (de) * | 1998-09-16 | 2000-03-23 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19906985A1 (de) * | 1999-02-19 | 2000-08-31 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
-
2001
- 2001-08-31 DE DE10142747A patent/DE10142747A1/de not_active Withdrawn
-
2002
- 2002-08-19 JP JP2003524724A patent/JP2005509051A/ja active Pending
- 2002-08-19 HU HU0401624A patent/HUP0401624A2/hu unknown
- 2002-08-19 CA CA002458529A patent/CA2458529A1/en not_active Abandoned
- 2002-08-19 EP EP02754998A patent/EP1425098A1/de not_active Withdrawn
- 2002-08-19 CN CNB028166876A patent/CN1289194C/zh not_active Expired - Fee Related
- 2002-08-19 MX MXPA04001909A patent/MXPA04001909A/es active IP Right Grant
- 2002-08-19 BR BR0212074-7A patent/BR0212074A/pt not_active IP Right Cessation
- 2002-08-19 RU RU2004109814/04A patent/RU2004109814A/ru not_active Application Discontinuation
- 2002-08-19 WO PCT/EP2002/009241 patent/WO2003020422A1/de active Application Filing
- 2002-08-19 PL PL02367455A patent/PL367455A1/xx not_active Application Discontinuation
- 2002-08-19 KR KR10-2004-7002928A patent/KR20040029087A/ko not_active Application Discontinuation
- 2002-08-28 TW TW091119473A patent/TW592815B/zh not_active IP Right Cessation
- 2002-08-28 US US10/229,882 patent/US6818587B2/en not_active Expired - Fee Related
-
2005
- 2005-05-09 HK HK05103884A patent/HK1071093A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1289194C (zh) | 2006-12-13 |
| CN1547505A (zh) | 2004-11-17 |
| KR20040029087A (ko) | 2004-04-03 |
| BR0212074A (pt) | 2004-09-28 |
| JP2005509051A (ja) | 2005-04-07 |
| WO2003020422A1 (de) | 2003-03-13 |
| US20030050187A1 (en) | 2003-03-13 |
| MXPA04001909A (es) | 2005-03-07 |
| EP1425098A1 (de) | 2004-06-09 |
| HK1071093A1 (en) | 2005-07-08 |
| TW592815B (en) | 2004-06-21 |
| CA2458529A1 (en) | 2003-03-13 |
| HUP0401624A2 (hu) | 2004-11-29 |
| PL367455A1 (en) | 2005-02-21 |
| US6818587B2 (en) | 2004-11-16 |
| DE10142747A1 (de) | 2003-03-20 |
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