DE10105143A1 - Verfahren zur UV-Schutzausrüstung von textilem Material - Google Patents

Verfahren zur UV-Schutzausrüstung von textilem Material

Info

Publication number
DE10105143A1
DE10105143A1 DE10105143A DE10105143A DE10105143A1 DE 10105143 A1 DE10105143 A1 DE 10105143A1 DE 10105143 A DE10105143 A DE 10105143A DE 10105143 A DE10105143 A DE 10105143A DE 10105143 A1 DE10105143 A1 DE 10105143A1
Authority
DE
Germany
Prior art keywords
textile material
textile
acid
component
components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE10105143A
Other languages
German (de)
English (en)
Inventor
Thomas Heidenfelder
Juergen Detering
Gerhard Wagenblast
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE10105143A priority Critical patent/DE10105143A1/de
Priority to EP02704685A priority patent/EP1383952A2/de
Priority to JP2002562817A priority patent/JP2004528486A/ja
Priority to PCT/EP2002/001179 priority patent/WO2002063091A2/de
Priority to MXPA03006782A priority patent/MXPA03006782A/es
Priority to US10/470,265 priority patent/US20040074012A1/en
Priority to BR0206936-9A priority patent/BR0206936A/pt
Priority to CA002437613A priority patent/CA2437613A1/en
Publication of DE10105143A1 publication Critical patent/DE10105143A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845—Aromatic mono- or polycarboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/2035—Aromatic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
DE10105143A 2001-02-06 2001-02-06 Verfahren zur UV-Schutzausrüstung von textilem Material Withdrawn DE10105143A1 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE10105143A DE10105143A1 (de) 2001-02-06 2001-02-06 Verfahren zur UV-Schutzausrüstung von textilem Material
EP02704685A EP1383952A2 (de) 2001-02-06 2002-02-05 Verfahren zur uv-schutzausrüstung von textilem material
JP2002562817A JP2004528486A (ja) 2001-02-06 2002-02-05 織物材料をｕｖ保護加工する方法
PCT/EP2002/001179 WO2002063091A2 (de) 2001-02-06 2002-02-05 Verfahren zur uv-schutzausrüstung von textilem material
MXPA03006782A MXPA03006782A (es) 2001-02-06 2002-02-05 Metodo para proteger materiales textiles contra la luz uv.
US10/470,265 US20040074012A1 (en) 2001-02-06 2002-02-05 Method for providing textile material with uv protection
BR0206936-9A BR0206936A (pt) 2001-02-06 2002-02-05 Processo para o acabamento de proteção contra uv de material têxtil, formulação detergente para a lavagem de material têxtil, formulação de pós-tratamento de lavagem de roupas e de condicionamento de lavagem de roupas, meio de acabamento de proteção contra uv de um material têxtil, material têxtil, e, uso de um óxido de zinco e/ou dióxido de titânio junto com absorvedores de uv orgânicos sobre o material têxtil
CA002437613A CA2437613A1 (en) 2001-02-06 2002-02-05 Uv protection of textile material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10105143A DE10105143A1 (de) 2001-02-06 2001-02-06 Verfahren zur UV-Schutzausrüstung von textilem Material

Publications (1)

Publication Number Publication Date
DE10105143A1 true DE10105143A1 (de) 2002-08-08

Family

ID=7672904

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10105143A Withdrawn DE10105143A1 (de) 2001-02-06 2001-02-06 Verfahren zur UV-Schutzausrüstung von textilem Material

Country Status (8)

Country Link
US (1) US20040074012A1 (pt)
EP (1) EP1383952A2 (pt)
JP (1) JP2004528486A (pt)
BR (1) BR0206936A (pt)
CA (1) CA2437613A1 (pt)
DE (1) DE10105143A1 (pt)
MX (1) MXPA03006782A (pt)
WO (1) WO2002063091A2 (pt)

Cited By (5)

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WO2003051975A1 (de) * 2001-12-14 2003-06-26 Basf Aktiengesellschaft Stabilisatorzusammensetzung i
EP1389645A3 (en) * 2002-08-02 2004-02-25 Massimo Guarducci S.r.l. High protection against uv radiation fabric and process for the manufacture thereof
WO2008128827A1 (de) * 2007-04-23 2008-10-30 Henkel Ag & Co. Kgaa Photokatalytisches material enthaltende flüssigsysteme
WO2009033877A3 (de) * 2007-09-10 2009-09-17 Henkel Ag & Co. Kgaa Modifiziertes titandioxid
WO2011042275A1 (en) * 2009-10-07 2011-04-14 Unilever Plc Fabric conditioners

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US8038728B2 (en) 2003-05-27 2011-10-18 The Hong Kong University Of Science And Technology Methods of fabric treatment
NZ551804A (en) * 2004-05-18 2010-06-25 Cockerell Dermatology Dev Ltd Soap bars having ultraviolet radiation protection
GB0623004D0 (en) * 2006-11-17 2006-12-27 Unilever Plc Fabric treatment method and composition to impart differential hydrophobocity
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US8690964B2 (en) 2011-10-11 2014-04-08 The Sweet Living Group, LLC Fabric having ultraviolet radiation protection
US9234310B2 (en) 2011-10-11 2016-01-12 The Sweet Living Group, LLC Fabric having ultraviolet radiation protection, enhanced resistance to degradation, and enhanced resistance to fire
US10907048B2 (en) 2018-04-12 2021-02-02 The Sweet Living Group, LLC Product having ultraviolet radiation protection
US20170260395A1 (en) * 2016-03-08 2017-09-14 The Sweet Living Group, LLC Additive for incorporating ultraviolet radiation protection into a polymer
US20210269648A1 (en) * 2011-10-11 2021-09-02 The Sweet Living Group, LLC Product having ultraviolet radiation protection
US8277518B1 (en) 2011-10-11 2012-10-02 The Sweet Living Group, LLC Ecological fabric having ultraviolet radiation protection
US9464260B2 (en) 2011-10-11 2016-10-11 The Sweet Living Group, LLC Laundry detergent composition for providing ultraviolet radiation protection for a fabric
CN102817236A (zh) * 2012-08-28 2012-12-12 北京中纺化工股份有限公司 一种高效日晒牢度提升剂及其制备方法与应用
CN102851942A (zh) * 2012-08-29 2013-01-02 昆山铁牛衬衫厂 防紫外线纯棉织物的整理方法
CN102851766A (zh) * 2012-08-29 2013-01-02 昆山铁牛衬衫厂 防紫外线纤维的生产方法
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WO2014064739A1 (ja) * 2012-10-26 2014-05-01 株式会社アズ 涼感性繊維布およびその製造方法
CN103469559A (zh) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 抗紫外线复合整理剂及其制备方法
CN103726297B (zh) * 2013-11-26 2016-10-05 常熟常圣服饰有限公司 抗紫外线面料的生产工艺
JP6485800B2 (ja) * 2014-01-07 2019-03-20 株式会社Adeka 繊維用機能性付与剤
CN107057125A (zh) * 2017-05-18 2017-08-18 句容亿格纳米材料厂 改性水杨酸对正辛基苯基酯的制备及其在抗光污染塑料中的应用
CN110592963A (zh) * 2019-10-09 2019-12-20 陈晓彤 一种耐老化抗紫外线型布料的生产工艺
US10676861B1 (en) 2019-11-08 2020-06-09 The Sweet Living Group, LLC Method for incorporating ultraviolet radiation protection and antimicrobial protection into rayon
US20230357985A1 (en) * 2022-05-04 2023-11-09 Claros Technologies Inc. Pre- ultraviolet radiation protective additives for textiles and methods of use

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003051975A1 (de) * 2001-12-14 2003-06-26 Basf Aktiengesellschaft Stabilisatorzusammensetzung i
US7196135B2 (en) 2001-12-14 2007-03-27 Basf Aktiengesellschaft Stabilizing composition I
EP1389645A3 (en) * 2002-08-02 2004-02-25 Massimo Guarducci S.r.l. High protection against uv radiation fabric and process for the manufacture thereof
WO2008128827A1 (de) * 2007-04-23 2008-10-30 Henkel Ag & Co. Kgaa Photokatalytisches material enthaltende flüssigsysteme
WO2009033877A3 (de) * 2007-09-10 2009-09-17 Henkel Ag & Co. Kgaa Modifiziertes titandioxid
WO2011042275A1 (en) * 2009-10-07 2011-04-14 Unilever Plc Fabric conditioners
CN102712876A (zh) * 2009-10-07 2012-10-03 荷兰联合利华有限公司 织物调理剂
CN102712876B (zh) * 2009-10-07 2014-03-12 荷兰联合利华有限公司 织物调理剂

Also Published As

Publication number Publication date
CA2437613A1 (en) 2002-08-15
JP2004528486A (ja) 2004-09-16
BR0206936A (pt) 2004-08-10
US20040074012A1 (en) 2004-04-22
WO2002063091A2 (de) 2002-08-15
EP1383952A2 (de) 2004-01-28
MXPA03006782A (es) 2003-11-13
WO2002063091A3 (de) 2003-11-27

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