CZ302375B6 - Termoplastická vulkanizacní kompozice a zpusob její prípravy - Google Patents
Termoplastická vulkanizacní kompozice a zpusob její prípravy Download PDFInfo
- Publication number
- CZ302375B6 CZ302375B6 CZ20000640A CZ2000640A CZ302375B6 CZ 302375 B6 CZ302375 B6 CZ 302375B6 CZ 20000640 A CZ20000640 A CZ 20000640A CZ 2000640 A CZ2000640 A CZ 2000640A CZ 302375 B6 CZ302375 B6 CZ 302375B6
- Authority
- CZ
- Czechia
- Prior art keywords
- polymer
- thermoplastic
- acid anhydride
- grafted
- aminosilane
- Prior art date
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- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- YNTOKMNHRPSGFU-UHFFFAOYSA-N n-Propyl carbamate Chemical compound CCCOC(N)=O YNTOKMNHRPSGFU-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10249298A | 1998-06-22 | 1998-06-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CZ2000640A3 CZ2000640A3 (cs) | 2001-02-14 |
| CZ302375B6 true CZ302375B6 (cs) | 2011-04-20 |
Family
ID=22290137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CZ20000640A CZ302375B6 (cs) | 1998-06-22 | 1999-06-22 | Termoplastická vulkanizacní kompozice a zpusob její prípravy |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6448343B1 (https=) |
| EP (1) | EP1021486B1 (https=) |
| JP (2) | JP3971574B2 (https=) |
| KR (1) | KR100569053B1 (https=) |
| CN (1) | CN1131880C (https=) |
| AT (1) | ATE277121T1 (https=) |
| AU (1) | AU744802B2 (https=) |
| BR (1) | BR9906549B1 (https=) |
| CZ (1) | CZ302375B6 (https=) |
| DE (1) | DE69920392T2 (https=) |
| ES (1) | ES2228068T3 (https=) |
| PL (1) | PL196185B1 (https=) |
| TW (1) | TW548313B (https=) |
| WO (1) | WO1999067330A1 (https=) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ302375B6 (cs) * | 1998-06-22 | 2011-04-20 | General Electric Company | Termoplastická vulkanizacní kompozice a zpusob její prípravy |
| ATE252614T1 (de) * | 1999-12-30 | 2003-11-15 | Michelin Soc Tech | Kautschukzusammensetzung für reifen mit einem kupplungsmittel (wesiser füllstoff/dienelastomer),das durch einen thermisch initierbaren radikalstarter aktiviert wird |
| DE10033446C5 (de) † | 2000-07-10 | 2006-12-14 | Dichtungstechnik G. Bruss Gmbh & Co. Kg | Wellendichtring |
| US7485371B2 (en) * | 2004-04-16 | 2009-02-03 | 3M Innovative Properties Company | Bonding compositions |
| US20050208308A1 (en) * | 2001-05-21 | 2005-09-22 | 3M Innovative Properties Company | Bonding compositions |
| US20040126574A1 (en) * | 2002-12-31 | 2004-07-01 | Teraoka Seisakusho Co., Ltd. | Flame retardant pressure-sensitive adhesive tape |
| US20060073754A1 (en) * | 2001-09-27 | 2006-04-06 | Teraoka Seisakusho Co., Ltd. | Flame retardant pressure-sensitive adhesive tape |
| US20040038018A1 (en) * | 2002-08-22 | 2004-02-26 | Trexel, Inc. | Thermoplastic elastomeric foam materials and methods of forming the same |
| WO2004018557A1 (ja) * | 2002-08-22 | 2004-03-04 | Idemitsu Petrochemical Co., Ltd. | α-オレフィン重合体組成物及びその製造方法 |
| US7064163B2 (en) * | 2002-09-04 | 2006-06-20 | Msi Technology Llc | Polyolefin-based adhesive resins and method of making adhesive resins |
| WO2005001037A2 (en) * | 2003-05-28 | 2005-01-06 | Toyota Technical Center, Usa, Inc. | Electrolyte membranes based on alkyloxysilane grafted thermoplastic polymers |
| IL156870A0 (en) | 2003-07-10 | 2004-02-08 | Carmel Olefines Ltd | Process for making thermoplastic vulcanizates |
| WO2005071012A1 (en) * | 2004-01-13 | 2005-08-04 | Polyone Corporation | Use of a thermoplastic vulcanizate as an impact modifier in blends of polyester and polycarbonate |
| US7365131B2 (en) * | 2004-04-28 | 2008-04-29 | The Goodyear Tire & Rubber Company | Thermoplastic vulcanizate composition |
| DE102004061983A1 (de) * | 2004-12-23 | 2006-07-06 | Rehau Ag + Co. | Materialzusammensetzung zur Vernetzung |
| US20060229399A1 (en) * | 2005-04-12 | 2006-10-12 | General Electric Company | Process for making a thermoplastic vulcanizate composition |
| US20060235156A1 (en) * | 2005-04-14 | 2006-10-19 | Griswold Roy M | Silylated thermoplastic vulcanizate compositions |
| FR2885362B1 (fr) * | 2005-05-04 | 2007-06-08 | Saint Gobain Vetrotex | Composition d'ensimage pour granules de fils de verre a forte teneur en verre |
| US20060258796A1 (en) * | 2005-05-13 | 2006-11-16 | General Electric Company | Crosslinked polyethylene compositions |
| FR2894252B1 (fr) * | 2005-12-07 | 2013-01-04 | Arkema | Composition reticulee comprenant un copolymere coeur ecorce, son procede d'obtention et ses utilisations |
| JP2007238533A (ja) * | 2006-03-10 | 2007-09-20 | Konishi Co Ltd | 低黄変性シリル化剤、それを用いたウレタン系樹脂、及びウレタン系樹脂組成物 |
| DE102006014985A1 (de) * | 2006-03-27 | 2007-10-04 | Deutsche Gumtec Ag | Thermoplastische Vulkanisate |
| US20070276067A1 (en) * | 2006-05-24 | 2007-11-29 | Kim Balfour | Poly(arylene ether) composition, method, and article |
| US20070276082A1 (en) * | 2006-05-24 | 2007-11-29 | Kim Balfour | Poly(arylene ether) composition, method, and article |
| US20070276096A1 (en) * | 2006-05-25 | 2007-11-29 | Wefer John M | Functional polyolefins useful as metal adhesion promoters |
| US20080039576A1 (en) * | 2006-08-14 | 2008-02-14 | General Electric Company | Vulcanizate composition |
| US20080038549A1 (en) * | 2006-08-14 | 2008-02-14 | General Electric Company | Composite structure |
| US8158710B2 (en) * | 2006-11-27 | 2012-04-17 | Sabic Innovative Plastics Ip B.V. | Polyester blends, methods of making, and articles formed therefrom |
| US8785553B2 (en) * | 2007-12-04 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Moisture curable propylene-α-olefin copolymers |
| DE102008041918A1 (de) * | 2008-09-09 | 2010-03-11 | Evonik Degussa Gmbh | Silanolkondensationskatalysatoren zur Vernetzung von gefüllten und ungefüllten Polymer-Compounds |
| DE102010043866A1 (de) * | 2010-11-12 | 2012-05-16 | Tesa Se | Klebmasse und Verfahren zur Kapselung einer elektronischen Anordnung |
| DE102010043853A1 (de) * | 2010-11-12 | 2012-05-16 | Tesa Se | Haft- oder Schmelzklebmassen für feuchtigkeitsunempfindliche Verklebungen |
| EP2574635A1 (en) * | 2011-09-28 | 2013-04-03 | Lanxess Inc. | Process for continuous production of halogen-free thermoplastic elastomer compositions |
| US8883921B2 (en) * | 2012-02-21 | 2014-11-11 | Fina Technology, Inc. | Process for cross-linked polyethylene production |
| CN102911440B (zh) * | 2012-09-18 | 2015-07-15 | 铜陵市铜都特种线缆厂 | 一种航空用绝缘电缆料及其制备方法 |
| EP2942369B1 (en) * | 2014-05-07 | 2016-07-13 | Falcone Specialities AG | Silane vulcanized thermoplastic elastomers |
| KR102220221B1 (ko) | 2014-06-27 | 2021-02-26 | 다우 글로벌 테크놀로지스 엘엘씨 | 냉각 수축 스플라이스를 위한 아이오노머를 형성하는 것에 의한 실리콘 고무／폴리올레핀 엘라스토머 블렌드의 인시튜 상용화 및 이의 제조 방법 |
| US20160160071A1 (en) * | 2014-12-04 | 2016-06-09 | Exxonmobil Chemical Patents Inc. | Water-Based Polyolefin Corrosion Inhibitors Based on Vinyl/Vinylidene Terminated Polyolefins |
| CN105157196A (zh) * | 2015-08-21 | 2015-12-16 | 滁州晨润工贸有限公司 | 一种耐低温空调面板的制造方法 |
| CN106810832A (zh) * | 2016-12-26 | 2017-06-09 | 沈阳化工大学 | 含有稠环结构交联剂的同质异构改性聚对苯二甲酸乙二醇酯及其制备方法 |
| CN107090125A (zh) * | 2017-05-10 | 2017-08-25 | 天长市通联焊业有限公司 | 一种高压直流电缆用绝缘材料及其制备方法 |
| JP7837272B2 (ja) * | 2019-12-31 | 2026-03-30 | セラニーズ・ポリマーズ・ホールディング，インコーポレーテッド | ポリマーブレンド |
| KR102410590B1 (ko) * | 2020-09-17 | 2022-06-16 | 디엘케미칼 주식회사 | 고무배합용 변성 폴리이소부틸렌 중합체 및 이를 포함하는 고무 조성물 |
| CN119955215B (zh) * | 2025-04-02 | 2025-11-07 | 广州海天塑胶有限公司 | 一种高刚度高韧性座椅pp复合材料及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0158764A1 (en) * | 1983-12-29 | 1985-10-23 | Monsanto Company | Compatibilized blends of acrylic ester copolymer rubber |
| EP0262233A1 (en) * | 1986-04-14 | 1988-04-06 | Tonen Chemical Corporation | Thermoplastic resin composition |
| US4764546A (en) * | 1986-04-25 | 1988-08-16 | Sumitomo Chemical Co., Ltd. | Filler-containing polypropylene resin composition and process for producing the same |
| WO1991008257A1 (en) * | 1989-12-01 | 1991-06-13 | Exxon Chemical Patents,Inc. | Thermoplastic resin compositions |
| EP0733675A1 (en) * | 1994-10-05 | 1996-09-25 | Idemitsu Kosan Company Limited | High-impact polystyrene resin composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4146529A (en) * | 1976-03-29 | 1979-03-27 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the production of modified polyolefin |
| JP2506399B2 (ja) * | 1988-01-13 | 1996-06-12 | 株式会社クラレ | ポリオレフイン樹脂組成物 |
| DE4313290A1 (de) | 1993-04-23 | 1994-10-27 | Kempter Werner | Verfahren und Vorrichtung zur Herstellung eines vernetzten extrudierten Polymerproduktes |
| DE4402943C2 (de) | 1994-02-01 | 1996-03-28 | Rustige Bernhard Gmbh & Co Kg | Polymerwerkstoff und Verfahren zu dessen Herstellung |
| CZ302375B6 (cs) * | 1998-06-22 | 2011-04-20 | General Electric Company | Termoplastická vulkanizacní kompozice a zpusob její prípravy |
-
1999
- 1999-06-22 CZ CZ20000640A patent/CZ302375B6/cs not_active IP Right Cessation
- 1999-06-22 JP JP2000555977A patent/JP3971574B2/ja not_active Expired - Fee Related
- 1999-06-22 PL PL338731A patent/PL196185B1/pl unknown
- 1999-06-22 KR KR1020007001731A patent/KR100569053B1/ko not_active Expired - Fee Related
- 1999-06-22 DE DE69920392T patent/DE69920392T2/de not_active Expired - Lifetime
- 1999-06-22 WO PCT/US1999/014019 patent/WO1999067330A1/en not_active Ceased
- 1999-06-22 EP EP99931855A patent/EP1021486B1/en not_active Expired - Lifetime
- 1999-06-22 CN CN998013579A patent/CN1131880C/zh not_active Expired - Fee Related
- 1999-06-22 AT AT99931855T patent/ATE277121T1/de not_active IP Right Cessation
- 1999-06-22 ES ES99931855T patent/ES2228068T3/es not_active Expired - Lifetime
- 1999-06-22 AU AU48275/99A patent/AU744802B2/en not_active Ceased
- 1999-06-22 BR BRPI9906549-5A patent/BR9906549B1/pt not_active IP Right Cessation
- 1999-07-13 TW TW088110458A patent/TW548313B/zh not_active IP Right Cessation
-
2000
- 2000-02-15 US US09/504,285 patent/US6448343B1/en not_active Expired - Lifetime
-
2006
- 2006-06-07 JP JP2006158497A patent/JP4732958B2/ja not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0158764A1 (en) * | 1983-12-29 | 1985-10-23 | Monsanto Company | Compatibilized blends of acrylic ester copolymer rubber |
| EP0262233A1 (en) * | 1986-04-14 | 1988-04-06 | Tonen Chemical Corporation | Thermoplastic resin composition |
| US4764546A (en) * | 1986-04-25 | 1988-08-16 | Sumitomo Chemical Co., Ltd. | Filler-containing polypropylene resin composition and process for producing the same |
| WO1991008257A1 (en) * | 1989-12-01 | 1991-06-13 | Exxon Chemical Patents,Inc. | Thermoplastic resin compositions |
| EP0733675A1 (en) * | 1994-10-05 | 1996-09-25 | Idemitsu Kosan Company Limited | High-impact polystyrene resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9906549B1 (pt) | 2009-01-13 |
| JP3971574B2 (ja) | 2007-09-05 |
| EP1021486A1 (en) | 2000-07-26 |
| ES2228068T3 (es) | 2005-04-01 |
| DE69920392D1 (de) | 2004-10-28 |
| BR9906549A (pt) | 2000-08-15 |
| ATE277121T1 (de) | 2004-10-15 |
| WO1999067330A1 (en) | 1999-12-29 |
| DE69920392T2 (de) | 2005-02-24 |
| US6448343B1 (en) | 2002-09-10 |
| PL196185B1 (pl) | 2007-12-31 |
| CN1131880C (zh) | 2003-12-24 |
| AU744802B2 (en) | 2002-03-07 |
| CN1275143A (zh) | 2000-11-29 |
| JP2006233228A (ja) | 2006-09-07 |
| AU4827599A (en) | 2000-01-10 |
| EP1021486B1 (en) | 2004-09-22 |
| HK1031890A1 (en) | 2001-06-29 |
| KR100569053B1 (ko) | 2006-04-10 |
| JP2002518573A (ja) | 2002-06-25 |
| TW548313B (en) | 2003-08-21 |
| KR20010023109A (ko) | 2001-03-26 |
| CZ2000640A3 (cs) | 2001-02-14 |
| JP4732958B2 (ja) | 2011-07-27 |
| PL338731A1 (en) | 2000-11-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PD00 | Pending as of 2000-06-30 in czech republic | ||
| MM4A | Patent lapsed due to non-payment of fee |
Effective date: 20120622 |