CU20120160A7 - Proceso de extracción por solventes para separar cobalto de níquel en solución acuosa - Google Patents
Proceso de extracción por solventes para separar cobalto de níquel en solución acuosaInfo
- Publication number
- CU20120160A7 CU20120160A7 CU2012000160A CU20120160A CU20120160A7 CU 20120160 A7 CU20120160 A7 CU 20120160A7 CU 2012000160 A CU2012000160 A CU 2012000160A CU 20120160 A CU20120160 A CU 20120160A CU 20120160 A7 CU20120160 A7 CU 20120160A7
- Authority
- CU
- Cuba
- Prior art keywords
- extraction
- solution
- extraction process
- solvent extraction
- nickel cobalt
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
- C22B23/0484—Separation of nickel from cobalt in acidic type solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
- C22B3/404—Mixtures of acyclic or carbocyclic compounds of different types of organic acids and oximes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Proceso para separar Co de Ni en una solución acuosa y que la solución que contiene Ni y Co se somete a extracción y en la extracción se utilizan diferencias cinéticas entre el Ni y el Co con el fin de conseguir al menos una separación parcial de Co de Ni. Este se lleva a cabo controlando la duración de la extracción de modo que se extrae una parte principal de Co y una parte menor de Ni de la solución para producir un extractante cargado, enriquecido con Co y empobrecido de Ni en comparación con la solución de alimentación y un refinado empobrecido de Co conteniendo Ni. En otra realización, la invención utiliza diferencias cinéticas entre el Ni y el Co durante la destilación para llevar a cabo la separación del Ni y el Co. El extractante cargado puede ser sometido a operaciones de destilación colectiva o destilación selectiva para obtener soluciones de Co y de Ni de las que se pueden recuperar Ni y Co. El proceso de la invención se puede incorporar en un proceso hidrometalúrgico para la extracción de Ni y/o Co de un mineral o concentrado conteniendo Ni y Co.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/784,037 US8979976B2 (en) | 2010-05-20 | 2010-05-20 | Solvent extraction process for separating cobalt from nickel in aqueous solution |
PCT/CA2011/000594 WO2011143764A1 (en) | 2010-05-20 | 2011-05-19 | Solvent extraction process for separating cobalt from nickel in aqueous solution |
Publications (2)
Publication Number | Publication Date |
---|---|
CU20120160A7 true CU20120160A7 (es) | 2013-06-28 |
CU24023B1 CU24023B1 (es) | 2014-07-30 |
Family
ID=44971330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CU2012000160A CU24023B1 (es) | 2010-05-20 | 2012-11-14 | Proceso de extracción por solventes para separar cobalto de níquel en solución acuosa |
Country Status (8)
Country | Link |
---|---|
US (2) | US8979976B2 (es) |
EP (1) | EP2572007A4 (es) |
CN (1) | CN103003454B (es) |
AU (1) | AU2011256100B2 (es) |
BR (1) | BR112012029311A2 (es) |
CA (1) | CA2799789C (es) |
CU (1) | CU24023B1 (es) |
WO (1) | WO2011143764A1 (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103740938A (zh) * | 2014-01-13 | 2014-04-23 | 合肥融捷金属科技有限公司 | 无皂化溶剂萃取法回收碳酸钴生产废水中钴的方法 |
US9410225B2 (en) | 2014-05-13 | 2016-08-09 | Teck Resources Limited | Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates |
CN104263928B (zh) * | 2014-09-05 | 2016-06-08 | 昆明理工大学 | 一种超重力场下溶剂萃取分离镍钴的方法 |
CN105803483B (zh) * | 2016-04-06 | 2019-01-25 | 王贺 | 一种电积镍、钴的制备方法 |
KR102041294B1 (ko) * | 2017-12-12 | 2019-11-06 | 재단법인 포항산업과학연구원 | 니켈 제련공정의 석출여액으로부터 코발트 회수 방법 |
JP7175756B2 (ja) * | 2018-12-27 | 2022-11-21 | Jx金属株式会社 | 有価金属の回収方法 |
US11359260B2 (en) * | 2019-09-04 | 2022-06-14 | Korea Resources Corporation | Method of inhibiting degradation of extractant by anhydrous environment avoiding and metal stripping |
CN110616322A (zh) * | 2019-09-20 | 2019-12-27 | 华中科技大学 | 一种利用酸性萃取剂萃取分离钴镍锰的非皂化萃取方法 |
JP7360091B2 (ja) * | 2019-12-27 | 2023-10-12 | 住友金属鉱山株式会社 | 溶媒抽出方法およびコバルト水溶液の製造方法 |
CN111747592A (zh) * | 2020-06-30 | 2020-10-09 | 深圳市深投环保科技有限公司 | 化学镀镍废液资源化利用系统及化学镀镍废液处理方法 |
US10995014B1 (en) | 2020-07-10 | 2021-05-04 | Northvolt Ab | Process for producing crystallized metal sulfates |
CN111996373A (zh) * | 2020-08-26 | 2020-11-27 | 重庆康普化学工业股份有限公司 | 一种从铜钴矿预处理浸出液中协同萃取钴的工艺 |
CN112320860B (zh) * | 2020-11-30 | 2023-02-17 | 北京博萃循环科技有限公司 | 一种提纯硫酸镍的方法 |
CN113512649B (zh) * | 2021-05-27 | 2023-01-13 | 金川集团股份有限公司 | 一种混酸体系下利用臭氧实现镍钴分离的生产方法 |
CN114959302B (zh) * | 2022-06-01 | 2024-03-29 | 中国恩菲工程技术有限公司 | 采用红土镍矿制备硫酸镍/钴的方法 |
CN115771973B (zh) * | 2022-12-16 | 2023-06-20 | 科立鑫(珠海)新能源有限公司 | 一种从强酸性废水中回收镍钴的方法 |
CN118064725B (zh) * | 2024-03-26 | 2024-07-12 | 科立鑫(阳江)新能源有限公司 | 一种镍钴锰废渣回收钴镍的工艺 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4120817A (en) * | 1972-07-03 | 1978-10-17 | Outokumpu Oy | Extraction agent composition |
US4193969A (en) * | 1976-11-12 | 1980-03-18 | Amax Inc. | Selective nickel and cobalt extraction from aqueous acidic solutions |
US4166837A (en) | 1978-03-31 | 1979-09-04 | King Industries, Inc. | Solvent-extraction process for recovery and separation of metal values |
ZW9882A1 (en) | 1981-11-03 | 1983-02-02 | Mineral Tech Council | Selective solvent extraction using organophosphorus and carboxylic acids |
US5378262A (en) * | 1994-03-22 | 1995-01-03 | Inco Limited | Process for the extraction and separation of nickel and/or cobalt |
JP3830986B2 (ja) * | 1995-03-07 | 2006-10-11 | 日本化学工業株式会社 | ジ(1,1,3,3−テトラメチルブチル)ホスフィン及びその製造方法 |
AUPO837197A0 (en) | 1997-08-01 | 1997-08-28 | Centaur Mining & Exploration Limited | Selective precipitation of nickel and cobalt |
ZA987217B (en) | 1997-08-15 | 2000-02-14 | Cominco Eng Services | Chloride assisted hydrometallurgical extraction of metal from sulphide or laterite ores. |
US6231823B1 (en) | 2000-03-27 | 2001-05-15 | Dynatec Corporation | Solvent extraction process for the separation of cobalt from nickel in aqueous sulphate-containing solutions |
WO2002022897A1 (en) | 2000-09-15 | 2002-03-21 | Commonwealth Scientific And Industrial Research Organisation | Recovery of nickel and cobalt from leach solutions |
CA2421970A1 (en) | 2000-09-15 | 2002-03-21 | Commonwealth Scientific And Industrial Research Organisation | Solvent extraction process for recovering nickel and cobalt from leach solutions |
CA2450440C (en) * | 2001-06-13 | 2009-02-03 | Bhp Billiton Sa Limited | Solvent extraction mixture comprising substituted imidazole or benzimidazole for the separation of groups of base metals |
CA2554446A1 (en) | 2004-01-28 | 2005-08-11 | Commonwealth Scientific And Industrial Research Organisation | Solvent extraction process for separating cobalt and/or nickel from impurities in leach solutions. |
US20080038168A1 (en) * | 2004-01-28 | 2008-02-14 | Commonwealth Scientific And Industrial Research Organisation | Solvent Extraction Process For Separating Cobalt And/Or Manganese From Impurities In Leach Solutions |
CA2581106A1 (en) | 2004-09-24 | 2006-03-30 | Commonwealth Scientific And Industrial Research Organisation | Synergistic solvent extraction process |
US7387767B2 (en) | 2005-04-07 | 2008-06-17 | Dynatec Corporation | Recovery of nickel, cobalt, iron, silica, zinc and copper from laterite ore by sulfuric acid leaching |
-
2010
- 2010-05-20 US US12/784,037 patent/US8979976B2/en not_active Expired - Fee Related
-
2011
- 2011-05-19 WO PCT/CA2011/000594 patent/WO2011143764A1/en active Application Filing
- 2011-05-19 BR BR112012029311A patent/BR112012029311A2/pt not_active Application Discontinuation
- 2011-05-19 EP EP11782821.0A patent/EP2572007A4/en not_active Withdrawn
- 2011-05-19 AU AU2011256100A patent/AU2011256100B2/en active Active
- 2011-05-19 CA CA2799789A patent/CA2799789C/en active Active
- 2011-05-19 CN CN201180035477.8A patent/CN103003454B/zh active Active
-
2012
- 2012-11-14 CU CU2012000160A patent/CU24023B1/es active IP Right Grant
-
2015
- 2015-02-11 US US14/619,407 patent/US20150152522A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US8979976B2 (en) | 2015-03-17 |
US20150152522A1 (en) | 2015-06-04 |
BR112012029311A2 (pt) | 2016-07-26 |
AU2011256100B2 (en) | 2014-05-08 |
CA2799789A1 (en) | 2011-11-24 |
US20110283838A1 (en) | 2011-11-24 |
CN103003454B (zh) | 2015-12-09 |
CU24023B1 (es) | 2014-07-30 |
AU2011256100A1 (en) | 2012-11-29 |
WO2011143764A1 (en) | 2011-11-24 |
CN103003454A (zh) | 2013-03-27 |
EP2572007A4 (en) | 2016-12-14 |
EP2572007A1 (en) | 2013-03-27 |
CA2799789C (en) | 2015-07-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant of patent |